Studies on the halogen substituted β-amino acids and their Cu(II) coordination complexes in crystallography

Abstract

Halogen substituted β-amino acids, D,L-3-amino-3-(4-fluoro)phenylpropionic acid(D,L-HL1, 1) and D,L-3-amino-3-(4-bromo)phenylpropionic acid(D,L-HL2, 2), as well as their Cu(II) coordination complexes [Cu(L1)₂(CH₃OH)₂]·2CH₃OH(3) and [Cu(L2)₂(CH₃OH)₂]·2CH₃OH(4) were investigated and their single crystal structures were discussed in details. Supramolecular helical chains were found in β-amino acids 1 and 2 while there was no helix in their coordination complexes 3 and 4. The formation of supramolecular helixes could be due to the hydrogen bonds between terminal ―NH₃ ⁺ and adjacent ―COO^– in β-amino acids 1 and 2. While, this kind of hydrogen bonds could not be observed in their Cu(II) coordination complexes 3 and 4, in which central-symmetrical dimers could be formed via coplanar coordinated bonds(N―Cu―O) between ―NH₂ and ―COO^–.

Keywords

β-Amino acid / Copper / H-Bonding / Halogen / Crystal structure

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