Zinc-coordination Polymers Based on a Donor-acceptor Mix-ligand System: Syntheses, Crystal Structures and Photophysical Properties
Binbin Qian , Ze Chang , Xian-He Bu
Chemical Research in Chinese Universities ›› 2020, Vol. 36 ›› Issue (1) : 74 -80.
Zinc-coordination Polymers Based on a Donor-acceptor Mix-ligand System: Syntheses, Crystal Structures and Photophysical Properties
By employing an electron-rich tricarboxytriphenyl amine as donor ligand and electron-deficient 2,4,6-tris(pyridin-4-yl)-1,3,5-triazine as acceptor ligand to assemble with Zn2+ ions, three new coordination polymers were successfully synthesized and characterized systematically. Three compounds with different structures were obtained by regulating the reaction solvent, and the effect of the reaction solvent on the synthesis of crystals was explored. Furthermore, the photophysical properties of the compounds were investigated.
Coordination polymer / Donor-acceptor interaction / Tricarboxytriphenyl amine / 2,4,6-Tris(pyridin-4-yl)-1,3,5-triazine
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