In-Situ Exsolved Metal Nanoparticles for Solid Oxide Fuel Cell Anode: Mechanism, Design Strategies and Application

Xiongzhuang Li , Xinwei Su , Qiao Yuan , Mengting Wang , Wei Kong , Shanliang Chen , Petr Senin , Daifen Chen , Ting Chen , Tao Wei

Chinese Journal of Chemistry ›› 2025, Vol. 43 ›› Issue (14) : 1707 -1730.

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Chinese Journal of Chemistry ›› 2025, Vol. 43 ›› Issue (14) : 1707 -1730. DOI: 10.1002/cjoc.70003
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In-Situ Exsolved Metal Nanoparticles for Solid Oxide Fuel Cell Anode: Mechanism, Design Strategies and Application

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Abstract

Solid oxide fuel cell (SOFC) is recognized as the third-generation fuel cell which transforms the chemical energy of different fuels directly into electrical energy with highly efficient. However, the sulfur poisoning and carbon deposition at high temperatures at the anode side hindered its commercialization. Using perovskite anodes combined with the in-situ exsolution (ISE) method has been extensively developed aimed at alleviating the above problems. This review is trying to depict a systematic overview of the mechanism of the ISE process, the strategies for designing ISE, and its application in SOFC anodes. We hope that this work could give a comprehensive understanding of future anodes for SOFC.

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Solid oxide fuel cell (SOFC) / In-situ exsolution / Perovskite / Anodes / Carbon deposition / Metal nanoparticles / Supported catalysts / Nanotechnology

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Xiongzhuang Li, Xinwei Su, Qiao Yuan, Mengting Wang, Wei Kong, Shanliang Chen, Petr Senin, Daifen Chen, Ting Chen, Tao Wei. In-Situ Exsolved Metal Nanoparticles for Solid Oxide Fuel Cell Anode: Mechanism, Design Strategies and Application. Chinese Journal of Chemistry, 2025, 43(14): 1707-1730 DOI:10.1002/cjoc.70003

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