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Abstract
Three different dimensional Ni(II) coordination polymers, [Ni(3-pna)(HIP)(H2O)3]·H2O(1), [Ni(3-pna)· (1,3,5-HBTC)](2) and [Ni2(H2O)(3-pna)2(1,4-CHDC)2]4(3)(3-pna=3-pyridylnicotinamide, H2HIP=5-hydroxyisophthalic acid, 1,3,5-H3BTC=1,3,5-benzenetricarboxylic acid, 1,4-H2CHDC=1,4-cyclohexanedicarboxylic acid), were synthesized under hydrothermal conditions and characterized by means of infrared spectra(IR), thermal gravimetric (TG) analyses, powder X-ray diffraction(PXRD) and single-crystal X-ray diffraction. Complex 1 has a structure of 1D single-stranded chain, which is further stretched by hydrogen-bond interactions to form a 2D supramolecular sheet. Complex 2 shows a 2D network, which is stretched to 3D supramolecular frameworks through hydrogen-bond interactions. Complex 3 reveals a 3D skeleton with a (3,3,6,6)-connected {3·72}{32·4}{33·42·5·73·85·9}{33·45·52·72·82·9} topology. The effects of different polycarboxylates on the ultimate architectures of the complexes 1—3 were discussed. Furthermore, the fluorescent and photocatalytic properties of the title complexes were also investigated.
Keywords
Crystal structure
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Dipyridylamide
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Polycarboxylate
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Photoluminescence property
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Photocatalytic property
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Xiaomei Wu, Guocheng Liu, Xiuli Wang, Jiyan Shao, Hongyan Lin, Xiang Wang.
Three Ni(II) coordination polymers with various architectures based on asymmetric bis-pyridyl-amide and polycarboxylates: Syntheses, structures and properties.
Chemical Research in Chinese Universities, 2016, 32(5): 719-724 DOI:10.1007/s40242-016-6072-z
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