Solvothermal Syntheses and Characterization of Three One-dimension Cadmium Selenidoarsenates [Ni(1,2-dap)₃][As₂CdSe₄], [Zn(1,2-dap)₃][As₂CdSe₄] and [Ni(en)₃][As₂CdSe₄]

Abstract

Three new cadmium selenidoarsenates, [Ni(1,2-dap)₃][As₂CdSe₄](1)(1,2-dap=1,2-diaminopropane), [Zn(1,2-dap)₃][As₂CdSe₄](2) and [Ni(en)₃][As₂CdSe₄](3)(en=ethylenediamine), were synthesized under solvothermal conditions. And they are isostructural and monoclinic crystalls. As seen from their structures, they exhibited one-dimensional(1D) chains composed of [As₂CdSe₄]^2- anions and [TM(amine)₃]²⁺(TM=Ni, Zn; amine=1,2-dap, en) cations. Their absorption edges are 2.32, 1.84 and 2.38 e V, and they show the properties of the semiconductor. These compounds were also characterized by means of single-crystal X-ray diffraction(XRD), powder X-ray diffraction (PXRD), solid-state optical absorption spectrometry, and so on.

Keywords

Solvothermal synthesis / Selenidoarsenate / Cadmium

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