Electrospinning preparation of β-cyclodextrin/glutaraldehyde crosslinked PVP nanofibrous membranes to adsorb dye in aqueous solution

Abstract

The insoluble β-cyclodextrin/glutaraldehyde crosslinked polyvinylpyrrolidone nanofibrous membranes were prepared by electrospinning technique. The membranes were extensively characterized by various techniques including attenuated total reflectance Fourier transform infrared spectroscopy(ATR-FTIR), X-ray diffraction(XRD), scanning electron microscopy(SEM) and UV-visible absorption to correlate membrane characteristics with their performance. The adsorption ability of the nanofibrous membranes was tested by performing extraction of Methyl orange(MO) dye in water. It was observed that β-cyclodextrin incorporated in polyvinylpyrrolidone provided the characteristics of high adsorption capacity of polyvinylpyrrolidone. Results of sorption experiments show that the nanofibrous membranes exhibited an adsorption rate of more than 95% for MO and the MO absorbent was 39.82 mg to per gram of β-cyclodextrin glutaraldehyde(β-CDXFM) crosslinked PVP under the optimized experimental conditions.

Keywords

β-Cyclodextrin / Glutaraldehyde / Polyvinylpyrrolidone / Adsorption / Nanofibrous membrane

References

[1] Crini G. Biores. Technol., 2006, 97: 1061.

[2] Pokhrel D, Viraraghavan T. Total Environ., 2004, 333: 37.

[3] Cao X W, Huang M L, Ding B, Yu J Y, Sun G. Desalination, 2013, 316: 120.

[4] Ding B, Wang M, Wang X, Yu J, Sun G. Mater. Today, 2010, 13: 16.

[5] Wang X, Ding B, Yu J, Wang M. Nano Today, 2011, 6: 510.

[6] Jiang H G, Yang Z J, Zhou X T, Fang Y X, Ji H B. Chin. J. Chem. Eng., 2012, 204: 784.

[7] Ozmen E Y, Sezgin M, Yilmaz A, Yilmaz M. Bioresource Technology, 2008, 99: 526.

[8] Szejtli J. J. Incl. Phenom. Macro., 2005, 52: 1.

[9] Cramer F, Dietsche W. Chem. Ber., 1959, 92: 378.

[10] Szejtli J. Pure Appl. Chem., 2004, 76: 1825.

[11] Breslow R. Adv. Chemother. Ser., 1980, 191: 1.

[12] Saenger W. Angew. Chem. Int. Ed., 1980, 19: 344.

[13] Szejtli J, Atwood J L, Davies J E D, Nicol D M. Inclusion Compounds, 1984, New York: Academic Press 331.

[14] Sybilska D, Zukowaik J, Krstulovic A M. Chiral Separation by HPLC, 1982, New York: Wiley.

[15] Kim G, Park J, Park S. J. Polym. Sci., Part B: Polym Phys, 2007, 45(15): 2038.

[16] Xu F, Cui F Z, Jiao Y P, Meng Q Y, Wang X P, Cui X Y. J. Mater. Sci. Mater. Med., 2009, 20(6): 1331.

[17] Bognitzki M, Frese T, Steinhart M, Greiner A, Wendorff J. Polym. Eng. Sci., 2001, 41(6): 982.

[18] Taina T, Helmut R. Macromolecules, 2010, 43(13): 5538.

[19] Yang Q, Li Z, Hong Y, Zhao Y, Qiu S, Wang C, Wei Y. J. Polym. Sci., Part B: Polym Phys, 2004, 42(20): 3721.

[20] McKay G. J. Chem. Tech. Biotechnol., 1982, 32: 759.

[21] Mendes L C, Rodrigues R C, Silva E P. Therm. Anal. Calorim., 2010, 101: 899.

[22] Singh K, Ingole P G, Bajaj H C, Hariom G. Desalination., 2012, 298: 13.

[23] Garg V K, Kumar R, Gupta R. Dyes Pigments, 2004, 62: 1.

[24] Crini G. Biores. Technol., 2003, 90: 193.

[25] Crini G. Dyes and Pigments, 2008, 77(2): 415.

[26] Díaz J E, Barrero A, Márquez M, Fernández-Nieves A, Loscertales I G. Rapid. Commun., 2010, 31: 183.

[27] Yilmaz E, Memon S, Yilmaz M. J. Hazard. Mater., 2010, 174: 592.

[28] Saeed K, Haider S, Oh T J, Park S Y. J. Membr. Sci., 2008, 322.

[29] Zhao D, Zhao L, Zhu C S, Shen X Y, Zhang X Z, Sha B F. J. Hazard. Mater., 2009, 171: 241.

[30] Deng S, Bai R, Chen J P. J. Colloid Interface Sci., 2003, 260.

[31] Pehlivan E, Altuna T, Parlayıcıa S. J. Hazard. Mater., 2009, 164: 982.

[32] He Z Y, Nie H L, White C B, Zhu L M, Zhou Y T, Zheng Y. Biores. Technol., 2008, 99: 7954.

[33] Hsu T C. J. Hazard. Mater., 2009, 171: 995.

[34] Mall I D, Srivatava V C, Agarwal N K. Dyes Pigm., 2006, 69: 210.