Assembly of two coordination polymers based on 2,2′-bipyridyl-4,4′-dicarboxylic acid ligand

Abstract

Two novel 2D coordination polymers, [Co(BPDC)DMSO]·DMSO(1)(BPDC=2,2′-bipyridyl-4,4′-dicarboxylic acid) and [Zn(BPDC)DMF]·DMF(2), were synthesized from 2,2′-bipyridyl-4,4′-dicarboxylic acid ligand (H2BPDC) under solvothermal conditions. Single crystal X-ray diffraction analyses reveal that compound 1 crystallizes in orthorhombic system and Pca2₁ space group with a=1.29628(13) nm, b=1.13721(13) nm, c=1.66457(19) nm, α=90°, β=90°, γ=90°, V=2.4538(5) nm3. Compound 2 crystallizes in monoclinic system and P21/c space group with a=0.9429(6) nm, b=1.4757(10) nm, c=1.5980(9) nm, α=90°, β=114°, γ=90°, V=2.030(2) nm³. Compounds 1 and 2 exhibit two different 3-connected hcb and fes topologies, respectively. The structures of the two compounds both contain interesting characters of double-helical chains (left- and right-handed helical chains). Additionally, the magnetic and luminescent properties of the two compounds were studied.

Keywords

Coordination polymer / Helical chain / Magnetic property / Luminescent property

References

[1] Li M., Li D., O’Keeffe M., Yaghi O. M. Chem. Rev, 2014, 114: 1343.

[2] Clough A., Zheng S. T., Zhao X., Lin Q. P., Feng P. Y., Bu X. H. Cryst. Growth Des, 2014, 14: 897.

[3] Zhou X. P., Li M., Liu J., Li D. J. Am. Chem. Soc, 2011, 134: 67.

[4] Luo Y. N., Xu X. Z., Sun F. X., Yu X. Y., Zhang X., Zhang T., Yu L. Y. Chem. Res. Chinese Universities, 2014, 30(30): 27.

[5] Luo J. H., Wang J., Li G. H., Huo Q. S., Liu Y. L. Chem. Commun, 2013, 49: 1143.

[6] Zhang Y., Chen L., Ju W. W., Xu Y. Chem. Res. Chinese Universities, 2014, 30(30): 194.

[7] Liu Y. Y., Li H. J., Han Y., Lü X. F., Hou H. W., Fan Y. T. Cryst. Growth Des, 2012, 12: 3505.

[8] Lin R. B., Li F., Liu S. Y., Qi X. L., Zhang J. P., Chen X. M. Angew. Chem. Int. Ed, 2013, 52: 1342.

[9] Feng X., Liu J., Chen J. L., Huo S. Z., Wang L. Y., Ng S. W. I. norg. Chem. Commun, 2014, 50: 42.

[10] Sun M. C., Yan F. C., Rui L., Xiao P. L., Jian Z., Cryst. Eng. Comm., 2013, 15, 10423

[11] Wang J. L., Wang D. J., Li X. Chem. Res. Chinese Universities, 2014, 30(30): 347.

[12] Guo S. S., Wang Z. L., Xu G. W., Wu Y. P., Li D. S. Inorg. Chem. Comm, 2014, 49: 143.

[13] Cao T. T., Peng Y. Q., Liu T., Wang S. N., Dou J. M., Li Y. W., Zhou C. H., Li D. C., Bai J. F. Cryst. Eng. Comm, 2014, 16: 10658.

[14] Han M. L., Duan Y. P., Li D. S., Xu G. W., Wu Y. P., Zhao J. Dalton Trans, 2014, 43: 1751.

[15] Wang S., Zhao T. T., Li G. H., Wojtas L., Huo Q. S., Eddaoudi M., Liu Y. L. J. Am. Chem. Soc, 2010, 132: 18038.

[16] Zuo Y., Fang M., Xiong G., Shi P. F., Zhao B., Cui J. Z., Cheng P. Cryst. Growth Des, 2012, 12: 3917.

[17] Tuikka M., Hirva P., Rissanen K., Korppi-Tommola J., Haukka M. Chem. Commun, 2011, 47: 4499.

[18] Tynan E., Jensen P., Lees A. C., Moubaraki B., Murray K. S., Kruger P. E. Cryst. Eng. Comm, 2005, 7: 90.

[19] Shi P. F., Zhao B., Xiong G., Hou Y. L., Cheng P. Chem. Commun, 2012, 48: 8231.

[20] Feng R., Chen L., Chen Q. H., Shan X. C., Gai Y. L., Jiang F. L., Hong M. C. Cryst. Growth Des, 2011, 11: 1705.

[21] Zhang H. B., Wu S. T., Tian C. B., Lin Z. J., Li Z. H., Lin P., Du S. W. Cryst. Eng. Comm, 2012, 14: 4165.

[22] Kent C. A., Mehl B. P., Ma L. Q., Papanikolas J. M., Meyer T. J., Lin W. B. J. Am. Chem. Soc, 2010, 132: 1276.

[23] Kent C. A., Liu D. M., Ma L. Q., Papanikolas J. M., Meyer T. J., Lin W. B. J. Am. Chem. Soc, 2011, 133: 1294.

[24] Sheldrick G. M. SHELXTL-NT, Version 5.1, 1997.