Basic catalytic performance of amino and acylamide functionalized metal-organic framework in the synthesis of chloropropene carbonate from CO₂ under atmospheric pressure

Abstract

In this work, a metal-organic framework with free standing basic groups(e. g., amino and acylamide groups) decorated in the pore wall was utilized to catalyze the CO₂ cycloaddition reaction and its basic properties were tested in Knoevenagel condensation reactions. The results reveal that the metal-organic framework(MOF) material has excellent catalytic activity and high repeatability for the synthesis of chloropropene carbonate from CO₂ and epichlorohydrin with no co-catalyst under mild reaction conditions, suggesting that it is a promising heterogeneous catalyst for CO₂ cycloaddition reaction.

Keywords

Metal-organic framework / Heterogeneous catalysis / CO₂ / Chloropropene carbonate

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