Liquid Metal and Silver Nanowires Synergic Network-Enabled Triboelectric Fiber for Strain-Insensitive Multifunctional Applications

Huiyun Zhang , Yuqi Chen , Shengxin Xiang , Xiao Wei , Lei Liu , Xinkai Xie , Yuan Ren , Qiongfeng Shi , Chengkuo Lee , Jun Wu

Advanced Fiber Materials ›› : 1 -17.

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Advanced Fiber Materials ›› :1 -17. DOI: 10.1007/s42765-025-00634-6
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Liquid Metal and Silver Nanowires Synergic Network-Enabled Triboelectric Fiber for Strain-Insensitive Multifunctional Applications

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Abstract

Fibrous triboelectric devices with self-powered sensing capability receive tremendous attention in wearable applications, yet are still facing dual challenges of instable electrode conductivity and limited triboelectric charge density in practical application scenarios. Here, a multifunctional triboelectric fiber with ultra-high strain insensitivity and great sensitivity is proposed through a liquid metal (LM)–silver nanowires (Ag NWs) synergic network strategy. On the one hand, the three-dimensional conductive network formed by Ag NWs bridging LM microdroplets effectively addresses the issue of resistance fluctuations in traditional fibrous electrodes under large deformations, exhibiting exceptionally high conductivity of up to 1.07 × 105S/m when stretched to 740%. Notably, Ag NWs-induced stress concentration, coupled with driven capillary action, can easily induce the rupture of the oxide layer on the LM surface under low stress and simplify the activation process inherent to classic LM-based electrodes. On the other hand, by utilizing the charge-trapping effect and dielectric optimization design induced by LM and Ag NWs doping, the triboelectric output is significantly enhanced with high sensitivity and linearity. Benefiting from its excellent stretchability, conductivity, and triboelectric output performance, the triboelectric fiber can then be applied for strain-insensitive multifunctional applications, including building a smart glove for virtual interaction, kinetic energy harvesting, Joule heating, and electromagnetic interference (EMI) shielding, opening up a new path for next-generation smart textiles.

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Keywords

Triboelectric fibers / Multifunctionality / Liquid metal / Silver nanowires / Strain insensitive

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Huiyun Zhang, Yuqi Chen, Shengxin Xiang, Xiao Wei, Lei Liu, Xinkai Xie, Yuan Ren, Qiongfeng Shi, Chengkuo Lee, Jun Wu. Liquid Metal and Silver Nanowires Synergic Network-Enabled Triboelectric Fiber for Strain-Insensitive Multifunctional Applications. Advanced Fiber Materials 1-17 DOI:10.1007/s42765-025-00634-6

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References

[1]

Luo Y, Abidian MR, Ahn J-H, Akinwande D, Andrews AM, Antonietti M, et al. . Technology roadmap for flexible sensors. ACS Nano, 2023, 17: 5211

[2]

Ates HC, Nguyen PQ, Gonzalez-Macia L, Morales-Narváez E, Güder F, Collins JJ, et al. . End-to-end design of wearable sensors. Nat Rev Mater, 2022, 7: 887

[3]

Zhang H, Hong J, Zhu J, Duan S, Xia M, Chen J, et al. . Humanoid electronic-skin technology for the era of artificial intelligence of things. Matter, 2025, 8102136

[4]

Wen D-L, Pang Y-X, Huang P, Wang Y-L, Zhang X-R, Deng H-T, et al. . Silk fibroin-based wearable all-fiber multifunctional sensor for smart clothing. Adv Fiber Mater, 2022, 4: 873.

[5]

Shen T, Liu S, Yue X, Wang Z, Liu H, Yin R, et al. . High-performance fibrous strain sensor with synergistic sensing layer for human motion recognition and robot control. Adv Compos Hybrid Mater, 2023, 6: 127.

[6]

Xu S, Xiao X, Chen J. Stretchable fiber strain sensors for wearable biomonitoring. Natl Sci Rev, 2024, 11: nwae173

[7]

Fu K, Zhou J, Wu H, Su Z. Fibrous self-powered sensor with high stretchability for physiological information monitoring. Nano Energy, 2021, 88106258

[8]

Horev YD, Maity A, Zheng Y, Milyutin Y, Khatib M, Yuan M, et al. . Stretchable and highly permeable nanofibrous sensors for detecting complex human body motion. Adv Mater, 2021, 33: 2102488.

[9]

Yu R, Wang C, Du X, Bai X, Tong Y, Chen H, et al. . In-situ forming ultra-mechanically sensitive materials for high-sensitivity stretchable fiber strain sensors. Natl Sci Rev, 2024, 11: nwae58.

[10]

Jang Y, Kim SM, Spinks GM, Kim SJ. Carbon nanotube yarn for fiber-shaped electrical sensors, actuators, and energy storage for smart systems. Adv Mater, 2020, 321902670

[11]

Jayathilaka WADM, Qi K, Qin Y, Chinnappan A, Serrano-García W, Baskar C, et al. . Significance of nanomaterials in Wearables: a review on wearable actuators and sensors. Adv Mater, 2019, 31: 1805921.

[12]

Yang Y, Liu Y, Yin R. Fiber/yarn and textile-based piezoresistive pressure sensors. Adv Fiber Mater, 2025, 7: 34.

[13]

Babu A, Aazem I, Walden R, Bairagi S, Mulvihill DM, Pillai SC. Electrospun nanofiber based TENGs for wearable electronics and self-powered sensing. Chem Eng J, 2023, 452139060

[14]

Zhang Y, Hu Y, Liu Q, Lou K, Wang S, Zhang N, et al. . Multiplexed optical fiber sensors for dynamic brain monitoring. Matter, 2022, 5: 3947.

[15]

Wen X, Sun S, Wu P. Dynamic wrinkling of a hydrogel–elastomer hybrid microtube enables blood vessel-like hydraulic pressure sensing and flow regulation. Mater Horiz, 2020, 7: 2150.

[16]

Yin M-j, Gu B, An Q-F, Yang C, Guan YL, Yong K-T. Recent development of fiber-optic chemical sensors and biosensors: mechanisms, materials, micro/nano-fabrications and applications. Coord Chem Rev, 2018, 376: 348.

[17]

Zou K, Li Q, Li D, Jiao Y, Wang L, Li L, et al. . A highly selective implantable electrochemical fiber sensor for real-time monitoring of blood homovanillic acid. ACS Nano, 2024, 18: 7485

[18]

Xia Y, Li J, Ji Z, Zhou K, Zhang Y, Liu Y, et al. . Surface-engineering cellulose nanofibers via in situ PEDOT polymerization for superior thermoelectric properties. Adv Mater, 2025, 37: 2506338.

[19]

Chang Z, Wang F, Wang Z, Yu J, Ding B, Li Z. Fiber-based electrochemical sweat sensors toward personalized monitoring. Prog Mater Sci, 2026, 156101579

[20]

Zhou Z, Chen K, Li X, Zhang S, Wu Y, Zhou Y, et al. . Sign-to-speech translation using machine-learning-assisted stretchable sensor arrays. Nat Electron, 2020, 3: 571.

[21]

Yan J, Wang H, Wang K, Kang W, Yang G. Thermally robust hierarchical nanofiber triboelectric yarns for efficient energy harvesting in firefighting E-textiles. Chem Eng J, 2024, 499156188

[22]

Liu ZF, Fang S, Moura FA, Ding JN, Jiang N, Di J, et al. . Hierarchically buckled sheath-core fibers for superelastic electronics, sensors, and muscles. Science, 2015, 349: 400

[23]

Zhou T, Cao C, Yuan S, Wang Z, Zhu Q, Zhang H, et al. . Interlocking-governed ultra-strong and highly conductive MXene fibers through fluidics-assisted thermal drawing. Adv Mater, 2023, 352305807

[24]

Lan L, Jiang C, Yao Y, Ping J, Ying Y. A stretchable and conductive fiber for multifunctional sensing and energy harvesting. Nano Energy, 2021, 84105954

[25]

Wei L, Wang S, Shan M, Li Y, Wang Y, Wang F, et al. . Conductive fibers for biomedical applications. Bioact Mater, 2023, 22: 343

[26]

Hu S, Han J, Shi Z, Chen K, Xu N, Wang Y, et al. . Biodegradable, super-strong, and conductive cellulose macrofibers for fabric-based triboelectric nanogenerator. Nano-Micro Lett, 2022, 14: 115.

[27]

Chai J, Wang G, Wang G, Shao R, Zhao J, Zhao G, et al. . Porous and conductive fiber woven textile for multi-functional protection, personal warmth, and intelligent motion/temperature perception. Adv Funct Mater, 2025, 352416428

[28]

Feng W, Zou L, Lan C, Shiju E, Pu X. Core–sheath CNT@MXene fibers toward absorption-dominated electromagnetic interference shielding fabrics. Adv Fiber Mater, 2024, 6: 1657.

[29]

Yi P, Zou H, Yu Y, Li X, Li Z, Deng G, et al. . MXene-reinforced liquid metal/polymer fibers via interface engineering for wearable multifunctional textiles. ACS Nano, 2022, 16: 14490

[30]

Yun G, Tang S-Y, Sun S, Yuan D, Zhao Q, Deng L, et al. . Liquid metal-filled magnetorheological elastomer with positive piezoconductivity. Nat Commun, 2019, 10: 1300

[31]

Lin Y, Fang T, Bai C, Sun Y, Yang C, Hu G, et al. . Ultrastretchable electrically self-healing conductors based on silver nanowire/liquid metal microcapsule nanocomposites. Nano Lett, 2023, 23: 11174

[32]

Zheng Y, Liu H, Yan L, Yang H, Dai L, Si C. Lignin-based encapsulation of liquid metal particles for flexible and high-efficiently recyclable electronics. Adv Funct Mater, 2024, 342310653

[33]

Guan T, Gao J, Hua C, Tao Y, Ma Y, Liu J. Liquid metal enabled thermoelectric effects: fundamental and application. Adv Funct Mater, 2025, 35: 2423909.

[34]

Chen J, Yi D, Shen B, Zheng W. Multifunctional liquid-metal composites for electromagnetic communication and attenuation. Adv Mater, 2025, 37: 2404595.

[35]

Zhou Y, Zhu Y, Hu Z, Yang X, Yang P, Huang L, et al. . Liquid metal-based self-healable and elastic conductive fiber in complex operating conditions. Energy Environ Sci, 2023, 6: e12448

[36]

He R, Zhao B, Gu C, Yin S, Wang Y, Qin W. Core-shell porous LM/TPU fibers with tunable conductive properties for use as strain and pressure sensors. Compos Commun, 2024, 51102075

[37]

Zhu S, So J-H, Mays R, Desai S, Barnes WR, Pourdeyhimi B, et al. . Ultrastretchable fibers with metallic conductivity using a liquid metal alloy core. Adv Funct Mater, 2013, 23: 2308.

[38]

Mun S, Lee S, Bae KJ, Bae Y, Lee H-M, Kim B-J, et al. . Bio-imitative synergistic color-changing and shape-morphing elastic fibers with a liquid metal core. Adv Fiber Mater, 2024, 6: 900.

[39]

Zheng L, Zhu M, Wu B, Li Z, Sun S, Wu P. Conductance-stable liquid metal sheath-core microfibers for stretchy smart fabrics and self-powered sensing. Sci Adv, 2021, 7eabg041

[40]

Guo H, Han Y, Zhao W, Yang J, Zhang L. Universally autonomous self-healing elastomer with high stretchability. Nat Commun, 2020, 11: 2037

[41]

Dong C, Leber A, Das Gupta T, Chandran R, Volpi M, Qu Y, et al. . High-efficiency super-elastic liquid metal based triboelectric fibers and textiles. Nat Commun, 2020, 11: 3537

[42]

Liu S, Reed SN, Higgins MJ, Titus MS, Kramer-Bottiglio R. Oxide rupture-induced conductivity in liquid metal nanoparticles by laser and thermal sintering. Nanoscale, 2019, 11: 17615

[43]

Mohammed MG, Kramer R. All-printed flexible and stretchable electronics. Adv Mater, 2017, 291604965

[44]

Liu S, Yuen MC, White EL, Boley JW, Deng B, Cheng GJ, et al. . Laser sintering of liquid metal nanoparticles for scalable manufacturing of soft and flexible electronics. ACS Appl Mater Interfaces, 2018, 10: 28232

[45]

Liu S, Shah DS, Kramer-Bottiglio R. Highly stretchable multilayer electronic circuits using biphasic gallium-indium. Nat Mater, 2021, 20: 851

[46]

Duan S, Zhang H, Liu L, Lin Y, Zhao F, Chen P, et al. . A comprehensive review on triboelectric sensors and AI-integrated systems. Mater Today, 2024, 80: 450.

[47]

Peng Z, Xiao X, Song J, Libanori A, Lee C, Chen K, et al. . Improving relative permittivity and suppressing dielectric loss of triboelectric layers for high-performance wearable electricity generation. ACS Nano, 2022, 16: 20251

[48]

Meng X, Cai C, Luo B, Liu T, Shao Y, Wang S, et al. . Rational design of cellulosic triboelectric materials for self-powered wearable electronics. Nano-Micro Lett, 2023, 15: 124.

[49]

He Y, Ni H, Mishra D, Peng S, Phan H-P, Boyer C, et al. . Advancing triboelectric human machine interfaces with core–sheath nanocomposite fibres: enhanced flexibility and motion identification via machine learning. Nano Energy, 2024, 127109737

[50]

Wang N, Liu Y, Feng Y, Yang J, Wu Y, Zhang B, et al. . Revamping triboelectric output by deep trap construction. Adv Mater, 2024, 362303389

[51]

Jiang H, Lei H, Wen Z, Shi J, Bao D, Chen C, et al. . Charge-trapping-blocking layer for enhanced triboelectric nanogenerators. Nano Energy, 2020, 75105011

[52]

Xu S, Wang J, Wu H, Zhao Q, Li G, Fu S, et al. . Quantifying dielectric material charge trapping and de-trapping ability via ultra-fast charge self-injection technique. Adv Mater, 2024, 36: 2312148.

[53]

Shrestha K, Pradhan GB, Bhatta T, Sharma S, Lee S, Song H, et al. . Intermediate nanofibrous charge trapping layer-based wearable triboelectric self-powered sensor for human activity recognition and user identification. Nano Energy, 2023, 108108180

[54]

Lin S, Yang W, Zhu X, Lan Y, Li K, Zhang Q, et al. . Triboelectric micro-flexure-sensitive fiber electronics. Nat Commun, 2024, 152374

[55]

Sha Z, Boyer C, Li G, Yu Y, Allioux F-M, Kalantar-Zadeh K, et al. . Electrospun liquid metal/PVDF-HFP nanofiber membranes with exceptional triboelectric performance. Nano Energy, 2022, 92106713

[56]

Ye Q, Wu Y, Qi Y, Shi L, Huang S, Zhang L, et al. . Effects of liquid metal particles on performance of triboelectric nanogenerator with electrospun polyacrylonitrile fiber films. Nano Energy, 2019, 61: 381.

[57]

Zhou Y, Zhang Y, Ruan K, Guo H, He M, Qiu H, et al. . MXene-based fibers: preparation, applications, and prospects. Sci Bull, 2024, 69: 2776.

[58]

Yu S, Zhang Q, Liu L, Ma R. Thermochromic conductive fibers with modifiable solar absorption for personal thermal management and temperature visualization. ACS Nano, 2023, 17: 20299

[59]

Zhao X, Wang L-Y, Tang C-Y, Zha X-J, Liu Y, Su B-H, et al. . Smart Ti3C2Tx MXene fabric with fast humidity response and Joule heating for healthcare and medical therapy applications. ACS Nano, 2020, 14: 8793

[60]

Wu N, Mao P, Chang N, Zhou Y, Yang W, Fu F, et al. . Weavable, reconfigurable triboelectric ferrofluid fiber for early warning. ACS Nano, 2024, 18: 33319

[61]

Kashani ZA, Pakzad R, Fakari FR, Haghparast MS, Abdi F, Kiani Z, et al. . Electromagnetic fields exposure on fetal and childhood abnormalities: Systematic review and meta-analysis. Open Med, 2023, 18: 20230697.

[62]

Wang Z, Cai G, Xia Y, Li P, Shi S, Wang B, et al. . Highly conductive graphene fiber textile for electromagnetic interference shielding. Carbon, 2024, 222118996

[63]

Zang W, Wang Y, Wu W, Yao J, Hao X, Yu B, et al. . Superstretchable liquid-metal electrodes for dielectric elastomer transducers and flexible circuits. ACS Nano, 2024, 18: 1226

[64]

Cho C, Shin W, Kim M, Bang J, Won P, Hong S, et al. . Monolithically programmed stretchable conductor by laser-induced entanglement of liquid metal and metallic nanowire backbone. Small, 2022, 18: 2202841.

[65]

Ye H, Wu B, Sun S, Wu P. A solid-liquid bicontinuous fiber with strain-insensitive ionic conduction. Adv Mater, 2024, 36: 2402501.

[66]

Yao M, Wu B, Feng X, Sun S, Wu P. A highly robust ionotronic fiber with unprecedented mechanomodulation of ionic conduction. Adv Mater, 2021, 332103755

[67]

Thrasher CJ, Farrell ZJ, Morris NJ, Willey CL, Tabor CE. Mechanoresponsive polymerized liquid metal networks. Adv Mater, 2019, 311903864

[68]

Li X, Lin J, Wu J, Liu M, Du P, Xu L, et al. . Stretchable and leakage-free liquid metal networks for thermal management. Adv Funct Mater, 2025, 352420839

[69]

Kim D-H, Lu N, Ma R, Kim Y-S, Kim R-H, Wang S, et al. . Epidermal electronics. Science, 2011, 333: 838

[70]

Xu S, Zhang Y, Cho J, Lee J, Huang X, Jia L, et al. . Stretchable batteries with self-similar serpentine interconnects and integrated wireless recharging systems. Nat Commun, 2013, 4: 1543

[71]

Zolfaghari N, Khandagale P, Ford MJ, Dayal K, Majidi C. Network topologies dictate electromechanical coupling in liquid metal–elastomer composites. Soft Matter, 2020, 16: 8818

[72]

Wang X, Zheng S, Xiong J, Liu Z, Li Q, Li W, et al. . Stretch-induced conductivity enhancement in highly conductive and tough hydrogels. Adv Mater, 2024, 36: 2313845.

[73]

Wang X, Meng S, Tebyetekerwa M, Li Y, Pionteck J, Sun B, et al. . Highly sensitive and stretchable piezoresistive strain sensor based on conductive poly(styrene-butadiene-styrene)/few layer graphene composite fiber. Compos Part A Appl Sci Manuf, 2018, 105: 291.

[74]

Zhang Y, Zhang D, Chen Y, Lin H, Zhou X, Zhang Y, et al. . Liquid metal enabled elastic conductive fibers for self-powered wearable sensors. Adv Mater Technol, 2023, 82202030

[75]

Zhao Y, Dong D, Gong S, Brassart L, Wang Y, An T, et al. . A moss-inspired electroless gold-coating strategy toward stretchable fiber conductors by dry spinning. Adv Electron Mater, 2019, 5: 1800462.

[76]

Qu Y, Nguyen-Dang T, Page AG, Yan W, Das Gupta T, Rotaru GM, et al. . Superelastic multimaterial electronic and photonic fibers and devices via thermal drawing. Adv Mater, 2018, 301707251

[77]

Li X, Li M, Xu J, You J, Yang Z, Li C. Evaporation-induced sintering of liquid metal droplets with biological nanofibrils for flexible conductivity and responsive actuation. Nat Commun, 2019, 10: 3514

[78]

Yu Y, Guo J, Ma B, Zhang D, Zhao Y. Liquid metal-integrated ultra-elastic conductive microfibers from microfluidics for wearable electronics. Sci Bull, 2020, 65: 1752.

[79]

Wang Q, Sun Y, Qin C, Lin Y, Fang T, Yang C, et al. . Stretchable and permeable liquid metal micromeshes featuring strain-insensitive resistance through in situ structural transformations. Adv Mater, 2025, 372417799

[80]

Wang ZL, Wang AC. On the origin of contact-electrification. Mater Today, 2019, 3034

[81]

Lin C, Sun L, Meng X, Yuan X, Cui C-X, Qiao H, et al. . Covalent organic frameworks with tailored functionalities for modulating surface potentials in triboelectric nanogenerators. Angew Chem Int Ed, 2022, 61e202211601

[82]

Kang H, Kim HT, Woo HJ, Kim H, Kim DH, Lee S, et al. . Metal nanowire–polymer matrix hybrid layer for triboelectric nanogenerator. Nano Energy, 2019, 58: 227.

[83]

Li X, Lin J, Wu J, Liu M, Du P, Xu L, et al. . Stretchable and leakage-free liquid metal networks for thermal management. Adv Funct Mater, 2025, 35: 2420839.

[84]

Yang G, Zhang X, Zhu J, Li Z, Pan D, Su F, et al. . Silver nanoparticles bridging liquid metal for wearable electromagnetic interference fabric. J Mater Sci Technol, 2025, 220: 320.

[85]

Xiang S, Wei X, Liu L, Hong J, Duan S, Zhang H, et al. . A permeable, metal-like conductivity, stretchable, strain-insensitivity, self-assembled and rapidly formed Janus-structured e-skin. Nano Energy, 2025, 136110712

Funding

National Natural Science Foundation of China(62301150)

National Key R&D Program of China(2022YFB3603403)

Southeast University Interdisciplinary Research Program for Young Scholars(2024FGC1007)

Start-up Research Fund of Southeast University(RF1028623164)

SEU Innovation Capability Enhancement Plan for Doctoral Students(CXJH_SEU 25112)

Fundamental Research Funds for the Central Universities(2242024K40015;2242025F10007)

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