Synthesis of Zn-containing aluminophosphate with ERI topology

Abstract

A Zn-containing aluminophosphate with ERI-zeotype structure was hydrothermally synthsized with 1,2-diaminocyclohexane(DACH) as the template. The result of the structural analysis indicates that the Zn-containing aluminosphate crystallized in the hexagonal space group of P6₃/m was constituted up by the alternating Al(Zn)O₄ and PO₄ tetrahedra. The organic amine DACH located in the ERI cages was used to balance the negative charge of the framework.

Keywords

Aluminophosphate / Substitution / ERI topology / Molecular sieve

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