Dual-modal Colorimetric and Fluorometric Method for Glucose Detection Using MnO₂ Sheets and Carbon Quantum Dots

Abstract

A novel dual-modal fluorometric and colorimetric method was developed for glucose detection using MnO₂ sheets and carbon quantum dots(CQDs). The glucose could be oxidized by glucose oxidase, in accompanied with the formation of H₂O₂ intermediate, which resulted in the decomposition of MnO₂ sheets, as well as the MnO₂ sheets(brown) changed to Mn²⁺ ions(colorless), which induced the absorption of MnO₂ sheet decreased and the fluorescence of CQDs increased, consequently. The linear detection ranges of glucose are 5–1000 µmol/L by fluorescent method and 5–60 µmol/L by colorimetric method. The limits of detection of these two measurements are 2.11 and 2.18 µmol/L, respectively. This method is easy to conduct, has reasonable sensitive and selectivity, and could be applied for the glucose detection in real human serum.

Keywords

MnO₂ / Carbon quantum dot / Colorimetric / Fluorescent / Dual-modal

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