Syntheses and supramolecular structures of two nickel(II) compounds based on two thiosemicarbazone ligands

Abstract

Two new compounds, [Ni₂(L¹)(Py)₆]Py·CH₃OH(1) and [Ni₃(L²)₂(Py)₄]·2DMF(2)(H₄L¹=N,N′-bisalicyl-bisthiocarbamide; H₃L²=3-hydroxyl-2-naphthalene thiosemicarbazide; Py=pyridine; DMF=dimethyl fumarate), based upon two thiosemicarbazone ligands have been obtained and characterized by elemental analysis, Fourier transform infrared(FTIR) and X-ray diffraction(XRD). Compound 1 possesses a binuclear cluster, in which the bisalicylbisthiocarbamide acts as a hexadentate bridge. Compound 2 exhibits a linear trinuclear cluster with the triply-deprotonated ligand acting as pentadentate bridge. C—H…O, C—H…π and C—H…S weak interactions further link these molecules to form interesting supramolecular networks.

Keywords

Thiosemicarbazone ligand / Weak interaction / Supramolecular framework

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