Investigation into experimental conditions and factors for cyclohexane oxidation with VO(acac)₂

Abstract

The catalytic activity of VO(acac)₂ for the cyclohexane(Cy) oxidation was studied. The effects of various parameters, such as the amounts of H₂O₂, HNO₃, H₂O and Cy were investigated. The highest total turnover number(TON) is 234, which can be increased to 353, 342 and 403, respectively with the adding of o-phthalic, m-phthalic or p-phthalic acid. A reaction mechanism was also supposed primarily.

Keywords

VO(acac)₂ / Cyclohexane oxidation / Mechanism / Phthalic acid / Additive

References

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