Preparation of Fe₃O₄-porphyrin nano-composited particles and their optical and magnetic properties

Abstract

Magnetic Fe₃O₄ nanoparticles were synthesized via the coprecipitation of ferrous and ferric ion. The morphology and magnetic properties of the magnetic Fe₃O₄ nanoparticles were investigated by transmission electron microscopy(TEM) and superconducting quantum interference device. Furthermore, the Fe₃O₄-porphyrin nanocomposite particles(FeOPNCPs) are prepared with Fe₃O₄ and porphyrin by sol-gel method. The patterns of FeOPNCPs were also characterized by means of scanning electron microscopy(SEM) and TEM. The optical and magnetic properties of FeOPNCPs were investigated on a UV-Vis spectrophotometer, a fluorescence spectrophotometer and a superconducting quantum interference device. These experimental results show that FeOPNCPs not only possess optical features of porphyrin but also retain the superparamagnetic features of Fe₃O₄ nanoparticles.

Keywords

Fe₃O₄ / Porphyrin / Nano-composited particle / Fluorescence / Magnetic property

References

[1] Haynes C. L., van Duyne R. P. J. Phys. Chem. B, 2001, 105: 5599.

[2] Xue Y. C., Zun D. L. J. Phys.: Condens. Mat., 1997, 9: 798.

[3] Kim H., Achermann M., Balet L. P., Hollingsworth J. A., Klimov V. I. J. Am. Chem. Soc., 2005, 127: 544.

[4] Yu X., Shan Y., Li G., Chen K. J. Mater. Chem., 2011, 21: 8104.

[5] Tian Q., Hu J., Zhu Y., Zou R., Chen Z., Yang S., Li R., Su Q., Han Y., Liu X. J. Am. Chem. Soc., 2013, 135: 8571.

[6] Sun C., Lee J. S., Zhang M. Adv. Drug Deliv. Rev., 2008, 60: 1252.

[7] Kim J., Kim H. S., Lee N., Kim T., Kim H., Yu T., Song I. C., Moon W. K., Hyeon T. Angew. Chem. Int. Ed., 2008, 47: 8438.

[8] Gao J., Zhang W., Huang P., Zhang B., Zhang X., Xu B. J. Am. Chem. Soc., 2008, 130: 3710.

[9] Ma Q., Yu W., Dong X., Wang J., Liu G., Xu J. Opt. Mater., 2013, 35: 526.

[10] Jiang J., Gu H., Shao H., Devlin E., Papaefthymiou G. C., Ying J. Y. Adv. Mater., 2008, 20: 4403.

[11] Weller D., Brändle H., Gorman G., Lin C. J., Notarys H. Appl. Phys. Lett., 1992, 61: 2726.

[12] Pankhurst Q. A., Connolly J., Jones S. K., Dobson J. J. J. Phys. D: Appl. Phys., 2003, 36: R167.

[13] Liang R. P., Yao G. H., Fan L. X., Qiu J. D. Anal. Chim. Acta, 2012, 737: 22.

[14] Liu Q., Hu L., Zhao Q., Zhu R., Yang Y., Jia Q., Bing B., Zhuo L. Meas. Sci. Technol., 2014, 41: 142.

[15] Gu L., He X., Wu Z. Mater. Chem. Phys., 2014, 148: 153.

[16] Li Y. C., Lin Y. S., Tsai P. J., Chen C. T., Chen W. Y., Chen Y. C. Anal. Chem., 2007, 79: 7519.

[17] Guo X. M., Su L. J., Yu L.X., Shi T. S. Chem. J. Chinese Univer-sities, 2006, 27(3): 410.

[18] Guo X. M., Guo B., Sun X., Zhang Q., Shi T. S. Chinese J. Chem., 2011, 29: 363.

[19] Guo X.M., Guo B., Zhang Q., Sun X. Dalton, 2011, 40: 3039.

[20] Stohr J., Nakajima R. J. Res. Dev., 1998, 42: 73.

[21] Guo X. M., Guo B. J. Phys. Chem., 2015, 19: 8591.

[22] Sudakar C., Subbanna N. G., Kutty N. T. Journal of Materials Chemistry, 2002, 1: 107.