Synthesis, structure and properties of two new coordination polymers based on 4-[(8-hydroxy-5-quinolinyl)azo]-benzenesulfonic acid

Abstract

Two new coordination polymers based on 4-[(8-hydroxy-5-quinolinyl)azo]-benzenesulfonic acid(H₂L), {[CdL(H₂O)₂]·H₂O} _n(1) and {[CdL(en)]·EtOH} _n(2)(en=ethylenediamine), were solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Compounds 1 and 2 exhibit infinite 1D ladder-shaped chain structures, which are isostructural except that the two coordinating water molecules in compound 1 were replaced by one en molecule in compound 2 due to the use of different organic base. Compounds 1 and 2 were constructed into different supramolecular frameworks by hydrogen bonding and π…π stacking interactions. In addition, the fluorescent properties of compounds 1 and 2 were investigated. Furthermore, they were also investigated via IR spectral analysis, elemental analysis, powder X-ray diffraction(PXRD) and thermogravimetric analysis(TGA).

Keywords

4-[(8-Hydroxy-5-quinolinyl)azo]-benzenesulfonic acid / Solvothermal synthesis / Coordination polymer / Fluorescent property

References

[1] Daniel M C, Astruc D. Chem. Rev., 2004, 104(1): 293.

[2] Kitagawa S, Kitaura R, Noro S. Angew. Chem. Int. Ed., 2004, 43: 2334.

[3] Eddaoudi M, Moler D B, Li H L, Chen B L, Reineke T M, O’Keeffe M, Yaghi O M. Acc. Chem. Res., 2001, 34(4): 319.

[4] Chen W, Su S Q, Song S Y, Song X Z, Zhang H J. Chem. J. Chinese Universities, 2012, 33(2): 215.

[5] Chun H, Kim D, Dybtsev D N, Kim K. Angew. Chem. Int. Ed., 2004, 43: 971.

[6] Kolotuchin S V, Fenlon E E, Wilson S R, Loweth C J, Zimmerman S C. Angew. Chem. Int. Ed., 1996, 34: 2654.

[7] Ma S Q, Zhou H C. J. Am. Chem. Soc., 2006, 128: 11734.

[8] Cairns A J, Perman J A, Wojtas L, Kravtsov V C, Alkordi M H, Eddaoudi M, Zaworotko M J. J. Am. Chem. Soc., 2008, 130: 1560.

[9] Evans O R, Lin W. Acc. Chem. Res., 2002, 35: 511.

[10] Moulton B, Zaworotko M J. Chem. Rev., 2001, 101: 1629.

[11] Long J R, Bloch E D, Britt D, Lee C, Donna C J, Uribe-Romo F J, Furukawa H, Yaghi O M. J. Am. Chem. Soc., 2010, 132: 14382.

[12] Chen Z F, Xiong R G, Abrahams B F, You X Z, Che C M. J. Chem. Soc. Dalton Trans., 2001, 17: 2453.

[13] Reineke T M, Eddaoudi M, Moler D B, O’Keeffe M, Yaghi O M. J. Am. Chem. Soc., 2000, 122: 4843.

[14] Chen Z F, Zhang Z L, Tan Y H, Tang Y Z, Fun H K, Zhou Z Y, Abrahams B F, Liang H. CrystEngComm, 2008, 10: 217.

[15] Park J S, Jeong S, Dho S K, Lee M G, Song C K. Dyes Pigm., 2010, 87: 49.

[16] Aytül S, Zeynel S, Nermin E. Dyes Pigm., 2008, 76(2): 470.

[17] Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structure, 1997, Göttingen: University of Göttingen.

[18] Dolomanov O V, Bourhis L J, Gildea R J, Howard J A K, Puschmann H. J. Appl. Cryst., 2009, 42: 339.

[19] Shi X, Zhu G S, Wang X H, Li G H, Fang Q R, Wu G, Tian G, Xu M, Zhao X J, Wang R W, Qiu S L. Cryst. Growth Des., 2005, 5(1): 341.

[20] Spek A L. PLATON, A Multipurpose Crystallographic Tool, 2006, Utrecht: Utrecht University.

[21] Yu X Y, Ye L, Zhang X, Cui X B, Zhang J P, Xu J Q, Hou Q, Wang T G. Dalton Trans., 2010, 39(44): 10617.

[22] Lan A J, Padmanabhan M, Li K H, Wu H H, Emge T J, Hong M C, Li J. Inorg. Chim. Acta, 2011, 366: 68.

[23] Tao J, Tong M L, Shi J X, Chen X M, Ng S W. Chem. Commun., 2000, 2043.

[24] Qi Y, Che Y X, Zheng J M. CrystEngComm, 2008, 10: 1137.

[25] Wei K J, Xie Y S, Ni J, Zhang M, Liu Q L. Cryst. Growth Des., 2006, 6(6): 1341.