Synthesis, structures and properties of two complexes based on benzimidazole or benzothiazole ligand

Abstract

Two complexes, Co(Hbim)₂(NCS)₂(Hbim=benzimidazole)(1) and [Cu(Hbzt)SCN] _n(Hbzt=benzothiazole) (2) were synthesized by the same synthesis method and characterized by elemental analysis, infrared spectroscopy(IR), thermogravimetric analysis(TGA), X-ray powder diffraction(XRPD) and single-crystal X-ray diffraction. The results from the single-crystal X-ray diffraction indicate that complex 1 is zero-dimensional(0D) framework and complex 2 is 2-dimensional(2D) framework. In complex 2, the 3-dimensional(3D) supermolecular architecture was built up by means of π-π stacking interaction, and two helical chains existed in its structure. The luminescence properties and the magnetic properties of the two complexes were investigated.

Keywords

Chemical synthesis / Crystal structure / Luminescence property / Magnetic property

References

[1] Cheng J W, Zheng S T, Yang G Y. Inorg. Chem., 2007, 46: 10261.

[2] Gong Y, Tang W, Hou W B, Zha Z Y, Hu C W. Inorg. Chem., 2006, 45: 4987.

[3] Park K S, Ni Z, Coté A P, Choi J Y, Huang R D, Uribe-Romo F J, Chae H K, Keeffe M O’, Yaghi O M. PANS, 2006, 103: 10186.

[4] Tu T, Assenmacher W, Peterlik H, Weisbarth R, Nieger M, Dötz K H. Angew. Chem. Int. Ed., 2007, 46: 6368.

[5] Chuprakov S, Hwang F W, Gevorgyan V. Angew. Chem., 2007, 119: 4841.

[6] Lu H J, Li X G, Wang S R, Gao W Z, Wang S S. Chem. Res. Chinese Universities, 2012, 28(2): 313.

[7] Li C J, Feng Z J, Zhao X J, Wang S N, Dou J M. Chem. Res. Chinese Universities, 2013, 29(2): 414.

[8] Su C Y, Goforth A M, Smith M D, Loye H C. Inorg. Chem., 2003, 42: 5685.

[9] Matthews C J, Clegg W, Heath S L, Martin N C, Stuart H M N, Lockhart J C. Inorg. Chem., 1998, 37: 199.

[10] Rajesh, Mathur P. Polyhedron, 1998, 17: 2607.

[11] Quintal S, Matos J, Fonseca I, Félix V, Drew M G B, Trindade N, Meireles M, Calhorda M J. Inorg. Chem. Acta, 2008, 361: 1584.

[12] Yang X P, Jones R A, Lai R J, Waheed A, Oye M M, Holmes A L. Polyhedron, 2006, 25: 881.

[13] González-Álvarez M, Alzuet G, Borrás J, Agudo L C, García-Granda S, Montejo-Bernardo J M. Inorg. Chem., 2005, 44: 9424.

[14] Tzanopoulou S, Pirmettis I C, Patsis G, Raptopoulou C, Terzis A, Papadopoulos M, Pelecanou M. Inorg. Chem., 2006, 45: 902.

[15] Toth A, Floriani C, Chiesi-Villa A, Guastinil C. Inorg. Chem., 1987, 26: 3897.

[16] Yen S K, Koh L L, Hahn F E, Huynh H V, Andy H T S. Organometallics, 2006, 25: 5105.

[17] Huynh H V, Meier N, Pape T, Ekkehardt H F. Organometallics, 2006, 25: 3012.

[18] Huang X Y, Meng X G, Zhang Y, Wang L, Liu C L. Chem. J. Chinese Universities, 2012, 33(6): 1151.

[19] Chen Q, Chang Z, Song W C, Song H, Song H B, Hu T L, Bu X H. Angew. Chem. Int. Ed., 2013, 52: 11550.

[20] Sielisch T, Cowie M. Organometallics, 1988, 7: 707.

[21] Raper E S. Coord. Chem. Rev., 1997, 165: 475.

[22] Ballester L, Coronado E, Gutierrez A, Mange A, Perpifitin M F, Pinilla E, Rico T. Inorg. Chem., 1992, 31: 2053.

[23] Colacio E, Kivekãs R, Lloret F, Sunberg M. Inorg. Chem., 2002, 41: 5141.

[24] Chesnut D J, Kusnetzow A, Birge R, Zubieta J. Inorg. Chem., 1999, 38: 5484.

[25] Li C X, Zhang G H, Shih H H, Jiang X Q, Sun P, Pan Y, Cheng C H. J. Organomet. Chem., 2009, 694: 2415.

[26] Weaver J A, Hxmbright P, Talbeizt P T, Kaiyg E, Thorpe A N. Inorg. Chem., 1970, 9: 268.

[27] Tong Y P, Zheng S L, Chen X M. Inorg. Chem., 2005, 44: 4270.

[28] Shavaleev N M, Scopelliti R, Gumy F, Bunzli J C G. Inorg. Chem., 2009, 48: 6178.

[29] Payra P, Hung S C, Kwok W H, Johnston D, Gallucci J, Chan M K. Inorg. Chem., 2001, 40: 4036.

[30] Lescop C, Belorizky E, Luneau D, Rey P. Inorg. Chem., 2002, 41: 3375.

[31] Casella L, Carugo O, Gullotti M, Garofani S, Zanello P. Inorg. Chem., 1993, 32: 2056.

[32] Arjmand F, Mohani B, Ahmad S. Eur. J. Med. Chem., 2005, 40: 1103.

[33] Mohapatra S C, Tehlan S, Hundal M S, Mathur P. Inorg. Chem. Acta, 2008, 361: 1897.

[34] Tarte N H, Woo S I, Cui L Q, Gong Y D, Hwang Y H. J. Organomet. Chem., 2008, 693: 729.

[35] Li Y W, Li J R, Wang L F, Zhou B Y, Chen Q, Bu X H. J. Mater. Chem. A, 2013, 1: 495.

[36] Zhong C F, Guo R F, Wu Q, Zhang H L. React. Funct. Polym., 2007, 67: 408.

[37] Sheldrick G M. SMART and SAINT Software Package, 1996, Madison, WI: Siemens Analytical X-Ray Instruments Inc.

[38] Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, 1997, Göttingen: University of Göttingen.

[39] Wang X L, Hu H L, Tian A X, Lin H Y, Li J. Inorg. Chem., 2010, 49: 10299.

[40] Mandal T N, Roy S, Barik A K, Gupta S, Butcher R J, Kar S K. Inorg. Chem. Acta, 2009, 362: 1315.

[41] Gao H L, Yi L, Zhao B, Zhao X Q, Cheng P, Liao D Z, Yan S P. Inorg. Chem., 2006, 45: 5980.

[42] Wang X W, Chen F P, Chen L, Chen J Z, Jiang W J, Cai T J, Deng Q. J. Mol. Struct., 2007, 842: 75.

[43] Xia C K, Lu C Z, Zhang Q Z, He X, Zhang J J, Wu D M. Cryst. Growth Des., 2005, 5: 1569.