Asymmetric Carbon Nanotube Yarns for Electrochemical and Mechanical Balance in Artificial Muscle Fascicle

Jae Sang Hyeon , Gyu Hyeon Song , Jieun Sim , Jinyeong Choi , Ji In Choi , Youngjin Jeong , Seon Jeong Kim

Advanced Fiber Materials ›› : 1 -10.

PDF
Advanced Fiber Materials ›› :1 -10. DOI: 10.1007/s42765-026-00705-2
Research Article
research-article
Asymmetric Carbon Nanotube Yarns for Electrochemical and Mechanical Balance in Artificial Muscle Fascicle
Author information +
History +
PDF

Abstract

Artificial muscle fascicles that mimic the hierarchical structure of biological muscles are essential for translating the high performance of individual artificial muscles into scalable soft robotics applications. However, in electrochemical artificial muscles, the muscle fascicles that consist of anodic and cathodic muscles have asymmetric actuation due to electrochemical imbalance between the anodic and cathodic sides, including voltage, capacitance, and ion volume. This imbalance reduces the overall actuation of muscle fascicles and poses a challenge for soft robot design. We here demonstrate an asymmetric configuration for carbon nanotube (CNT) artificial muscles to resolve both the electrochemical imbalances and the subsequent mechanical imbalance. The ratio of cathodic-to-anodic muscles in the fascicles was tuned to achieve electrochemical balance, and the spring index of the coiled structure was adjusted to match the mechanical modulus between the muscles. This asymmetric strategy was further extended to multiplied structures, forming the basis of artificial muscle fascicles with improved performance. These results provide a scalable strategy for translating high-performance individual CNT artificial muscles into efficient and powerful artificial muscle fascicles for future soft robotic systems.

Graphical abstract

Keywords

Fiber-type actuators / Artificial muscle fascicles / Carbon nanotubes / Electrochemistry / Asymmetric configuration

Cite this article

Download citation ▾
Jae Sang Hyeon, Gyu Hyeon Song, Jieun Sim, Jinyeong Choi, Ji In Choi, Youngjin Jeong, Seon Jeong Kim. Asymmetric Carbon Nanotube Yarns for Electrochemical and Mechanical Balance in Artificial Muscle Fascicle. Advanced Fiber Materials 1-10 DOI:10.1007/s42765-026-00705-2

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

Hu H, Zhang S, Zhang M, Xu J, Salim T, Li Y, Hu X, Zhang Z, Cheng G, Yuan N, Lam YM, Ding J. Artificial muscles based on coiled conductive polymer yarns. Adv Funct Mater. 2024, 342401685.

[2]

Haines CS, Lima MD, Li N, Spinks GM, Foroughi J, Madden JDW, Kim SH, Fang S, de Andrade MJ, Göktepe F, Göktepe Ö, Mirvakili SM, Naficy S, Lepró X, Oh J, Kozlov ME, Kim SJ, Xu X, Swedlove BJ, Wallace GG, Baughman RH. Artificial muscles from fishing line and sewing thread. Science. 2014, 343868.

[3]

Zhang M, Fang S, Cai W, Hu C, Göktepe F, Oh J, Wang Z, Ekanayake I, Göktepe Ö, Baughman RH. Mandrel-free fabrication of giant spring-index and stroke muscles for diverse applications. Science. 2025, 3871101.

[4]

Combe A, Chen S, Pacella G, Stuart MCA, de Boer JY, Portale G, Feringa BL. Photoactuating artificial muscle from supramolecular assembly of an overcrowded alkene-derived molecular switch. Nat Commun. 2025, 163897.

[5]

Madani Z, Silva PES, Baniasadi H, Vaara M, Das S, Arias JC, Seppälä J, Sun Z, Vapaavuori J. Light-driven multidirectional bending in artificial muscles. Adv Mater. 2024, 362405917.

[6]

Wang YZ, Wang YC, Liu TT, Zhao QL, Li CS, Cao MS. Nano-organic r-GO-hybrid microwave absorber for electromagnetic–thermal–mechanical coupled response and self-adaptive electromagnetic devices. Adv Funct Mater. 2025, 352500368.

[7]

Wang YC, Wang YZ, Shu JC, Cao WQ, Li CS, Cao MS. Graphene implanted shape memory polymers with dielectric gene dominated highly efficient microwave drive. Adv Funct Mater. 2023, 332303560.

[8]

Yan D, Luo J, Wang S, Han X, Lei X, Jiao K, Wu X, Qian L, Zhang X, Zhao X, Di J, Zhang Z, Gao Z, Zhang J. Carbon nanotube-directed 7 GPa heterocyclic aramid fiber and its application in artificial muscles. Adv Mater. 2024, 362306129.

[9]

Ejehi F, Vafaiee M, Bavi O, Mahmoudi Maymand V, Asadian E, Mohammadpour R. Asymmetric flexible graphene oxide papers for moisture-driven actuators and water level indicators. Alex Eng J. 2024, 107406.

[10]

Foroughi J, Spinks GM, Wallace GG, Oh J, Kozlov ME, Fang S, Mirfakhrai T, Madden JDW, Shin MK, Kim SJ, Baughman RH. Torsional carbon nanotube artificial muscles. Science. 2011, 334494.

[11]

Lima MD, Li N, de Andrade MJ, Fang S, Oh J, Spinks GM, Kozlov ME, Haines CS, Suh D, Foroughi J, Kim SJ, Chen Y, Ware T, Shin MK, Machado LD, Fonseca AF, Madden JDW, Voit WE, Galvão DS, Baughman RH. Electrically, chemically, and photonically powered torsional and tensile actuation of hybrid carbon nanotube yarn muscles. Science. 2012, 338. 928

[12]

Mu J, de Andrade MJ, Fang S, Wang X, Gao E, Li N, Kim SH, Wang H, Hou C, Zhang Q, Zhu M, Qian D, Lu H, Kongahage D, Talebian S, Foroughi J, Spinks G, Kim H, Ware TH, Sim HJ, Lee DY, Jang Y, Kim SJ, Baughman RH. Sheath-run artificial muscles. Science. 2019, 365. 150

[13]

Chu H, Hu X, Wang Z, Mu J, Li N, Zhou X, Fang S, Haines CS, Park JW, Qin S, Yuan N, Xu J, Tawfick S, Kim H, Conlin P, Cho M, Cho K, Oh J, Nielsen S, Alberto KA, Razal JM, Foroughi J, Spinks GM, Kim SJ, Ding J, Leng J, Baughman RH. Unipolar stroke, electroosmotic pump carbon nanotube yarn muscles. Science. 2021, 371. 494

[14]

Kim MS, Lee HS, Cho Y, Heo JK, Quan YJ, Lee SW, Pahk HJ, Ahn SH. Surface nanopatterned shape memory alloy (SMA)-based photosensitive artificial muscle. Adv Opt Mater. 2022, 10. 2102024

[15]

Kalashnikov N, Moraes C. Morphodynamic tissues via integrated programmable shape memory actuators. Adv Funct Mater. 2019, 29. 1903327

[16]

Niu D, Li D, Chen J, Zhang M, Lei B, Jiang W, Chen J, Liu H. SMA-based soft actuators with electrically responsive and photoresponsive deformations applied in soft robots. Sens Actuators A Phys. 2022, 341. 113516

[17]

Sun G, Zuo S, Xu W, Wang J, Wang Z, Kong H, Khedr M, Xiao F. Recovery stress control and prediction in NiTi shape memory alloy wires under electrical actuation. Sens Actuators A Phys. 2025, 394. 116970

[18]

Wang J, Huang B, Gu X, Zhu J, Zhang W. Actuation performance of machined helical springs from NiTi shape memory alloy. Int J Mech Sci. 2022, 236. 107744

[19]

Lee JA, Li N, Haines CS, Kim KJ, Lepró X, Ovalle-Robles R, Kim SJ, Baughman RH. Electrochemically powered, energy-conserving carbon nanotube artificial muscles. Adv Mater. 2017, 29. 1700870

[20]

Kim KJ, Hyeon JS, Kim H, Mun TJ, Haines CS, Li N, Baughman RH, Kim SJ. Enhancing the work capacity of electrochemical artificial muscles by coiling plies of twist-released carbon nanotube yarns. ACS Appl Mater Interfaces. 2019, 11. 13533

[21]

Wang Y, Qiao J, Wu K, Yang W, Ren M, Dong L, Zhou Y, Wu Y, Wang X, Yong Z, Di J, Li Q. High-twist-pervaded electrochemical yarn muscles with ultralarge and fast contractile actuations. Mater Horiz. 2020, 7. 3043

[22]

Wang X, Wang Y, Ren M, Dong L, Zhou T, Yang G, Yang H, Zhao Y, Cui B, Li Y, Li W, Yuan X, Qiao G, Wu Y, Wang X, Xu P, Di J. Knittable electrochemical yarn muscle for morphing textiles. ACS Nano. 2024, 18. 9500

[23]

Jin Y, Jeon EJ, Jeong S, Min S, Choi YS, Kim SH, Lee JS, Shin J, Yu JH, Ahn DH, Kim YG. Reconstruction of muscle fascicle‐like tissues by anisotropic 3d patterning. Adv Funct Mater. 2021, 31. 2006227

[24]

Hyeon JS, Kim KW, Song GH, Li T, Sim HJ, Kim SJ. Force sensing of carbon nanotube artificial muscles based on electrochemical double layer. Sens Actuators B Chem. 2025, 442. 138109

[25]

Wu H, Li C, Wang Y, Wang Z, Peng Y, Wei Z, Wang H. Perception, interaction, and positioning. Adv Intell Syst. 2025, 7. 2400412

[26]

Dong L, Ren M, Wang Y, Qiao J, Wu Y, He J, Wei X, Di J, Li Q. Self-sensing coaxial muscle fibers with bi-lengthwise actuation. Mater Horiz. 2021, 8. 2541

[27]

Wang YZ, Wang YC, Liu TT, Zhao QL, Li CS, Cao MS. MXene hybridized polymer with enhanced electromagnetic energy harvest for sensitized microwave actuation and self-powered motion sensing. Nano-Micro Lett. 2025, 17. 65

[28]

Shao Q, Zhou L, Zhou J, Liu XJ, Zhao H. Long, fibrous, and tailorable dielectric elastomer artificial muscles via mask-free stamping of carbon nanotube electrodes. Adv Funct Mater. 2025, 35. 2422905

[29]

Cho J, Lee M, Park T, Wang Y, Lee H, Cai S, Park YL. Bio-inspired artificial muscle-tendon complex of liquid crystal elastomer for bidirectional afferent-efferent signaling. Adv Mater. 2026, 38. e03094

[30]

Qiao J, Di J, Zhou S, Jin K, Zeng S, Li N, Fang S, Song Y, Li M, Baughman RH, Li Q. Large-stroke electrochemical carbon nanotube/graphene hybrid yarn muscles. Small. 2018, 14. 1801883

[31]

Ren M, Dong L, Wang X, Li Y, Zhao Y, Cui B, Yang G, Li W, Yuan X, Zhou T, Xu P, Wang X, Di J, Li Q. Dual-ion co-regulation system enabling high-performance electrochemical artificial yarn muscles with energy-free catch states. Nano-Micro Lett. 2023, 15. 162

[32]

Mazar FM, Martinez JG, Tyagi M, Alijanianzadeh M, Turner APF, Jager EWH. Artificial muscles powered by glucose. Adv Mater. 2019, 31. 1901677

[33]

Park JW, Song GH, Hyeon JS, Wang Z, Baughman RH, Kim SJ. Zinc-air powered carbon nanotube yarn artificial muscle. Sens Actuators B Chem. 2025, 431. 137447

[34]

Wang T, Zhang Y, Li B, Hu Y, Aabloo A, Chang L. Electrical-modulated flexible acoustic metamaterial: enhancing low-frequency absorption via an ionic electroactive polymer. ACS Appl Mater Interfaces. 2024, 16. 51433

[35]

Liu L, Wang C, Wu Z, Xing Y. Ultralow-voltage-drivable artificial muscles based on a 3D structure MXene-PEDOT:PSS/AgNWs electrode. ACS Appl Mater Interfaces. 2022, 14. 18150

[36]

Hyeon JS, Park JW, Baughman RH, Kim SJ. Electrochemical graphene/carbon nanotube yarn artificial muscles. Sens Actuators B Chem. 2019, 286. 237

[37]

Park CL, Goh B, Kim KJ, Oh S, Suh D, Song YC, Kim H, Kim ES, Lee H, Lee DW, Choi J, Kim SH. Synergistic actuation performance of artificial fern muscle with a double nanocarbon structure. Mater Today Adv. 2024, 21. 100459

[38]

Ni B, Gelas L, Ananieva G, Vancaeyzeele C, Nguyen GTM, Vidal F, Plesse C. Artificial muscle based on coiled CNT yarns and biofriendly ionogels. Sens Actuators B Chem. 2024, 403. 135227

[39]

Wang Y, Zhao Y, Ren M, Zhou Y, Dong L, Wei X, He J, Cui B, Wang X, Xu P, Di J, Li Q. Artificial muscle fascicles integrated with high-performance actuation properties and energy-storage function. Nano Energy. 2022, 102. 107609

[40]

Hyeon JS, Wang Q, Tawfick S, Lee J, Smith KC, Zhang M, Park JW, Song GH, Wang Z, Fang S, Baughman RH, Kim SJ. Improving energy conversion efficiency of ion-driven artificial muscles based on carbon nanotube yarn. J Power Sources. 2025, 646. 237234

[41]

Ren M, Qiao J, Wang Y, Wu K, Dong L, Shen X, Zhang H, Yang W, Wu Y, Yong Z, Chen W, Zhang Y, Di J, Li Q. Strong and robust electrochemical artificial muscles by ionic-liquid-in-nanofiber-sheathed carbon nanotube yarns. Small. 2021, 17. 2006181

[42]

Ananieva G, Vancaeyzeele C, Nguyen GTM, Aguilera-Bulla D, Pinault M, Vidal F, Plesse C. Bio-friendly artificial muscles based on carbon nanotube yarns and eutectogel derivatives. Adv Funct Mater. 2026, 36. e15458

[43]

Spinks GM, Bakarich SE, Aziz S, Salahuddin B, Xin H. Using force-displacement relations to obtain actuation parameters from artificial muscles. Sens Actuators A Phys. 2019, 290. 90

[44]

Song J, Kim S, Yoon S, Cho D, Jeong Y. Enhanced spinnability of carbon nanotube fibers by surfactant addition. Fibers Polym. 2014, 15. 762

[45]

Oh S, Kim KJ, Goh B, Park CL, Lee GD, Shin S, Lim S, Kim ES, Yoon KR, Choi C, Kim H, Suh D, Choi J, Kim SH. Chemo-mechanical energy harvesters with enhanced intrinsic electrochemical capacitance in carbon nanotube yarns. Adv Sci. 2022, 9. 2203767

[46]

Song GH, Lee DY, Gwak H, Moon JH, Hyeon JS, Choi J, Kim H, Jeong Y, Choi C, Kim SJ. Asymmetric mechano‐electrochemical energy harvesting system with surface charge–modified carbon nanotube yarn for wearable devices. Small. 2025, 21. e08487

Funding

Ministry of Science and ICT, South Korea(RS-2024–00406534)

RIGHTS & PERMISSIONS

Donghua University, Shanghai, China

PDF

0

Accesses

0

Citation

Detail

Sections
Recommended

/