3D Tungsten Trioxide Nanosheets as Optoelectronic Materials for On-chip Quantification of Global Antioxidant Capacity

Abstract

The photoelectrochemical properties of semiconductors mainly depend on the size and shape of the corresponding nanoparticles. Herein, 3D WO₃ nanosheets were controllably synthesized with the aid of polyethyleneimine, which presents enhanced photocurrent responses. Based on this excellent photoelectrochemical property, a photoelectrochemical chip was prepared by lithography technology for the smart monitoring of the antioxidant capacity(AC) in red wine and exhibits a series of advantages including rapid response time, high sensitivity, and long-lasting stability. The mechanism of the present photoelectrochemical sensing was explored and shows a single electron transfer reaction. Furthermore, only 200 µL of samples are required for one testing, which demonstrates that the present photoelectrochemical chip can be potentially integrated with a portable commercial device(such as a mobile phone) for further research and development of food and drug supervision.

Keywords

3D tungsten trioxide nanosheet / Photoelectrochemical chip / Antioxidant capacity assessment / Red wine assessment / Gallic acid

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