Synthesis, structure and fluorescent property of coordination polymer from 4-[(8-hydroxy-5-quinolinyl)azo]-benzoic acid

Abstract

One new coordination polymer based on 4-[(8-hydroxy-5-quinolinyl)azo]-benzoic acid(H₂L), {[CdL(H₂O)]·H₂O}n (1) was solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction, infrared spectrometry, elemental analysis, powder X-ray diffraction(PXRD) and thermogravimetric analysis (TGA). In compound 1, L²⁻ ligands link Cd(II) to form a sinusoidal ruffling layer, in which the carboxylic groups connect Cd(II) into an infinite Cd—O chain. And the layers are further stabilized by hydrogen bonding and π…π interactions, forming a three-dimensional(3D) supramolecular network. In addition, the fluorescent property of compound 1 was also investigated.

Keywords

Three-dimensional supramolecular network / 4-[(8-Hydroxy-5-quinolinyl)azo]-benzoic acid / Fluorescent property

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