Two Pentavanadate-based Organic-inorganic Materials with Third-order NLO Properties

Abstract

Two isolated organic-inorganic pentavanadate-based hybrids, ${\rm[H_2N(CH_3)_2]_{6.34}[V^V(\mu_3-O)_4V^{IV}_4O_5(SO_4)_4]\cdot(SO_4)_{0.67}\cdot(DMF)\cdot[HN(CH_3)_2]_{1.66}}$\end{document}(1) and [(HN)₂(CH₂)₂(CH₃)₄][V^V(μ ₃-O)₄V₄ ^IVO₅(SO₄)₄][H₂N(CH₃)₂]₃·(DMF)· [HN(CH₃)₂]_0.5(2)(DMF=N,N-dimethylformamide) have been synthesized under solvothermal conditions and structu-rally characterized. In compound 1, three adjacent basic units form a triangle type cluster. The symmetric double-layer exists in compound 2. The study of the third-order nonlinear optical(NLO) properties for the two compounds demonstrates that the two-photon absorption(TPA) cross-section σ values of compounds 1 and 2 are 1372 and 1228 GM, respectively, indicating that both compounds may have potential application in optical field.

Keywords

Pentavanadate / Third-order nonlinear optical property / Crystal structure

References

[1] Hayashi Y. Coord. Chem. Rev., 2011, 255: 2270.

[2] Kioseoglou E., Petanidis S., Gabriel C., Salifoglou A. Coord. Chem. Rev., 2015, 301: 87.

[3] Monakhov K. Y., Bensch W., Kögerler P. Chem. Soc. Rev., 2015, 44: 8443.

[4] Inoue Y., Kodama S., Taya N., Sato H., Oh-ishi K., Ishii Y. Inorg. Chem., 2018, 57: 7491.

[5] Chen J. J., Ye J. C., Zhang X. G., Symes M. D., Fan S. C., Long D. L., Zheng M. S., Wu D. Y., Croni L., Dong Q. F. Adv. Energy Mater., 2018, 8: 1701021.

[6] Li J. K., Huang X. Q., Yang S., Ma H. W., Chi Y. N., Hu C. W. Inorg. Chem., 2015, 54: 1454.

[7] Notario-Estévez A., Kozłowski P., Linnenberg O., Coen D. G., López X., Monakhov K. Y. Phys. Chem. Chem. Phys., 2018, 20: 17847.

[8] Cao J. P., Shen F. C., Luo X. M., Cui C. H., Lan Y. Q., Xu Y. RSC Adv., 2018, 8: 18560.

[9] Tao J., Zhang X. M., Tong M. L., Chen X. M. Dalton. Trans., 2001, 6: 770.

[10] Xiao D. R., Hou Y., Wang E. B., Li Y. G., Lu J., Xu L., Hu C. W. J. Mol. Struct., 2004, 69: 123.

[11] Xiao D. R., Xu Y., Hou Y., Wang E. B., Wang S. T., Li Y. G., Xu L., Hu C. W. Eur.^J. Inorg. Chem., 2004, 7: 1385.

[12] Chen L., Jiang F. L., Lin Z. Z., Zhou Y. F., Yue C. Y., Hong M. C. J.^Am. Chem. Soc., 2005, 127: 8588.

[13] Karet G. B., Sun Z. M., Streib W. E., Bollinger J. C., Hendrickson D. N., Christou G. Chem. Comm., 1999, 22: 2249.

[14] Khan M. I., Ayesh S., Doedens R. J., Yu M. H., O’Connor C. J. Chem. Commun., 2005, 36: 49.

[15] Liu X., Yi X. H., Zhang F. Chem. Inform., 2011, 42: 12.

[16] Zhang H. M., Yang J., Kan W. Q., Liu Y. Y., Ma J. F. Cryst. Growth Des., 2016, 16: 265.

[17] Campbell M. L., Sulejmanovic D., Schiller J. B., Turner E. M., Shiou-Jyh H., Whitehead D. C. Helv. Chim. Acta, 2017, 100: e1600338.

[18] Ma H., Jen A. K. Y., Dalton L. R. Adv. Mater., 2002, 14: 1339.

[19] Spasenović M., Betz M., Costa L., van Driel H. M. Phys. Rev. B, 2008, 77: 085201.

[20] Senthil K., Kalainathan S., Kumar A. R., Aravindan P. G. RSC Adv., 2014, 4: 56112.

[21] Qian Y., Xiao G. M., Wang G., Lin B. P., Cui Y. P., Sun Y. M. Dyes Pigm., 2007, 75: 218.

[22] Chen S. H., Qin Z. H., Liu T. F., Wu X. Z., Li Y. J., Liu H. B., Song Y. L., Li Y. L. Phys. Chem. Chem. Phys., 2013, 15: 12660.

[23] Al-Yasari A., Steerteghem N. V., Moll H. E., Clays K., Fielden J. Dalton Trans., 2016, 45: 2818.

[24] Sheldrick G. M. SADABS, Program for Bruker Area Detector Absorption Correction, 1997.

[25] Sheldrick G. M. SHELXL-2014, Program for Structure Refinement, Universität of Göttingen, 2014.

[26] Zhang Y. T., Wang X. L., Zhou E. L., Wu X. S., Song B. Q., Shao K. Z., Su Z. M. Dalton Trans., 2016, 45: 3698.

[27] Zhang Y. T., Wang X. L., Li S. B., Song B. Q., Shao K. Z., Su Z. M. Inorg. Chem., 2016, 55: 8770.

[28] Breen J. M., Clérac R., Zhang L., Cloonan S. M., Kennedy E., Fee-ney M., McCabe T., Williams D. C., Schmitt W. Dalton Trans., 2012, 41: 2918.

[29] Brown I. D. Chem. Rev., 2009, 109: 6858.

[30] Karet G. B., Sun Z. M., Heinrich D. D., McCusker J. K., Folting K., Streib W. E., Huffman J. C., Hendrickson D. N., Christou G. Inorg. Chem., 1996, 35: 6450.

[31] Zhang Z. J., Wojtas L., Zaworotko M. J. Chem. Sci., 2014, 5: 927.

[32] Cao J. P., Xiong Y., Luo X. M., Chen L., Shi J., Zhou M. J., Xu Y. Dalton Trans., 2018, 47: 6054.

[33] Luo X. M., Chen L., Dong Y. Y., Li J., Cui C. H., Cao J. P., Xu Y. Dalton Trans., 2018, 47: 9504.