Nickel(II)-Catalyzed Reductive Coupling of Xanthate Esters with Sulfur-Containing and Selenium-Containing Compounds: Synthesis of Unsymmetric Sulfides and Selenides
Jia-Hui Han , Daopeng Sheng , Yi-Rong Chen , Xiao-Yue Shuai , Weidong Rao , Shu-Su Shen , Shun-Yi Wang
Chinese Journal of Chemistry ›› 2024, Vol. 42 ›› Issue (20) : 2453 -2458.
Nickel(II)-Catalyzed Reductive Coupling of Xanthate Esters with Sulfur-Containing and Selenium-Containing Compounds: Synthesis of Unsymmetric Sulfides and Selenides
Unsymmetric sulfides and selenides have great applications in the pharmaceutical field. Herein, we describe the reductive coupling reaction of xanthate esters with sulfur-containing and selenium-containing compounds (thio(seleno)sulfonates and disulfides(selenides)) under the nickel-catalyzed condition. It provides a mild and effective method for the synthesis of unsymmetric sulfides and selenides which has the advantages of mild reaction conditions, high yields and a wide range of substrates.
Sulfur-containing and selenium-containing compounds / Sulfides and selenides / Xanthate esters / Nickel / Radical / Synthetic methods
2024 SIOC, CAS, Shanghai, & WILEY-VCH GmbH
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