PDF
Abstract
Four lanthanide coordination polymers, LaL3(H2O)2(1), LnL2(µ3-OH)(H2O)[Ln=Eu(2),Tb(3)] and ErL3·2H2O(4) were synthesized via hydrothermal reactions of lanthanide oxide with 4-pyridin-4-ylbenzonic acid(HL), and characterized by means of elemental analyses, infrared(IR) spectrometer, powder X-ray diffraction(PXRD), thermogravimetric analyses(TGA) and single-crystal XRD. The results reveal that complex 1 possesses a linear chain structure, complexes 2 and 3 possess isostructural ladder-like chains, while complex 4 possesses a 2D layer with 4-connected sql topology. Furthermore, the luminescence properties and UV-Vis spectra of complexes 2 and 3 were investigated.
Keywords
Hydrothermal synthesis
/
Lanthanide
/
Luminescence property
Cite this article
Download citation ▾
Weihui Fang, Guoyu Yang.
A series of lanthanide coordination polymers constructed from 4-pyridin-4-ylbenzoate.
Chemical Research in Chinese Universities, 2015, 31(2): 187-191 DOI:10.1007/s40242-015-4316-y
| [1] |
Yaghi O M, O’Keeffe M, Ockwig N W, Chae H K, Eddaoudi M, Kim J. Nature, 2003, 423: 705.
|
| [2] |
Kagan H B. Chem. Rev., 2002, 102: 1805.
|
| [3] |
Rocha J, Carlos L D, Paz F A, Ananias D. Chem. Soc. Rev., 2011, 40: 926.
|
| [4] |
Zhao X Q, Wang H, Dong L J, Xu Q H. Chem. J. Chinese Universities, 2013, 34(6): 1318.
|
| [5] |
Benelli C, Gatteschi D. Chem. Rev., 2002, 102: 2369.
|
| [6] |
Khan N H, Kureshy R I, Abdi S H R, Agrawal S, Jasra R V. Coord. Chem. Rev., 2008, 252: 593.
|
| [7] |
Zhang M B, Zhang J, Zheng S T, Yang G Y. Angew. Chem. Int. Ed., 2005, 44: 1385.
|
| [8] |
Cheng J W, Zhang J, Zheng S T, Zhang M B, Yang G Y. Angew. Chem. Int. Ed., 2006, 45: 73.
|
| [9] |
Cheng J W, Zheng S T, Liu W, Yang G Y. CrystEngComm, 2008, 10: 1047.
|
| [10] |
Huang Y G, Jiang F L, Hong M C. Coord. Chem. Rev., 2009, 253: 2814.
|
| [11] |
Fang W H, Cheng L, Huang L, Yang G Y. Inorg. Chem., 2013, 52: 6.
|
| [12] |
Fang W H, Wang Z L, Yang G Y. Chin. J. Inorg. Chem., 2010, 26: 1917.
|
| [13] |
Wang Z L, Fang W H, Yang G Y. J. Cluster Sci., 2009, 20: 725.
|
| [14] |
Fang W H, Wang Z L, Yang G Y. J. Cluster Sci., 2010, 21: 187.
|
| [15] |
Wang Z L, Fang W H, Yang G Y. Chinese J. Struct. Chem., 2009, 28: 1453.
|
| [16] |
Sheldrick G M. SADABS, Program for Siemens Area Detector Absorption Corrections, 1997, Göttingen: University of Göttingen.
|
| [17] |
Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, 1997, Göttingen: University of Göttingen.
|
| [18] |
Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, 1997, Göttingen: University of Göttingen.
|
| [19] |
Fu J, Zheng L, Zhang Z, Xu Y. Inorg. Chim. Acta, 2012, 383: 112.
|
| [20] |
Wang S H, Hu H Z, Chen C, Ma R N Z N. Chem. J. Chinese Universities, 2014, 35(10): 2055.
|
| [21] |
Sun Y Q, Zhang J, Chen Y M, Yang G Y. Angew. Chem. Int. Ed., 2005, 44: 5814.
|
| [22] |
Pan L, Huang X, Li J, Wu Y, Zheng N. Angew. Chem. Int. Ed., 2000, 39: 527.
|
| [23] |
Zhang Y, Chen L, Ju W W, Xu Y. Chem. Res. Chinese Universities, 2014, 30(2): 194.
|
| [24] |
Blatov V A, Shevchenko A P, Proserpio D M. Cryst. Growth Des., 2014, 14: 3576.
|
| [25] |
Sun Y Q, Zhang J, Yang G Y. Chem. Commun., 2006, 1947.
|
| [26] |
Kirby A F, Foster D, Richardson F S. Chem. Phys. Lett., 1983, 95: 507.
|
| [27] |
Cheng J W, Zheng S T, Yang G Y. Dalton Trans., 2007, 4059.
|
| [28] |
Yan W M, Long J F, Fu Z Y, Rui F, Lian C, Chun H M. Inorg. Chem. Commun., 2012, 15: 25.
|
