In Situ Fabrication of Superfine Perovskite Composite Nanofibers with Ultrahigh Stability by One-Step Electrospinning Toward White Light-Emitting Diode

Abstract

All-inorganic CsPbX₃ (X = Cl, Br, I) perovskite nanocrystals (NCs) are emerging as promising candidate materials for optoelectronic devices due to their splendid optical and electrical properties. However, the intrinsic instability greatly limits their practical application. Herein, a feasible strategy is proposed for fabricating highly stable and luminescent CsPbBr₃@PVDF-HFP/PS nanofibers by combining one-step electrospinning method with 1H,1H,2H,2H-perfluorodecyltrimethoxysilane (PFDTMS)-assisted post-treatment. The bright-emitting CsPbBr₃ NCs can be effectively encapsulated within polymer nanofibers, which exhibit ultrafine diameter of only 88.1 ± 2.8 nm and high photoluminescence quantum yield (PLQY) of 87.9% via rationally optimizing the electrospinning parameters, concentration of perovskite precursors and ligands. Most importantly, the superhydrophobic surface structures of nanofibers are formed by the hydrolysis and condensation of PFDTMS under moist environment. Benefiting from the double effective protection of polymer matrices and hydrophobic PFDTMS oligomers against moisture erosion, the CsPbBr₃@PVDF-HFP/PS nanofibers present an obviously improved stability, which can retain 90% initial PL intensity after water immersion for 70 days. Furthermore, an efficient white light-emitting diode with wide color gamut covering 117% of National Television System Committee (NTSC) standard is successfully fabricated based on the composite nanofiber membranes, suggesting their promising prospect for solid-state lighting and display applications.

Graphical Abstract

Superfine perovskite nanofibers with efficient fluorescence and ultrahigh stability are fabricated by combining one-step electrospinning method with PFDTMS-assisted post-treatment.

Funding

National Key Research and Development Program of China(2021YFB3500504); National Natural Science Foundation of China(52103359); Innovation Program of Shanghai Municipal Education Commission(2017-01-07-00-03-E00025); Shanghai Sailing Program(21YF1400600); Fundamental Research Funds for the Central Universities(2232020G-07)