Introduction of H2SO4 and H3PO4 into Crystalline Porous Organic Salts(CPOS-1) for Outstanding Proton Conductivity

Yuxia Wang; Tingting Yan; Teng Ben

doi:10.1007/s40242-020-9276-1

Chemical Research in Chinese Universities ›› 2020, Vol. 36 ›› Issue (5) : 976 -980. DOI: 10.1007/s40242-020-9276-1

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Introduction of H₂SO₄ and H₃PO₄ into Crystalline Porous Organic Salts(CPOS-1) for Outstanding Proton Conductivity

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Abstract

To improve the proton conduction of crystalline porous organic salts(CPOS-1), H₂SO₄ and H₃PO₄ were introduced into the channel to obtain H₂SO₄@CPOS-1 and H₃PO₄@CPOS-1. Compared to CPOS-1, the proton conductivities of H₂SO₄@CPOS-1 and H₃PO₄@CPOS-1 increased two orders of magnitude and one order of magnitude at 303 K and 100% RH, respectively. It can be attributed to the increasing concentration of the protons, which dissociates from the acids.

Keywords

Proton conductivity / Crystalline porous organic salt / H₂SO₄ / H₃PO₄

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Yuxia Wang, Tingting Yan, Teng Ben. Introduction of H₂SO₄ and H₃PO₄ into Crystalline Porous Organic Salts(CPOS-1) for Outstanding Proton Conductivity. Chemical Research in Chinese Universities, 2020, 36(5): 976-980 DOI:10.1007/s40242-020-9276-1

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