Structural characterization and luminescence properties of two 4d-4f Ln-Ag coordination compounds based on dinuclear lanthanide clusters

Abstract

Two new compounds, [ErAg(INA)₂(C₂O₄)]·2H₂O(1)(HINA=nicotinic acid) and [Tb_0.8Y_0.2Ag₂(IN)₄·(H₂O)₅]·NO₃·2H₂O(2)(HIN=isonicotinic acid), based on the {₂} building units, have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, infrared spectroscopy, thermal analysis and powder X-ray diffraction(PXRD). Single-crystal X-ray diffraction data reveal that both compounds crystallized in the low-symmetry triclinic space group P$\mathop {\rm{1}}\limits^{\rm{ - }} $. Compound 1 is a 3D heterometallic coordination framework based on {Er₂} clusters, oxalate ligands and bridging [Ag(INA)] linkers, while compound 2 consists of 0D [Tb_0.8·Y_0.2Ag₂(IN)₄(H₂O)₅]₂ subunits that give a 3D supramolecular structure through hydrogen bond interaction. The photoluminescent properties of both compounds(1 and 2) were studied.

Keywords

4d–4f Ln-Ag coordination compound / Doping / Hydrothermal synthesis / Crystal structure

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