Recent Advances of Aqueous Fiber-Shaped Zn Ion Batteries

Ting Xiong , Xiaowei Yan , Wenzhan Zhang , Yaoxin Zhang , Zhongchao Bai , Huakun Liu

Advanced Fiber Materials ›› 2025, Vol. 7 ›› Issue (5) : 1383 -1402.

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Advanced Fiber Materials ›› 2025, Vol. 7 ›› Issue (5) : 1383 -1402. DOI: 10.1007/s42765-025-00557-2
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Recent Advances of Aqueous Fiber-Shaped Zn Ion Batteries

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Abstract

The rapid advancement of wearable electronics has driven significant interest in the development of wearable energy storage technologies. Among them, aqueous zinc ion batteries (ZIBs) have gained considerable attention as promising candidates for portable and wearable applications. In particular, aqueous fiber-shaped ZIBs offer distinctive advantages, such as miniaturization, flexibility, and wearability, making them especially suitable for powering next-generation wearable devices. This review provides a comprehensive overview of the recent advances in aqueous fiber-shaped ZIBs, focusing on the fabrication of fiber-based electrodes and various battery configurations. In addition, we highlight the evolution of fiber-shaped ZIBs from single-function to multi-function systems, exploring their potential for diverse applications. The review also addresses the key challenges in this field and discusses future research directions to drive the further development of aqueous fiber-shaped ZIBs.

Keywords

Aqueous zinc ion batteries / Fiber-shaped device / High-performance / Diverse applications

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Ting Xiong, Xiaowei Yan, Wenzhan Zhang, Yaoxin Zhang, Zhongchao Bai, Huakun Liu. Recent Advances of Aqueous Fiber-Shaped Zn Ion Batteries. Advanced Fiber Materials, 2025, 7(5): 1383-1402 DOI:10.1007/s42765-025-00557-2

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References

[1]

SongM, TanH, ChaoD, FanHJ. Recent advances in Zn-Ion batteries. Adv Funct Mater, 2018, 281802564

[2]

LiH, MaL, HanC, WangZ, LiuZ, TangZ, ZhiC. Advanced rechargeable zinc-based batteries: recent progress and future perspectives. Nano Energy, 2019, 62: 550-587

[3]

FangG, ZhouJ, PanA, LiangS. Recent advances in aqueous zinc-ion batteries. ACS Energy Lett, 2018, 3: 2480-2501

[4]

XuC, LiB, DuH, KangF. Energetic zinc ion chemistry: the rechargeable zinc ion battery. Angew Chem, Int Ed, 2012, 51: 933-935

[5]

MingJ, GuoJ, XiaC, WangW, AlshareefHN. Zinc-ion batteries: Materials, mechanisms, and applications. Mater Sci Eng R Rep, 2019, 135: 58-84

[6]

ZhangN, ChenX, YuM, NiuZ, ChengF, ChenJ. Materials chemistry for rechargeable zinc-ion batteries. Chem Soc Rev, 2020, 49: 4203-4219

[7]

JiaX, LiuC, NealeZG, YangJ, CaoG. Active materials for aqueous zinc ion batteries: synthesis, crystal structure, morphology, and electrochemistry. Chem Rev, 2020, 120: 7795-7866

[8]

LiuH, WangJ-G, YouZ, WeiC, KangF, WeiB. Rechargeable aqueous zinc-ion batteries: mechanism, design strategies and future perspectives. Mater Today, 2021, 42: 73-98

[9]

Jia H, Liu K, Lam Y, Tawiah B, Xin JH, Nie W, Jiang S-x. Fiber-based materials for aqueous zinc ion batteries. Adv Fiber Mater.2022;5:36–58.

[10]

MoF, LiangG, HuangZ, LiH, WangD, ZhiC. An overview of fiber-shaped batteries with a focus on multifunctionality, scalability, and technical difficulties. Adv Mater, 2020, 32e1902151

[11]

ZhangQ, JinY, QiS, MaQ, WangZ, LvP, ShiF, WeiW. Overview of fiber-shaped energy storage devices: from fabrication to application. Nano Energy, 2024, 128109896

[12]

KhumujamDD, KshetriT, SinghTI, SinghSB, KimNH, LeeJH. Achieving the optimal performance of VO@CoNC anchored on MX/CF through phosphorous-doped induced defects for the fiber-shaped solid-state Zn-ion battery. Chem Eng J, 2024, 486150252

[13]

HeB, ZhouZ, ManP, ZhangQ, LiC, XieL, WangX, LiQ, YaoY. V2O5 nanosheets supported on 3D N-doped carbon nanowall arrays as an advanced cathode for high energy and high power fiber-shaped zinc-ion batteries. J Mater Chem A, 2019, 7: 12979-12986

[14]

CongZ, GuoW, ZhangP, ShaW, GuoZ, ChangC, XuF, GangX, HuW, PuX. Wearable antifreezing fiber-shaped Zn/PANI batteries with suppressed Zn dendrites and operation in sweat electrolytes. ACS Appl Mater Interfaces, 2021, 13: 17608-17617

[15]

ZhangH, XiongT, ZhouT, ZhangX, WangY, ZhouX, WeiL. Advanced fiber-shaped aqueous Zn ion battery integrated with strain sensor. ACS Appl Mater Interfaces, 2022, 14: 41045-41052

[16]

XiongT, ZhouX, WangY, ZhouT, HuangR, ZhongH, ZhangX, YuanS, WangZ, XinJ, XueJ, LeeWSV, WeiL. Photo-powered all-in-one energy harvesting and storage fibers towards low-carbon smart wearables. Energy Storage Mater, 2024, 65103146

[17]

LiaoM, WangJ, YeL, SunH, LiP, WangC, TangC, ChengX, WangB, PengH. A high-capacity aqueous zinc-ion battery fiber with air-recharging capability. J Mater Chem A, 2021, 9: 6811-6818

[18]

GaoT, YanG, YangX, YanQ, TianY, SongJ, LiF, WangX, YuJ, LiY, GuoS. Wet spinning of fiber-shaped flexible Zn-ion batteries toward wearable energy storage. J Energy Chem, 2022, 71: 192-200

[19]

LeeJ-G, KwonY, JuJ-Y, ChoiS, KangY, YuW-R, KimDW. Fiber electrode by one-pot wet-spinning of graphene and manganese oxide nanowires for wearable lithium-ion batteries. J Appl Electrochem, 2017, 47: 865-875

[20]

ChoiW, KwonY, YuW-R, KimDW. Graphite fiber electrode by continuous wet-spinning. ACS Appl Energy Mater, 2022, 5: 8963-8972

[21]

TangQ, LiL, GuoK, ZhuR, LiuM, ChenX. One-step hydrothermal method produced all graphene fiber electrode for high-performance supercapacitor. Int J Energy Res, 2022, 46: 14105-14115

[22]

ZhangQ, YangF, ZhangC, DongH, SuiJ, YuL, ChenY, YuJ, DongL. A novel wire-shaped supercapacitor based on MnO2 nanoflakes and carbon nanotubes with high performance synthesized by sacrificial template method. Appl Surf Sci, 2021, 551149417

[23]

PingZ, LianJ, LiuY. Optimization of the electrodeposition process of a polypyrrole/multi-walled carbon nanotube fiber electrode for a flexible supercapacitor. RSC Adv, 2022, 12: 18134-18143

[24]

Abdul BashidHA, LimHN, KamaruzamanS, Abdul RashidS, YunusR, HuangNM, YinCY, RahmanMM, AltarawnehM, JiangZT, AlagarsamyP. Electrodeposition of polypyrrole and reduced graphene oxide onto carbon bundle fibre as electrode for supercapacitor. Nanoscale Res Lett, 2017, 12246

[25]

JianY, JuJ, PeiL, GaoW, LiD, WangW, QiaoY, LuZ. Constructing high-performance yarn-shaped electrodes via twisting-after-coating technique for weavable seawater battery. ACS Appl Mater Interfaces, 2024, 16: 71038-71047

[26]

LanX, TangT, XieH, HasanSW, LiangL, TianZQ, ShenPK. Robust, conductive, and high loading fiber-shaped electrodes fabricated by 3D active coating for flexible energy storage devices. Nano Lett, 2022, 22: 5795-5802

[27]

ZhouY, WangCH, LuW, DaiL. Recent advances in fiber-shaped supercapacitors and lithium-ion batteries. Adv Mater, 2020, 32e1902779

[28]

ZhangY, BaiW, RenJ, WengW, LinH, ZhangZ, PengH. Super-stretchy lithium-ion battery based on carbon nanotube fiber. J Mater Chem A, 2014, 2: 11054-11059

[29]

Xiong T, He B, Zhou T, Wang Z, Wang Z, Xin J, Zhang H, Zhou X, Liu Y, Wei. Stretchable fiber‐shaped aqueous aluminum ion batteries. EcoMat. 2022;4:e12218.

[30]

FuY, CaiX, WuH, LvZ, HouS, PengM, YuX, ZouD. Fiber supercapacitors utilizing pen ink for flexible/wearable energy storage. Adv Mater, 2012, 24: 5713-5718

[31]

LiM, MengJ, LiQ, HuangM, LiuX, OwusuKA, LiuZ, MaiL. Finely crafted 3D electrodes for dendrite-free and high-performance flexible fiber-shaped Zn–Co batteries. Adv Funct Mater, 2018, 281802016

[32]

ZengZ, ShaoZ, ShenR, LiH, JiangJ, WangX, LiW, GuoS, LiuY, ZhengG. Coaxial electrospun tai chi-inspired lithium-ion battery separator with high performance and fireproofing capacity. ACS Appl Mater Interfaces, 2023, 15: 44259-44267

[33]

GuanQ, LiY, BiX, YangJ, ZhouJ, LiX, ChengJ, WangZ, WangB, LuJ. Dendrite-free flexible fiber-shaped Zn battery with long cycle life in water and air. Adv Energy Mater, 2019, 91901434

[34]

XiaZ, LiS, WuG, ShaoY, YangD, LuoJ, JiaoZ, SunJ, ShaoY. Manipulating hierarchical orientation of wet-spun hybrid fibers via rheological engineering for Zn-Ion fiber batteries. Adv Mater, 2022, 34e2203905

[35]

LiC, WangW, LuoJ, ZhuangW, ZhouJ, LiuS, LinL, GongW, HongG, ShaoZ, DuJ, ZhangQ, YaoY. High-fluidity/high-strength dual-layer gel electrolytes enable ultra-flexible and dendrite-free fiber-shaped aqueous zinc metal battery. Adv Mater, 2024, 36e2313772

[36]

Xiao X, Xiao X, Zhou Y, Zhao X, Chen G, Liu Z, Wang Z, Lu C, Hu M, Nashalian A, Shen S, Xie K, Yang W, Gong Y, Ding W, Servati P, Han C, Dou SX, Li W, Chen J. An ultrathin rechargeable solid-state zinc ion fiber battery for electronic textiles. Sci Adv. 2021;7:eabl3742.

[37]

HuF, LiM, GaoG, FanH, MaL. The gel-state electrolytes in Zinc-Ion batteries. Batteries, 2022, 8214

[38]

LiC, WangW, TangY, ZhuangW, ZhangJ, ZhangD, QianX, HongG, DuJ, YaoY. Building microcracked structure fibrous cathode coated by Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) for ultra-stable fiber-shaped aqueous zinc ions batteries. J Colloid Interface Sci, 2025, 677: 551-559

[39]

WangJ, LiaoM, HuangX, LiP, LiJ, YeL, GaoY, PengH, WangB. Enhanced cathode integrity for zinc–manganese oxide fiber batteries by a durable protective layer. J Mater Chem A, 2022, 10: 10201-10208

[40]

SunY, NatsukiJ, XuS, SunP, ZhouW, LiB, NieW, NatsukiT. High-performance flexible zinc-ion battery: Slurry-coated on carbon fiber. Mater Lett, 2024, 371136866

[41]

LuY, ZhangH, LiuH, NieZ, XuF, ZhaoY, ZhuJ, HuangW. Electrolyte dynamics engineering for flexible fiber-shaped aqueous zinc-Ion battery with ultralong stability. Nano Lett, 2021, 21: 9651-9660

[42]

MaY, XieX, LvR, NaB, OuyangJ, LiuH. Nanostructured polyaniline-cellulose papers for solid-state flexible aqueous Zn-Ion battery. ACS Sust Chem Eng, 2018, 6: 8697-8703

[43]

CaoM, ChenW, MaY, HuangH, LuoS, ZhangC. Cross-linked K2Ti4O9 nanoribbon arrays with superior rate capability and cyclability for lithium-ion batteries. Mater Lett, 2020, 279128495

[44]

ChenX, WeiS, WangJ, TongF, SöhnelT, WaterhouseGIN, ZhangW, KennedyJ, TaylorMP. Lithium insertion/extraction mechanism in Mg2Sn anode for lithium-ion batteries. Intermetallics, 2024, 169108306

[45]

LiuC, LiQ, SunH, WangZ, GongW, CongS, YaoY, ZhaoZ. MOF-derived vertically stacked Mn2O3@C flakes for fiber-shaped zinc-ion batteries. J Mater Chem A, 2020, 8: 24031-24039

[46]

YiH, MaY, ZhangS, NaB, ZengR, ZhangY, LinC. Robust aqueous Zn-Ion fiber battery based on high-strength cellulose yarns. ACS Sust Chem Eng, 2019, 7: 18894-18900

[47]

LiuY, WangJ, ZengY, LiuJ, LiuX, LuX. Interfacial engineering coupled valence tuning of MoO3 cathode for high-capacity and high-rate fiber-shaped zinc-ion batteries. Small, 2020, 16e1907458

[48]

ZhangQ, LiC, LiQ, PanZ, SunJ, ZhouZ, HeB, ManP, XieL, KangL, WangX, YangJ, ZhangT, ShumPP, LiQ, YaoY, WeiL. Flexible and high-voltage coaxial-fiber aqueous rechargeable zinc-ion battery. Nano Lett, 2019, 19: 4035-4042

[49]

WangC, HeT, ChengJ, GuanQ, WangB. Bioinspired interface design of sewable, weavable, and washable fiber zinc batteries for wearable power textiles. Adv Func Mater, 2020, 302004430

[50]

XuJ, ZhuK, ZhuZ, LiangP, ZhangZ, ZhengH, LiuJ, YanK, WangJ. Continuous wet spinning of V2O5 fiber electrodes with silver-plated yarn core for Zn ion fiber batteries. J Power Sources, 2024, 614235009

[51]

JiangZ, WangY, ChenH, ZhaiS, LiM, SongsiriritthigulP, OoTZ, LwinNW, ZawM, HuiKS, ChenF. Flexible fiber-shape Zn-MnO2 battery for wearable electronic devices. Journal of Energy Storage, 2024, 98113010

[52]

SubjalearndeeN, HeN, ChengH, TesatchabutP, EiamlamaiP, LimthongkulP, IntasantaV, GaoW, ZhangX. Gamma(ɣ)-MnO2/rGO fibered cathode fabrication from wet spinning and dip coating techniques for cable-shaped Zn-Ion batteries. Adv Fiber Mater, 2022, 4: 457-474

[53]

WuJ, ZhouJ, GuoJ, MengY, XieY, LingY, ZhengB, WangZ, ZhangQ. Self-supporting nickel-doped V2O5 nanoarrays as bifunctional electrodes for wearable aqueous zinc-ion batteries and pressure sensors. Carbon, 2024, 223119009

[54]

Li Y, Guan Q, Cheng J, Wang B. Amorphous H0.82MoO3.26 cathodes based long cyclelife fiber-shaped Zn-ion battery for wearable sensors. Energy Storage Mater 2022;49:227–235.

[55]

ChengX, YangX, ZhangY, LvP, YangJ, HuangF, WeiQ. Sulfur vacancies tune the charge distribution of NiCo2S4 for boosting the energy density of stretchable yarn-based Zn Ion batteries. Adv Fiber Mater, 2023, 5: 650-661

[56]

LiH, LiuZ, LiangG, HuangY, HuangY, ZhuM, PeiZ, XueQ, TangZ, WangY. Waterproof and tailorable elastic rechargeable yarn zinc ion batteries by a cross-linked polyacrylamide electrolyte. ACS Nano, 2018, 12: 3140-3148

[57]

LiM, LiZ, YeX, ZhangX, QuL, TianM. Tendril-inspired 900% ultrastretching fiber-based Zn-Ion batteries for wearable energy textiles. ACS Appl Mater Interfaces, 2021, 13: 17110-17117

[58]

LiT, XuQ, WaqarM, YangH, GongW, YangJ, ZhongJ, LiuZ. Millisecond-induced defect chemistry realizes high-rate fiber-shaped zinc-ion battery as a magnetically soft robot. Energy Storage Materials, 2023, 55: 64-72

[59]

LiuF, XuS, GongW, ZhaoK, WangZ, LuoJ, LiC, SunY, XueP, WangC, WeiL, LiQ, ZhangQ. Fluorescent fiber-shaped aqueous zinc-Ion batteries for bifunctional multicolor-emission/energy-storage textiles. ACS Nano, 2023, 17: 18494-18506

[60]

WangGY, LiGX, TangYD, ZhaoZ, YuW, MengCZ, GuoSJ. Flexible and antifreezing fiber-shaped solid-state zinc-ion batteries with an integrated bonding structure. J Phys Chem Lett, 2023, 14: 3512-3520

[61]

TranMX, LiuG, ArdhiREA, LeeS-W, LeeJK. A flexible fiber-shaped solar chargeable zinc–polyaniline battery with a fullerene-based electron transfer layer. Energy Storage Mater, 2024, 65103145

[62]

MaL, LiN, LongC, DongB, FangD, LiuZ, ZhaoY, LiX, FanJ, ChenS, ZhangS, ZhiC. Achieving both high voltage and high capacity in aqueous zinc-ion battery for record high energy density. Adv Funct Mater, 2019, 291906142

[63]

RuanP, LiangS, LuB, FanHJ, ZhouJ. Design strategies for high-energy-density aqueous zinc batteries. Angew Chem, 2022, 134e202200598

[64]

LiuP, LvR, HeY, NaB, WangB, LiuH. An integrated, flexible aqueous Zn-ion battery with high energy and power densities. J Power Sources, 2019, 410: 137-142

[65]

XiaoX, ZhengZ, ZhongX, GaoR, PiaoZ, JiaoM, ZhouG. Rational design of flexible Zn-based batteries for wearable electronic devices. ACS Nano, 2023, 17: 1764-1802

[66]

YuP, ZengY, ZhangH, YuM, TongY, LuX. Flexible Zn-Ion batteries: recent progresses and challenges. Small, 2019, 15e1804760

[67]

WangW, LiC, LiuS, ZhangJ, ZhangD, DuJ, ZhangQ, YaoY. Flexible quasi-solid-state aqueous zinc-ion batteries: design principles, functionalization strategies, and applications. Adv Energy Mater, 2023, 132300250

[68]

ZhuX, ZhangH, HuangY, HeE, ShenY, HuangG, YuanS, DongX, ZhangY, ChenR, ZhangX, WangY. Recent progress of flexible rechargeable batteries. Sci Bull, 2024, 69: 3730-3755

[69]

DongH, LiJ, GuoJ, LaiF, ZhaoF, JiaoY, BrettDJ, LiuT, HeG, ParkinIP. Insights on flexible zinc-ion batteries from lab research to commercialization. Adv Mater, 2021, 332007548

[70]

HuangJQ, GuoX, LinX, ZhuY, ZhangB. Hybrid aqueous/organic electrolytes enable the high-performance Zn-Ion batteries. Research (Wash D C), 2019, 20192635310

[71]

YangJ, ZhaoR, WangY, BaiY, WuC. Regulating uniform Zn deposition via hybrid artificial layer for stable aqueous Zn-Ion batteries. Energy Mater Adv, 2022, 20229809626

[72]

KimHJ, KimS, YuJH, LimJ-H, YashiroH, MyungS-T. Unlocking long-term stability: electrolyte additives for suppressing zinc dendrite growth in aqueous zinc metal batteries. Chem Eng J, 2025, 506160017

[73]

ZhouJ, ZhangZ, JiangW, HouS, YangK, LiQ, PanL, YangJ. Ion-sieving Janus separator modified by Ti3C2Tx toward dendrite-free zinc-ion battery. J Alloy Compd, 2023, 950169836

[74]

ZhouL, LiS, JainA, ChenG, GuoD, KangJ, ZhaoY. Lithium battery thermal management based on lightweight stepped-channel liquid cooling. J Electrochem Energy Convers Stor, 2024, 21031012

[75]

WangC, ChenY. Unsupervised dynamic prognostics for abnormal degradation of lithium-ion battery. Appl Energy, 2024, 365123280

Funding

Research Fund for International Scientists, National Natural Science Foundation of China.(52350710795)

Shanghai Pujiang Program(24PJA090)

RIGHTS & PERMISSIONS

Donghua University, Shanghai, China

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