Assembly of five coordination polymers based on 5,11,17,23-tetra-tert-butyl-25-(carboxymethoxy)-calix[4]arene ligand

Abstract

Five coordination polymers, [Co(H₃L)₂(dib)]·1.5H₂O(1), [Cu(H₃L)₂(dib)](2), [Co(H₃L)(mtpy)]·DMF(3), [Ni(H₃L)₂(mtpy)(H₂O)]·3DMF·H₂O(4), and [Cd(H₃L)₂(pybim)]·1.5H₂O(5), have been successfully prepared from 5,11,17,23-tetra-tert-butyl-25-(carboxymethoxy)calix[4]arene, metal salts, and N-donor auxiliary ligands under hydrothermal conditions[dib=1,4-di(1H-imidazol-1-yl)butane, pybim=2-(2'-pyridyl)benzimidazole, and mtpy=4'-(4- methylphenyl)-2,2':6',2''-terpyridine]. Structural analysis suggests that the metal ion first joins two organic carboxy-late ligands to form the independent units, which are further extended by the N-donor auxiliary ligand to give the final structure. Compounds 1 and 2 display 1D infinite chains bridged by a flexible bidentate dib ligand. Compounds 3―5, with multidentate chelate ligands, reveal discrete 0D units. Furthermore, in compounds 3 and 5, 1D supramolecular architectures are exhibited due to π-π interactions.

Keywords

Calix[4]arene / Crystal structure / Auxiliary ligand

References

[1] Wang L., Han Y., Feng X., Zhou J., Qi P., Wang B. Coord. Chem. Rev., 2016, 307: 361.

[2] Yang J., Ma J. F., Batten S. R. Chem. Commun., 2012, 48(64): 7899.

[3] Xiao D. J., Gonzalez M. I., Darago L. E., Vogiatzis K. D., Haldoupis E., Gagliardi L., Long J. R. J. Am. Chem. Soc., 2016, 138(22): 7161.

[4] Deenadayalan M. S., Sharma N., Verma P. K., Nagaraja C. M. Inorg. Chem., 2016, 55(11): 5320.

[5] Lu L., Mu B., Li N., Huang R. Chem. Res. Chinese Universities, 2015, 31(5): 712.

[6] Zheng T., Han Y., Liu N. Chem. Res. Chinese Universities, 2016, 32(2): 184.

[7] Liu L., Zhang X. N., Han Z. B., Gao M. L., Cao X. M., Wang S. M. J. Mater. Chem. A, 2015, 3(27): 14157.

[8] Du M., Li C. P., Liu C. S., Fang S. M. Coord. Chem. Rev., 2013, 257: 1282.

[9] Zhang J., Liu Y., Gong L., Zhang C. Polyhedron, 2016, 107: 68.

[10] Xue L. P., Chang X. H., Li S. H., Ma L. F., Wang L. Y. Dalton Trans., 2014, 43(19): 7219.

[11] Rosa I. M. L., Costa M. C. S., Vitto B. S., Amorim L., Correa C. C., Pinheiro C. B., Doriguetto A. C. Cryst. Growth Des., 2016, 16(3): 1606.

[12] Li Q. Q., Zhang W. Q., Ren C. Y., Fan Y. P., Li J. L., Liu P., Wang Y. Y. CrystEngComm, 2016, 18(19): 3358.

[13] Li X. Y., Liu M., Yue K. F., Wu Y. P., He T., Yan N., Wang Y. Y. CrystEngComm, 2015, 17(43): 8273.

[14] Dey S. K., Mitra P., Mukherjee A. Cryst. Growth Des., 2015, 15(2): 706.

[15] Wang S., Zhang R., Wang J., Shen L., Zeng Y., Zhang D. Chem. Res. Chinese Universities, 2014, 30(1): 9.

[16] Zhou P., Wang C., Qiu Q. M., Yao J. F., Sheng C. F., Li H. Dalton Trans., 2015, 44(40): 17810.

[17] Zhang H. M., Yang J., Liu Y. Y., Kang D. W., Ma J. F. CrystEng-Comm, 2015, 17(16): 3181.

[18] Guo X. G., Yang W. B., Wu X. Y., Zhang Q. K., Lin L., Yu R., Chen H. F., Lu C. Z. Dalton Trans., 2013, 42(42): 15106.

[19] Lee E., Kim Y., Heo J., Park K. M. Cryst. Growth Des., 2015, 15(8): 3556.

[20] Wang K., Yang E. C., Zhao X. J., Dou H. X., Liu Y. Cryst. Growth Des., 2014, 14(9): 4631.

[21] Tsymbal L. V., Lampeka Y. D., Boyko V. I., Kalchenko V. I., Shish-kina S. V., Shishkin O. V. CrystEngComm, 2014, 16(18): 3707.

[22] Park K. M., Lee E., Park C. S., Lee S. S. Inorg. Chem., 2011, 50(23): 12085.

[23] Henkelis J. J., Ronson T. K., Hardie M. J. CrystEngComm, 2014, 16(18): 3688.

[24] Liu M., Liao W. P., Hu C. H., Du S. C., Zhang H. J. Angew. Chem. Int. Ed., 2012, 51(7): 1585.

[25] Tan H. Q., Du S. C., Bi Y. F., Liao W. P. Chem. Commun., 2013, 49(74): 8211.

[26] Liu Y. Y., Chen C., Ma J. F., Yang J. Crystengcomm, 2012, 14(19): 6201.

[27] Chen C., Ma J. F., Liu B., Yang J., Liu Y. Y. Cryst. Growth Des., 2011, 11(10): 4491.

[28] Othman A. B., Cheriaa N., Abidi R., Vicens J., Thuery P., Acta Cryst., 2004, C60, o859-61

[29] He Y. C., Guo J., Yang J., Liu H. Y., Liu Y. Y., Zhai Q. Y., Shen Q. T., Ma J. F. Polyhedron, 2015, 99: 156.

[30] Jablonska-Wawrzycka A., Rogala P., Michalkiewicz S., Hodorowicz M., Barszcz B. Dalton Trans., 2013, 42(17): 6092.

[31] Sheldrick G. M. SHELXL-97, Programs for X-Ray Crystal Structure Solution, 1997.

[32] Sheldrick G. M. SHELXL-97, Programs for X-Ray Crystal Structure Refinement, 1997.

[33] Farrugia L. J. WINGX: A Windows Program for Crystal Structure Analysis, 1988.