Hydrothermal synthesis, structure and property of transition metal(Mn, Zn, Cd or Pb) coordination frameworks using quinoline-8-oxy-acetate acid and dicarboxylic acid as ligands

Abstract

Five transition metal coordination compounds, [Mn₂(8-qoac)₂(bdc)(H₂O)₄](1)(8-qoacH=quinoline-8-oxy-acetate acid, H₂bdc=benzene-1,4-dicarboxylic acid), [Zn₄(8-qoac)₄(bdc)₂] _n(2), {[Cd₂(8-qoac)₂(Hip)₂(H₂O)₂]·(H₂O)₄} _n(3)(H₂ip=benzene-1,3-dicarboxylic acid), [Pb₃(8-qoac)₂(bdc)_1.5(H₂O)Cl] _n(4) and [Zn₂(8-qoac)(8-ql)(bdc)] _n (5)(8-Hql=8-hydroxyquinoline), were synthesized by hydrothermal syntheses of metal salts with benzenedicarboxylic acid and 8-qoacH. Compound 1 possesses a discrete dimer bridged by bdc²⁻ ligand. Compound 2 presents a 2D layer network constructed from bdc²⁻ linkers and 1D infinite ribbons, in which Zn(II) centers are bridged by 8-qoac⁻ with a tetradentate binding mode. Compound 3 displays a 1D zigzag chain, with adjacent chains further connected via extensive O-H…O hydrogen bonds to generate a 3D supramolecular structure. Compound 4 shows a 3D framework containing trinuclear lead secondary building units and bdc²⁻ linkers, in which a new coordination mode of 8-qoac⁻ ligand is observed. In compound 5, Zn(II) ions are simultaneously bridged by 8-qoac⁻, 8-ql⁻ and bdc²⁻ ligands to form tetranuclear zinc units, which are further interlinked by bdc²⁻ linkers to yield a 2D wave-like layer. Based on intraligand(IL)(π-π*) fluorescent emission, compounds 1–5 possess strong purple fluorescent emissions. In addition, the thermal stabilities of compounds 1–5 were studied.

Keywords

Coordination compound / Quinoline-8-oxy-acetate acid / Crystal structure / Photoluminescence property

References

[1] Kitagawa S, Kitaura R, Noro S. Angew. Chem. Int. Ed., 2004, 43: 2334.

[2] Zheng Y Z, Wei HY, Pan F, Wang Z M, Chen Z D, Gao S. Angew. Chem. Int. Ed., 2005, 44: 5841.

[3] Eddaoudi M, Kim J, Rosi N, Vodak D, Wachter J, O’Keeffe M, Yaghi O M. Science, 2002, 295: 469.

[4] Zhang J P, Zhang Y B, Lin J B, Chen X M. Chem. Rev., 2012, 112: 1001.

[5] Zheng Y Z, Gao S, Sun H L, Su G, Wang Z M, Zhang SW. Chem. Commun., 2004, 1906.

[6] Liu C, Zhuo X, Zhang H, Liu X H. Chem. J. Chinese Universities, 2014, 35(5): 928.

[7] Wang Y Y, Zhang Z, Sun Y J, Li J Y. Chem. J. Chinese Universities, 2014, 35(3): 449.

[8] Müller I M, Robson R. Angew. Chem. Int. Ed., 2000, 39: 4357.

[9] Abrahams B F, Jackson P A, Robson R. Angew. Chem. Int. Ed., 1998, 37: 2656.

[10] Park K M, Moon S T, Kang Y J, Kim H J, Seo J, Lee S S. Inorg. Chem. Commun., 2006, 9: 671.

[11] Benito-Garagorri D, Lackner-Warton W, Standfest-Hauser C M, Mereiter K, Kirchner K. Inorg. Chim. Acta, 2010, 363: 3674.

[12] Kalita D, Deka H, Samanta S S, Guchait S, Baruah J B. J. Mol. Struct., 2011, 990: 183.

[13] Zheng Z B, Wu RT, Li J K, Sun Y F. J. Coord. Chem., 2008, 61: 2750.

[14] Al-Mandhary M R A, Fitchett C M, Steel P J. Aust. J. Chem., 2006, 59: 307.

[15] Man S P, Benoit D M, Buchaca E, Esan F, Motevalli M, Wilson J, Sullivan A. Inorg. Chem., 2006, 45: 5328.

[16] Al-Mandhary M R A, Steel P J. Eur. J. Inorg. Chem., 2004, 329.

[17] Cheng X N, Zhang W X, Chen X M. J. Am. Chem. Soc., 2007, 129: 15738.

[18] Fan J, Wang Z H, Huang Z F, Yin X, Zhang W G. Inorg. Chem. Commun., 2010, 13: 659.

[19] Wang Y H, Song RF, Zhang F Y. J. Mol. Struct., 2005, 752: 104.

[20] Lin H P, Zhou F, Li J, Zhang X W, Zhang L, Jiang X Y, Zhang Z L, Zhang J H. J. Phys. Chem. C, 2011, 115: 24341.

[21] Qiao J, Wang L D, Duan L, Li Y, Zhang D Q, Qiu Y. Inorg. Chem., 2004, 43: 5096.

[22] O’Keeffe M, Yaghi O M. Chem. Rev., 2012, 112: 675.

[23] Paz F A A, Khimyak Y Z, Bond A D, Rocha J, Klinowski J. Eur. J. Inorg. Chem., 2002, 2823.

[24] Braun M E, Steffek C D, Kim J, Rasmussen P G, Yaghi O M. Chem. Commun., 2001, 2532.

[25] Li X J, Ma G C, Xu X H. J. Coord. Chem., 2013, 66: 3249.

[26] Koelsch C F. J. Am. Chem. Soc., 1931, 53: 304.

[27] Sheldrick G M. SHELXS-97, Program for X-ray Crystal Structure Determination, 1997, Göttingen: University of Göttingen.

[28] Sheldrick G M. SHELXL-97, Program for X-ray Crystal Structure Refinement, 1997, Göttingen: University of Göttingen.

[29] Wang J J, Bao Q L, Chen J X. J. Coord. Chem., 2013, 66: 2578.

[30] Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 1997 5th Ed. New York: John Wiley&Sons, 62.

[31] Liang J H, Wei Q, Qiao C F, Xia Z Q, Ye G, Chen S P. Chin. J. Chem., 2012, 30: 715.

[32] Shimoni L L, Glusker J P, Bock C W. Inorg. Chem., 1998, 37: 1853.

[33] Hancock R D, Reibenspies J H, Maumela H. Inorg. Chem., 2004, 43: 2981.

[34] Luckay R, Cukrowski I, Mashishi J, Reibenspies J H, Bond A H, Rogers R D, Hancock R D. J. Chem. Soc., Dalton Trans., 1997, 901.

[35] Hua J Y, Li S S, Zhao J A, Chen S F, Hou H W, Zhao H P. J. Coord. Chem., 2012, 65: 1258.

[36] Wang Z, Wei Q, Xie G, Yang Q, Chen S P, Gao S L. J. Coord. Chem., 2012, 65: 256.

[37] Qiao C F, Wei Q, Xia Z Q, Liang J H, Chen S P. Chin. J. Chem., 2011, 29: 724.

[38] Zhou H P, Wang P, Zheng L X, Geng W Q, Yin J H, Gan X P, Xu G Y, Wu J Y, Tian Y P, Kan Y H, Tao X T, Jiang M H. J. Phys. Chem. A, 2009, 113: 2584.

[39] Simeon T M, Ratner M A, Schatz G C. J. Phys. Chem. A, 2013, 117: 7918.

[40] Xia Z Q, Chen S P, Wei Q, Qiao C F. J. Solid State Chem., 2011, 184: 1777.

[41] Vogler A, Kunkely H. Coord. Chem. Rev., 2006, 250: 1622.

[42] Ballardini R, Varani G, Indelli M T, Scandola F. Inorg. Chem., 1986, 25: 3858.

[43] Kunkely H, Vogler A. Chem. Phys. Lett., 1999, 304: 187.

[44] Djurovicht P I, Watts R J. Inorg. Chem., 1993, 32: 4681.

[45] Valeur B. Molecular Fluorescence Principles and Applications, 2002, Weinheim: Wiley-VCH, 72.

[46] Xu J K, Sun X C, Ju C X, Yang L R, Bi C F, Sun M. J. Coord. Chem., 2013, 66: 2693.

[47] Wang H H, Gan Q, Wang X J, Xue L, Liu S H, Jiang H. Org. Lett., 2007, 9: 4995.

[48] Zhao X X, Ma J P, Dong Y B, Huang R Q. Cryst. Growth Des., 2007, 7: 1058.

[49] Zhao H, Chen J M, Lin J R, Wang W X. J. Coord. Chem., 2011, 64: 2735.