Aldol reactions catalyzed by proline functionalized polyacrylonitrile fiber

Abstract

A proline functionalized fiber catalyst was employed for aldol reactions in water. In the presence of the fiber catalyst, the aldol reactions proceeded smoothly at 40 °C and the products were obtained in excellent yields which were higher than those obtained for the reactions catalyzed by L-proline or trans-4-hydroxy-L-proline. This newly developed fiber catalyst is applicable to the reactions of a wide range of aromatic aldehydes and exhibits excellent reusability(up to 6 times) without any additional treatment.

Keywords

Polyacrylonitrile fiber(PANF) / Proline / Aldol reaction / Supported catalyst

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