Rigorous Fireproofing, Thermal Protection, Graded Fire Alarm and Body Language Recognition: Designing Nano-Coated Aramid for Smart Firefighting Clothing

Xiang Dong , Yan Ma , Shidai Zhang , Caiyu Rong , Xiaoyu Jiang , Yan Li , Shibin Nie , Konghu Tian

Advanced Fiber Materials ›› 2025, Vol. 7 ›› Issue (5) : 1545 -1562.

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Advanced Fiber Materials ›› 2025, Vol. 7 ›› Issue (5) : 1545 -1562. DOI: 10.1007/s42765-025-00569-y
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Rigorous Fireproofing, Thermal Protection, Graded Fire Alarm and Body Language Recognition: Designing Nano-Coated Aramid for Smart Firefighting Clothing

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Abstract

Smart firefighting clothing is in urgent need of rigorous fire resistance. Here, a novel 2D nanomaterial, silver nanoparticle@polydopamine@M(OH)(OCH3) (M=Co, Ni) (AgNP@PDA@M(OH)(OCH3)), was utilized to construct self-assembled nano-coated aramid fiber (NCANF). Through phase interface catalysis and high-temperature reduction, NCANF forms a distinctive “metal–carbon–air” honeycomb-like buffer that enables NCANF to withstand the butane flame (1300 °C) for at least 60 s, exceeding the performance of firefighting uniform (FU, Nomex) in service. In this process, the back temperature of NCANF decreased by more than 50% compared to FU, with a maximum difference of 236.1 °C. NCANF offers a rapid fire alarm response under 3 s with a maximum resistance change rate of 15%, and supports the graded indication using arithmetic amplifier circuit. NCANF maintained a maximum resistance change rate of approximately 63% during 50 repeated bends of the manipulator joint. Leveraging the relationship between the joint bending angle and resistance change rate, an “attitude code” system can be established as the initial parameter matrix of a neural network and can enable the recognition of the firefighters’ body language. NCANF well solves the problem of current smart firefighting clothing that lacks rigorous fireproofing and is promising to establish a linked rescue mode based on real-time on-site information collection.

Keywords

Nano coating / Smart firefighting clothing / Aramid fiber / Fire resistance / Fire alarm / Gesture recognition

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Xiang Dong, Yan Ma, Shidai Zhang, Caiyu Rong, Xiaoyu Jiang, Yan Li, Shibin Nie, Konghu Tian. Rigorous Fireproofing, Thermal Protection, Graded Fire Alarm and Body Language Recognition: Designing Nano-Coated Aramid for Smart Firefighting Clothing. Advanced Fiber Materials, 2025, 7(5): 1545-1562 DOI:10.1007/s42765-025-00569-y

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References

[1]

HuiZY, ZhangLR, RenGZ, SunGZ, YuH-D, HuangW. Green flexible electronics: natural materials, fabrication, and applications. Adv Mater, 2023, 35e2211202

[2]

LeeJH, ChoK, KimJK. Age of flexible electronics: emerging trends in soft multifunctional sensors. Adv Mater, 2024, 36e2310505

[3]

ChoiHW, ShinD-W, YangJ, LeeS, FigueiredoC, SinopoliS, UllrichK, JovančićP, MarraniA, MomentèR, GomesJ, BranquinhoR, EmanueleU, LeeH, BangSY, JungS-M, HanSD, ZhanS, Harden-ChatersW, SuhY-H, et al.. Smart textile lighting/display system with multifunctional fibre devices for large scale smart home and IoT applications. Nat Commun, 2022, 13814

[4]

WengW, ChenPN, HeSS, SunXM, PengHS. Smart electronic textiles. Angew Chem Int Ed, 2016, 55: 6140-6169

[5]

ChenGR, LiYZ, BickM, ChenJ. Smart textiles for electricity generation. Chem Rev, 2020, 120: 3668-3720

[6]

WangP, SunGF, HuaSC, YuW, MengCZ, HanQ, KimJ, GuoSJ, ShenGZ, LiY. Multifunctional all-nanofiber cloth integrating personal health monitoring and thermal regulation capabilities. InfoMat, 2024, 7e12629

[7]

LeeSY, LimH, ChoiHJ, AhnJ, ChoiYK, OhDY, ChaeD, LeeH, OhSJ. Designing comfortable-to-use wearable strain sensors with thermal management through radiative cooling function. Chem Eng J, 2024, 498155691

[8]

LuoY, MiaoYP, WangHM, DongK, HouL, XuYY, ChenWC, ZhangY, ZhangYY, FanW. Laser-induced Janus graphene/poly(p-phenylene benzobisoxazole) fabrics with intrinsic flame retardancy as flexible sensors and breathable electrodes for fire-fighting field. Nano Res, 2023, 16: 7600-7608

[9]

YuZC, WanYH, QinY, JiangQ, GuanJ-P, ChengX-W, WangXC, OuyangSN, QuXR, ZhuZY, WangJF, HeHL. High fire safety thermal protective composite aerogel with efficient thermal insulation and reversible fire warning performance for firefighting clothing. Chem Eng J, 2023, 477147187

[10]

JiangQ, WanYH, QinY, QuXR, ZhouM, HuoSQ, WangXC, YuZC, HeHL. Durable and wearable self-powered temperature sensor based on self-healing thermoelectric fiber by coaxial wet spinning strategy for fire safety of firefighting clothing. Adv Fiber Mater, 2024, 6: 1387-1401

[11]

YuZ, ZhuZ, ZhangY, LiX, LiuX, QinY, ZhengZ, ZhangL, HeH. Biodegradable and flame-retardant cellulose-cased wearable triboelectric nanogenerator for mechanical energy harvesting in firefighting clothing. Carbohydr Polym, 2024, 334122040

[12]

ZhuYF, ZhaoBB, ChengZF, YuT, LiY. Efficient flame-retardant and multifunctional conductive flax fabric for intelligent fire protection and human motion monitoring. Chem Eng J, 2023, 474145610

[13]

JinX, ZhangJ, WangB, LiXL, ZengJ, MaJY, ZhaoXM, WuWQ, Del Río SáezJS, ZhangXQ, WangD-Y, WangR. Multifunctional polylactic acid sensing fabric based on biomass flame retardants for intelligent fire early-warning. Int J Biol Macromol, 2024, 259129158

[14]

WangFM, ZhaoJY, HuXR, SuXZ, SunFX. Robust treble-weaving wearable textiles for pressure and temperature monitoring in harsh environments. ACS Appl Mater Interfaces, 2024, 16: 48269-48279

[15]

CuiYF, HeXY, LiuWD, ZhuSY, ZhouM, WangQ. Highly stretchable, sensitive, and multifunctional thermoelectric fabric for synergistic-sensing systems of human signal monitoring. Adv Fiber Mater, 2024, 6: 170-180

[16]

HeHL, QinY, ZhuZY, JiangQ, OuyangS, WanYH, QuXR, XuJ, YuZC. Temperature-arousing self-powered fire warning e-textile based on p-n segment coaxial aerogel fibers for active fire protection in firefighting clothing. Nano-Micro Lett, 2023, 15: 149-168

[17]

ShengZZ, LiuZW, HouYL, JiangHT, LiYZ, LiGY, ZhangXT. The rising aerogel fibers: status, challenges, and opportunities. Adv Sci, 2023, 10e2205762

[18]

PengZY, GaoC, LiuYC, GeC, GongHR, ChenZ, QinY, LiuKS, XuD, FangJ, XuWL. Enhancing electrical output and thermal adaptivity in an interlocked core-sheath triboelectric yarn/fabric for intelligent fire-rescue systems. Chem Eng J, 2024, 486150172

[19]

HeHL, QinY, LiuJR, WangYS, WangJF, ZhaoYH, ZhuZY, JiangQ, WanYH, QuXR, YuZC. A wearable self-powered fire warning e-textile enabled by aramid nanofibers/MXene/silver nanowires aerogel fiber for fire protection used in firefighting clothing. Chem Eng J, 2023, 460141661

[20]

ZhangY-X, LiY-D, DuA-K, WuYP, ZengJ-B. Layer-by-layer assembly of chitosan and carbon nanotube on cotton fabric for strain and temperature sensing. J Mater Sci Technol, 2024, 173: 114-120

[21]

ZhangMJ, WangML, ZhangMX, YangCG, LiYN, ZhangYM, HuJT, WuGZ. Flexible and thermally induced switchable fire alarm fabric based on layer-by-layer self-assembled silver sheet/Fe3O4 nanowire composite. ACS Appl Mater Interfaces, 2019, 11: 47456-47467

[22]

FangCJ, LiuJH, LiuPJ, ChenWH. Flexible and multifunctional papers with nacre-mimetic MXene/chitosan nanostructures for joule/solar heating and motion monitoring. ACS Appl Polym Mater, 2024, 6: 8429-8438

[23]

ZhuJ, SongYT, WangJC, YangQR, MaSQ, ZhangS, ChenTY, JiaZH. A highly flame-retardant, agile fire-alarming and ultrasensitive cotton fabric-based piezoresistive sensor for intelligent fire system. Polym Degrad Stab, 2023, 211110338

[24]

MaYL, ShiWL, TangKK, LiSS, SunJT, XuDF, LiWC, HuXL, TianMW. Flexible polyimide-based flame-retardant E-textile for fire damage warning in firefighting clothing. Prog Org Coat, 2024, 192108517

[25]

YanJ, WangHX, WangKB, KangWM, YangG. Thermally robust hierarchical nanofiber triboelectric yarns for efficient energy harvesting in firefighting E-textiles. Chem Eng J, 2024, 499156188

[26]

ZengQT, WangBL, LaiXJ, LiHQ, ChenZH, ZengXR, ZhangLQ. A multifunctional flame-retardant TA-MXene based nanocoating for cotton fabric. Prog Org Coat, 2024, 189108333

[27]

WangBL, LaiXJ, LiHQ, JiangCC, GaoJF, ZengXR. Multifunctional MXene/chitosan-coated cotton fabric for intelligent fire protection. ACS Appl Mater Interfaces, 2021, 13: 23020-23029

[28]

LiuZT, MaP, UlstrupJ, ChiQJ, ZhuK, ZhouXG. New class of two-dimensional bimetallic nanoplatelets for high energy density and electrochemically stable hybrid supercapacitors. Nano Res, 2017, 10: 3018-3034

[29]

DongX, SunZY, LiDL, DuanQC, MaY, LiuS. A novel nanohybrid, Fe3O4/NHS@M(OH)(OCH3)@rGO (M= Co, Ni), with petal-shaped anisotropic interfaces imparts efficient EMW absorption, flame retardancy, and thermal management properties to epoxy resin. Polymer, 2024, 301127069

[30]

DongX, MaY, FanXG, ZhaoS, XuYX, LiuS, JinD. Nickel modified two-dimensional bimetallic nanosheets, M(OH)(OCH3) (M=Co, Ni), for improving fire retardancy and smoke suppression of epoxy resin. Polymer, 2021, 235124263

[31]

DongX, DaiGW, XieL, LiDL, SunZY, LiuS. Heat-triggered shape recovery, EMI shielding and flame retardant: A novel cellulose/M(OH)(OCH3)@dopamine@Ag (M=Co, Ni) nanopaper for early fire alarm. Int J Biol Macromol, 2024, 264130270

[32]

CamlibelNO, KandolaBK. Highly sensitive textile pressure sensors with novel hierarchical architecture based on conductive polymers, silver nanoparticles and carbon nanotubes. Sens Actuators A, 2025, 382116166

[33]

GodaES, Abu ElellaMH, HongSE, PanditB, YoonKR, GamalH. Smart flame retardant coating containing carboxymethyl chitosan nanoparticles decorated graphene for obtaining multifunctional textiles. Cellulose, 2021, 28: 5087-5105

[34]

AttiaNF, OhH, El AsherySEA. Design and fabrication of metal-organic-framework based coatings for high fire safety and UV protection, reinforcement and electrical conductivity properties of textile fabrics. Prog Org Coat, 2023, 179107545

[35]

XingLL, WangYR, ChengJ, ChenGQ, XingTL. Robust and flexible smart silk/PEDOT conductive fibers as wearable sensor for personal health management and information transmission. Int J Biol Macromol, 2023, 248125870

[36]

Jiang DW, Lian MY, Xu MJ, Sun Q, Xu BB, Thabet HK, El-Bahy SM, Ibrahim MM, Huang MN, Guo ZH. Advances in triboelectric nanogenerator technology—applications in self-powered sensors, internet of things, biomedicine, and blue energy. Adv Compos Hybrid Mater. 2023;6:57.

[37]

DongK, PengX, WangZL. Fiber/fabric-based piezoelectric and triboelectric nanogenerators for flexible/stretchable and wearable electronics and artificial intelligence. Adv Mater, 2020, 32e1902549

[38]

EspentiCS, SurendraTV, Krishna RaoKSV, AnsariMA, RaoKM, HanSS. Harnessing durable antimicrobial cellulose cotton fabric coated with silver nanoparticles via a green approach for photocatalytic applications. J Mol Liq, 2024, 416126483

[39]

XiaoMY, GuoYB, ZhangJY, LiuYS, RenYL, LiuXH. Diethylene triamine penta methylene phosphonic acid encountered silver ions: A convenient method for preparation of flame retardant and antibacterial lyocell fabric. Cellulose, 2021, 28: 7465-7481

[40]

WangXZ, LuoJB, TuoYX, GuYF, LiuWL, WangST, ZhouY, ZhangJ. Hierarchical heterostructure of NiFe2O4 nanoflakes grown on the tip of NiCo2O4 nanoneedles with enhanced interfacial polarization effect to achieve highly efficient electrocatalytic oxygen evolution. Chem Eng J, 2023, 457141169

[41]

SunLT, LiangXL, LiuHM, CaoHJ, LiuXH, JinY, LiXY, ChenS, WuXD. Activation of Co-O bond in (110) facet exposed Co3O4 by Cu doping for the boost of propane catalytic oxidation. J Hazard Mater, 2023, 452131319

[42]

MaoT, XieSH, TuJ, XiaoH, WangP. Facile fabrication of ultradurable flame-retardant and hydrophobic cotton fabric with P/N-rich maltodextrin derivative and octadecyltrimethoxysilane. Int J Biol Macromol, 2024, 280135685

[43]

WangYD, MaL, YuanJ, ZhuZM, LiuXM, LiDS, HeLQ, XiaoF. Furfural-based P/N/S flame retardant towards high-performance epoxy resins with flame retardancy, toughness, low dielectric properties and UV Resistance. Polym Degrad Stab, 2023, 212110343

[44]

FengHM, WangWH, WangW, ZhangMT, WangCW, MaCC, LiW, ChenSG. Charge transfer channels of silver @ cuprous oxide heterostructure core-shell nanoparticles strengthen high photocatalytic antibacterial activity. J Colloid Interface Sci, 2021, 601: 531-543

[45]

WangWH, HaoXP, ChenSG, YangZQ, WangCY, YanR, ZhangX, LiuH, ShaoQ, GuoZH. pH-responsive Capsaicin@chitosan nanocapsules for antibiofouling in marine applications. Polymer, 2018, 158: 223-230

[46]

MaoYY, WangD, HuJL, FuSH. Mechanically flexible and flame retardant polyphenol-bridged casein/MXene composite for fire proofing repeatable contact/non-contact fire monitoring. Chem Eng J, 2023, 454140161

[47]

CorazzariI, NisticòR, TurciF, FagaMG, FranzosoF, TabassoS, MagnaccaG. Advanced physico-chemical characterization of chitosan by means of TGA coupled on-line with FTIR and GCMS: Thermal degradation and water adsorption capacity. Polym Degrad Stab, 2015, 112: 1-9

[48]

YanK, WangJ, ZongY, XuQN. A multifunctional coating toward wearable superhydrophobic fabric sensor with self-healing and flame-retardant properties with high fire alarm response. Chem Eng J, 2024, 489151315

[49]

DingL, SunL, YuJK, CaoYF, LiuXH, RenYL, LiYS. 0D bio-based carbon dots and 2D MXene hybridization toward fabricating flame-retardant, conductive and sensing cellulose fabrics. Chem Eng J, 2024, 488150776

[50]

ChenF, LiuLL, WuJH, RuiXH, ChenJJ, YuY. Single-atom iron anchored tubular g-C3N4 catalysts for ultrafast Fenton-like reaction: roles of high-valency iron-oxo species and organic radicals. Adv Mater, 2022, 342202891

[51]

MatsuhisaN, InoueD, ZalarP, JinH, MatsubaY, ItohA, YokotaT, HashizumeD, SomeyaT. Printable elastic conductors by in situ formation of silver nanoparticles from silver flakes. Nat Mater, 2017, 16: 834-840

[52]

LiZ, CaoX-M, JiangL-Y, WeiP, ZhangJ, WangD-Y. Interface-charring catalysis enables fire-safe and mechanically reinforced epoxy via facile interfacial aggregation induction. Polym Degrad Stab, 2022, 206110189

[53]

BiQQ, LiYM, HeL, WangDY. Bio-derived modified halloysite nanotubes as eco-friendly flame retardants to endow epoxy with high thermal stability, mechanical performance and flame retardancy. Chem Eng J, 2024, 500157438

[54]

SunQ, ZhangXY, GuPZ, LiangX, HuZY, YangX, LiuMX, HuangJ, ZuGQ. Highly stretchable MXene-based meta-aerogels with near-zero and negative poisson’s ratios. Adv Funct Mater, 2023, 34: 1-13

[55]

ChenQ, GaoQS, WangX, SchubertDW, LiuXH. Flexible, conductive, and anisotropic thermoplastic polyurethane/polydopamine/MXene foam for piezoresistive sensors and motion monitoring. Compos Part A: Appl Sci Manuf, 2022, 155106838

[56]

WuHD, LiuW, GeS, TangC, LiYH, ShengPF, WuSH. Vat photopolymerization of silicon carbide strengthened alumina ceramic composites with honeycomb structure for heat insulation and oil/water separation. Ceram Int, 2024, 50: 31504-31518

[57]

ZhangQR, MaL, XueTT, TianJ, FanW, LiuTX. Flame-retardant and thermal-protective polyimide-hydroxyapatite aerogel fiber-based composite textile for firefighting clothing. Compos Part B: Eng, 2023, 248: 110377-110385

[58]

SunLC, GuoYJ, OuRX, XuJW, GaoF, MengQZ, ChenSL, GuoCG, FanQ, WangQW. Ultrastrong and thermo-remoldable lignin-based polyurethane foam insulation with active-passive fire resistance. Adv Funct Mater, 2024, 341

[59]

TaoJ, ZhaoWT, ZhouXR, ZhangJW, ZhangYF, FanMH, WuMJ, LiuLY, ZhouZJ, ZhuH, XiongJQ. Robust all-fabric e-skin with high-temperature and corrosion tolerance for self-powered tactile sensing. Nano Energy, 2024, 128109930

[60]

FuR, ZhaoX, ZhangXY, SuZQ. Design strategies and applications of wearable piezoresistive strain sensors with dimensionality-based conductive network structures. Chem Eng J, 2023, 454140467

[61]

YueXY, FangCQ, YaoQZ, LiuCT, ShenCY, LiuH. Tunable porous fiber-shaped strain sensor with synergistic conductive network for human motion recognition and tactile sensing. Chem Eng J, 2024, 491151853

Funding

National Natural Science Foundation of China(52403063)

Outstanding Youth Scientific Research Project in Anhui Province(2022AH020055)

RIGHTS & PERMISSIONS

Donghua University, Shanghai, China

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