Multifunctional Semiconducting Fibers for Visual Detection of Sarin Gas

Abstract

There is a growing need for protective instruments that can be used in extreme environments, including those encountered during exoplanet exploration, anti-terrorism activities, and in chemical plants. These instruments should have the ability to detect external threats visually and monitor internal physiological signals in real time for maximum safety. To address this need, multifunctional semiconducting fibers with visual detection ranging from yellow to red and near-field communication (NFC) capabilities have been developed for use in personal protective clothing. A composite conductive yarn with semiconducting fluorescent probe molecules is embroidered on the clothing, forming an NFC coil that allows for the visual monitoring of atmospheric safety through color changes. The fluorescence detection system was able to selectively detect diethyl chlorophosphate (DCP), a substitute for the toxic gas sarin, with a detection limit of 6.08 ppb, which is lower than the life-threatening concentration of sarin gas. Furthermore, an intelligent protective suit with the abovementioned dual functions was fabricated with good mechanical cycle stability and repeatability. Real-time physiological signals such as the temperature and humidity of the wearer could be read through the NFC conveniently. Such intelligent protective suits can quickly provide an early warning to the identified low-dose DCP and evaluate the health of wearer according to the changes in physiological signals. This study offers a smart, low-cost strategy for designing intelligent protective devices for extreme environments.

Funding

Fundamental Research Funds for the Central Universities(2232021G-12); National Natural Science Foundation of China(62022085); Science and Technology Commission of Shanghai Municipality(21520710700)