Synthesis, structures, fluorescence and magnetism of two lanthanide metal-organic frameworks with CaF₂ topology based on silicon-centered tetrahedral ligand

Abstract

Two 3D multifunctional lanthanide metal-organic frameworks(MOFs), Pr(HTCPS)(H₂O)·2DMF·C₂H₅OH·5H₂O(JUC-93) and Pr₃(TCPS)₂(NO₃)(H₂O)₄(DMA)₂·2DMA·C₂H₅OH·3H₂O(JUC-94)[H₄TCPS=tetrakis(4-carboxyphenyl)silane, DMF=N,N′-dimethylformamide, DMA=N,N′-dimethylacetamide and JUC=Jilin University China] were synthesized by the self-assembly of a rigid silicon-centered tetrahedral carboxylate ligand H₄TCPS and Pr(III) ions in different solvothermal reactions. X-Ray crystallography revealed that they exhibited a rare CaF₂ topology framework, constructed from the 4-connected tetrahedral TCPS unit with the 8-connected dinuclear praseodymium cluster unit and trinuclear praseodymium cluster unit, respectively. In addition, the luminescent and magnetic properties of the two compounds were investigated.

Keywords

Metal-organic framework / Tetrakis(4-carboxyphenyl)silane / CaF₂ topology / Magnetic property / Fluorescence

References

[1] Jin R Z, Bian Z, He Y B, Gao L X. Chem. Res. Chinese Universities, 2010, 26(6): 857.

[2] Cui Y, Yue Y, Qian G, Chen B. Chem. Rev., 2012, 112: 1126.

[3] Deng H, Doonan C J, Furukawa H, Ferreira R B, Towne J, Knobler C B, Wang B, Yaghi O M. Science, 2010, 327: 846.

[4] Qu X J, Wang S, Zhang D J, Jing X M, Zhang L R, Li G H, Huo Q S, Liu Y L. Chem. Res. Chinese Universities, 2012, 28(4): 581.

[5] Lin S W, Wu Q, Wang E B. Chem. Res. Chinese Universities, 2012, 28(3): 375.

[6] Wang J, Liu Z Q, Su T T. Chem. Res. Chinese Universities, 2011, 27(3): 354.

[7] Zhang J P, Kitagawa S. J. Am. Chem. Soc., 2008, 130: 907.

[8] Klein N, Senkovska I, Baburin I A, Grünker R, Stoeck U, Schlichtenmayer M, Streppel B, Mueller U, Leoni S, Hirscher M, Kaskel S. Chem. Eur. J., 2011, 17: 13007.

[9] Wang Z, Kravtsov V C, Zaworotko M J. Angew. Chem. Int. Ed., 2005, 44: 2877.

[10] Chen W, Su S Q, Song S Y, Song X Z, Zhang H J. Chem. J. Chinese Universities, 2012, 33(2): 215.

[11] Hu K Q, Kou H Z. Chem. J. Chinese Universities, 2012, 33(5): 892.

[12] Chen W X, Wu G H, Zhuang G L, Kong X J, Long L S, Huang R B, Zheng L S. Chem. J. Chinese Universities, 2011, 32(3): 519.

[13] Zhang Y B, Zhou H L, Lin R B, Zhang C, Lin J B, Zhang J P, Chen X M. Nat. Commun., 2011, 3: 642.

[14] Zheng S T, Wu T, Chou C, Fuhr A, Feng P, Bu X. J. Am. Chem. Soc., 2012, 134: 4517.

[15] Zheng S T, Bu J J, Wu T, Chou C, Feng P, Bu X. Angew. Chem. Int. Ed., 2011, 50: 8858.

[16] Becerril J, Hamilton A D. Angew. Chem. Int. Ed., 2007, 46: 4471.

[17] Wang X L, Li Y G, Lu Y, Fu H, Su Z M, Wang E B. Cryst. Growth Des., 2010, 10: 4227.

[18] Chen B, Eddaoudi M, Reineke T M, Kampf J W, O’Keeffe M, Yaghi O M. J. Am. Chem. Soc., 2000, 122: 11559.

[19] Xue M, Zhu G, Li Y, Zhao X, Jin Z, Kang E, Qiu S. Cryst. Growth Des., 2008, 8: 2478.

[20] Rosi N L, Eddaoudi M, Kim J, O’Keeffe M, Yaghi O M. Angew. Chem. Int. Ed., 2002, 41: 284.

[21] Férey G, Mellot-Draznieks C, Serre C, Millange F, Dutour J, Surblé S, Margiolaki I. Science, 2005, 309: 2040.

[22] Sahoo S C, Kundu T, Banerjee R. J. Am. Chem. Soc., 2011, 133: 17950.

[23] Fang Q, Zhu G, Xue M, Sun J, Wei Y, Qiu S, Xu R. Angew. Chem. Int. Ed., 2005, 44: 3845.

[24] Wang S, Yun R, Peng Y, Zhang Q, Lu J, Dou J, Bai J, Li D, Wang D. Cryst. Growth Des., 2012, 12: 79.

[25] Zhao J P, Hu B W, Yang Q, Hu T L, Bu X H. Inorg. Chem., 2009, 48: 7111.

[26] Tan C K, Wang J, Leng J D, Zheng L L, Tong M L. Eur. J. Inorg. Chem., 2008, 2008: 771.

[27] Zhang X M, Fang R Q, Wu H S. J. Am. Chem. Soc., 2005, 127: 7670.

[28] Lo S M F, Chui S S Y, Shek L Y, Lin Z, Zhang X X, Wen G H, Williams I D. J. Am. Chem. Soc., 2000, 122: 6293.

[29] Long D L, Hill R J, Blake A J, Champness N R, Hubberstey P, Proserpio D M, Wilson C, Schröder M. Angew. Chem. Int. Ed., 2004, 43: 1851.

[30] Xue M, Zhang J, Xiang S C, Jin Z, Liang C D, Zhu G S, Qiu S L, Chen B L. J. Mater. Chem., 2010, 20: 3984.

[31] Yang X P, Jones R A, Rivers J H, Lai R P J. Dalton Trans., 2007, 3936.

[32] Feng X, Wang L Y, Zhao J S, Wang J G, Weng N S, Liu B, Shi X G. CrystEngComm, 2010, 12: 774.

[33] Jiang H L, Tsumori N, Xu Q. Inorg. Chem., 2010, 49: 10001.

[34] Bürgstein M R, Roesky P W. Angew. Chem. Int. Ed., 2000, 39: 549.

[35] Zhang Z H, Wan S Y, Okamura T A, Sun W Y, Ueyama N. Z. Anorg. Allg. Chem., 2006, 632: 679.

[36] Cañadillas-Delgado L, Fabelo O, Pasán J, Delgado F S, Déniz M, Sepúlveda E, Laz M M, Julve M, Ruiz-Pérez C. Cryst. Growth Des., 2008, 8: 1313.

[37] Deng Z P, Huo L H, Wang H Y, Gao S, Zhao H. CrystEngComm, 2010, 12: 1526.

[38] Gustafsson M, Bartoszewicz A, Martín-Matute B N, Sun J, Grins J, Zhao T, Li Z, Zhu G, Zou X. Chem. Mater., 2010, 22: 3316.

[39] Chen B, Yang Y, Zapata F, Lin G, Qian G, Lobkovsky E B. Adv. Mater., 2007, 19: 1693.

[40] Ma S, Wang X S, Yuan D, Zhou H C. Angew. Chem. Int. Ed., 2008, 47: 4130.

[41] Ma S, Yuan D, Wang X S, Zhou H C. Inorg. Chem., 2009, 48: 2072.

[42] Ben T, Pei C, Zhang D, Xu J, Deng F, Jing X, Qiu S. Energy Environ. Sci., 2011, 4: 3991.

[43] Lambert J B, Liu Z, Liu C. Organometallics, 2008, 27: 1464.

[44] Davies R P, Less R, Lickiss P D, Robertson K, White A J P. Cryst. Growth Des., 2010, 10: 4571.

[45] Davies R P, Less R J, Lickiss P D, Robertson K, White A J P. Inorg. Chem., 2008, 47: 9958.

[46] Davies R P, Lickiss P D, Robertson K, White A J P. CrystEng- Comm, 2012, 14: 758.

[47] Davies R P, Lickiss P D, Robertson K, White A J P. Aust. J. Chem., 2011, 64: 1239.

[48] Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, 1997, Göttingen, Germany: University of Göttingen.

[49] Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, 1997, Göttingen, Germany: University of Göttingen.

[50] Spek A L. J. Appl. Crystallogr., 2003, 36: 7.

[51] van der Sluis P, Spek A L. Acta Crystallogr., Sect. A: Found., 1990, 46: 194.

[52] Michaelides A, Skoulika S, Bakalbassis E G, Mrozinski J. Cryst. Growth Des., 2003, 3: 487.

[53] Yan B, Zhang H, Wang S, Ni J. Mater. Res. Bull., 1998, 33: 1517.

[54] Dai J C, Wu X T, Fu Z Y, Cui C P, Hu S M, Du W X, Wu L M, Zhang H H, Sun R Q. Inorg. Chem., 2002, 41: 1391.

[55] Kahn M L, Sutter J P, Golhen S, Guionneau P, Ouahab L, Kahn O, Chasseau D. J. Am. Chem. Soc., 2000, 122: 3413.