Elastic and Stretchable Functional Fibers: A Review of Materials, Fabrication Methods, and Applications

Abstract

Elastic and stretchable functional fibers have drawn attentions from wide research field because of their unique advantages including high dynamic bending elasticity, stretchability and high mechanic strength. Lots of efforts have been made to find promising soft materials and improve the processing methods to fabricate the elastomer fibers with controllable fiber geometries and designable functionalities. Significant progress has been made and various interdisciplinary applications have been demonstrated based on their unique mechanical performance. A series of remarkable applications, involving biomedicine, optics, electronics, human machine interfaces etc., have been successfully achieved. Here, we summarize main processing methods to fabricate soft and stretchable functional fibers using different types of elastic materials, which are either widely used or specifically developed. We also introduce some representative applications of multifunctional elastic fibers to reveal this promising research area. All these reported applications indicate that the fast innovated interdisciplinary area is of great potential and inspire more remarkable ideas in fiber sensing, soft electronics, functional fiber integration and other related research fields.

Graphic abstract

Keywords

Elastic fibers / Stretchable fibers / Fiber sensing / Multifunctional fibers / Engineering / Materials Engineering

References

[1] XiongJ, LeePS. Progress on wearable triboelectric nanogenerators in shapes of fiber, yarn, and textile. Sci. Technol. Adv. Mater., 2019, 20: 837.

[2] DongK, PengX, WangZL. Fiber/fabric-based piezoelectric and triboelectric nanogenerators for flexible/stretchable and wearable electronics and artificial intelligence. Adv. Mater., 2020, 32: 1902549.

[3] YanW, RichardI, KurtulduG, JamesND, SchiavoneG, SquairJW, Nguyen-DangT, DasGupta T, QuY, CaoJD, IgnatansR, LacourSP, TileliV, CourtineG, LöfflerJF, SorinF. Structured nanoscale metallic glass fibres with extreme aspect ratios. Nat. Nanotech., 2020, 15: 875.

[4] ZhangJ, ZhangT, ZhangH, WangZ, LiC, WangZ, LiK, HuangX, ChenM, ChenZ. Single-crystal SnSe thermoelectric fibers via laser-induced directional crystallization: from 1D fibers to multidimensional fabrics. Adv. Mater., 2020, 32: 2002702.

[5] YangZ, RenJ, ZhangZ, ChenX, GuanG, QiuL, ZhangY, PengH. Recent advancement of nanostructured carbon for energy applications. Chem. Rev., 2015, 115: 5159.

[6] WangZ, WuT, WangZ, ZhangT, ChenM, ZhangJ, LiuL, QiM, ZhangQ, YangJ. Designer patterned functional fibers via direct imprinting in thermal drawing. Nat. Commun., 2020, 11: 1

[7] YanW, PageA, Nguyen-DangT, QuY, SordoF, WeiL, SorinF. Advanced multimaterial electronic and optoelectronic fibers and textiles. Adv. Mater., 2019, 31: 1802348.

[8] LokeG, YanW, KhudiyevT, NoelG, FinkY. Recent progress and perspectives of thermally drawn multimaterial fiber electronics. Adv Mater., 2020, 32: 1904911.

[9] YanW, QuY, GuptaTD, DargaA, NguyênDT, PageAG, RossiM, CeriottiM, SorinF. Semiconducting nanowire-based optoelectronic fibers. Adv. Mater., 2017, 29: 1700681.

[10] FrankJA, AntoniniM-J, AnikeevaP. Next-generation interfaces for studying neural function. Nat. Biotechnol., 2019, 37: 1013.

[11] QiM, ZhangNMY, LiK, TjinSC, WeiL. Hybrid plasmonic fiber-optic Sensors. Sensors, 2020, 20: 3266.

[12] YanW, DongC, XiangY, JiangS, LeberA, LokeG, XuW, HouC, ZhouS, ChenM. Thermally drawn advanced functional fibers: new frontier of flexible electronics. Mater. Today., 2020, 35: 168.

[13] DongC, PageAG, YanW, Nguyen-DangT, SorinF. Microstructured multimaterial fibers for microfluidic sensing. Adv. Mater. Technol., 2019, 4: 1900417.

[14] SunH, YouX, JiangY, GuanG, FangX, DengJ, ChenP, LuoY, PengH. Self-healable electrically conducting wires for wearable microelectronics. Angew. Chem. Int. Ed., 2014, 53: 9526.

[15] YuD, GohK, WangH, WeiL, JiangW, ZhangQ, DaiL, ChenY. Scalable synthesis of hierarchically structured carbon nanotube-graphene fibres for capacitive energy storage. Nat. Nanotech., 2014, 9: 555.

[16] SunH, ZhangY, ZhangJ, SunX, PengH. Energy harvesting and storage in 1D devices. Nat. Rev. Mater., 2017, 2: 17023.

[17] LiaoM, YeL, ZhangY, ChenT, PengH. The recent advance in fiber-shaped energy storage devices. Adv. Electron. Mater., 2019, 5: 1800456.

[18] ZhouY, WangC-H, LuW, DaiL. Recent advances in fiber-shaped supercapacitors and lithium-ion batteries. Adv Mater., 2020, 32: 1902779.

[19] YangS, MachariaDK, AhmedS, ZhuB, ZhongQ, WangH, ChenZ. Flexible and reusable non-woven fabric photodetector based on polypyrrole/crystal violate lactone for NIR light detection and writing. Adv. Fiber Mater., 2020, 2: 150.

[20] Wei L. Advanced Fiber Sensing Technologies. Springer; 2020.

[21] WangL, FuX, HeJ, ShiX, ChenT, ChenP, WangB, PengH. Application challenges in fiber and textile electronics. Adv. Mater., 2020, 32: 1901971.

[22] WengW, YangJ, ZhangY, LiY, YangS, ZhuL, ZhuM. A route toward smart system integration: from fiber design to device construction. Adv. Mater., 2020, 32: 1902301.

[23] Chen T., Hao R., Peng H., Dai L. High-performance, stretchable, wire-shaped supercapacitors. Angew. Chem. In.t Ed. 2015, 54, 618.

[24] SunH, XieS, LiY, JiangY, SunX, WangB, PengH. Large-area supercapacitor textiles with novel hierarchical conducting structures. Adv. Mater., 2016, 28: 8431.

[25] ShiQ, SunJ, HouC, LiY, ZhangQ, WangH. Advanced functional fiber and smart textile. Adv. Fiber Mater., 2019, 1: 3.

[26] GaoP, LiJ, ShiQ. A hollow polyethylene fiber-based artificial muscle. Adv. Fiber Maters., 2019, 1: 214.

[27] LiJ, SunJ, WuD, HuangW, ZhuM, ReichmanisE, YangS. Functionalization-directed stabilization of hydrogen-bonded polymer complex fibers: elasticity and conductivity. Adv. Fiber Mater., 2019, 1: 71.

[28] ChenJ, PakdelE, XieW, SunL, XuM, LiuQ, WangD. High-performance natural melanin/poly(vinyl alcohol-co-ethylene) nanofibers/PA6 Fiber for twisted and coiled fiber-based actuator. Adv. Fiber Mater., 2020, 2: 64.

[29] LeberA, CholstB, SandtJ, VogelN, KolleM. Stretchable thermoplastic elastomer optical fibers for sensing of extreme deformations. Adv. Funct. Mater., 2019, 29: 1802629.

[30] CooperCB, ArutselvanK, LiuY, ArmstrongD, LinY, KhanMR, GenzerJ, DickeyMD. Stretchable capacitive sensors of torsion, strain, and touch using double helix liquid metal fibers. Adv. Funct Mater., 2017, 27: 1605630.

[31] Tong Y., Feng Z., Kim J., Robertson J. L., Jia X., Johnson B. N. 3D printed stretchable triboelectric nanogenerator fibers and devices. Nano Energy. 2020, 104973.

[32] XuPA, MishraAK, BaiH, AubinCA, ZulloL, ShepherdRF. Optical lace for synthetic afferent neural networks. Sci. Robot., 2019, 4: 34.

[33] ZhangQ, LiL, LiH, TangL, HeB, LiC, PanZ, ZhouZ, LiQ, SunJ, WeiL, FanX, ZhangT, YaoY. Ultra-endurance coaxial-fiber stretchable sensing systems fully powered by sunlight. Nano Energy., 2019, 60: 267.

[34] PengH, ShiX, ZuoY, ZhaiP, ShenJ, YangY, GaoZ, LiaoM, WangJ, XuXLarge-area display textiles integrated with functional systems., 2020.

[35] QuY, Nguyen-DangT, PageAG, YanW, DasGupta T, RotaruGM, RossiRM, FavrodVD, BartolomeiN, SorinF. Superelastic multimaterial electronic and photonic fibers and devices via thermal drawing. Adv. Mater., 2018, 30: 1707251.

[36] YuL, ParkerS, XuanH, ZhangY, JiangS, TousiM, ManteghiM, WangA, JiaX. Flexible multi-material fibers for distributed pressure and temperature sensing. Adv. Funct. Mater., 2020, 30: 1908915.

[37] LeberA, DongC, ChandranR, GuptaTD, BartolomeiN, SorinF. Soft and stretchable liquid metal transmission lines as distributed probes of multimodal deformations. Nat. Electron., 2020, 1: 11

[38] Zhao H., O’Brien K., Li S., Shepherd R. F. Optoelectronically innervated soft prosthetic hand via stretchable optical waveguides. Sci. Robot. 2016, 1, eaai7529.

[39] Chang-YenDA, EichRK, GaleBK. A monolithic PDMS waveguide system fabricated using soft-lithography techniques. J. Lightwave Technol., 2005, 23: 2088.

[40] KeeJS, PoenarDP, NeuzilP, YobasL. Design and fabrication of poly (dimethylsiloxane) single-mode rib waveguide. Opt. Express., 2009, 17: 11739.

[41] CaiZ, QiuW, ShaoG, WangW. A new fabrication method for all-PDMS waveguides. Sens. Actuators A: Physical., 2013, 204: 44.

[42] MissinneJ, KalathimekkadS, Van HoeB, BosmanE, VanfleterenJ, Van SteenbergeG. Stretchable optical waveguides. Opt. Express., 2014, 22: 4168.

[43] GuoJ, NiuM, YangC. Highly flexible and stretchable optical strain sensing for human motion detection. Optica., 2017, 4: 1285.

[44] GuoJ, ZhouB, YangC, DaiQ, KongL. Stretchable and temperature-sensitive polymer optical fibers for wearable health monitoring. Adv. Funct. Mater., 2019, 29: 1902898.

[45] ElmogiA, BosmanE, MissinneJ, Van SteenbergeG. Comparison of epoxy-and siloxane-based single-mode optical waveguides defined by direct-write lithography. Opt. Mater., 2016, 52: 26.

[46] ChoiM, HumarM, KimS, YunSH. Step-index optical fiber made of biocompatible hydrogels. Adv. Mater., 2015, 27: 4081.

[47] GuoJ, LiuX, JiangN, YetisenAK, YukH, YangC, KhademhosseiniA, ZhaoX, YunSH. Highly stretchable, strain sensing hydrogel optical fibers. Adv. Mater., 2016, 28: 10244.

[48] YetisenAK, JiangN, FallahiA, MontelongoY, Ruiz-EsparzaGU, TamayolA, ZhangYS, MahmoodI, YangSA, KimKS. Glucose-sensitive hydrogel optical fibers functionalized with phenylboronic acid. Adv. Mater., 2017, 29: 1606380.

[49] ZhuS, SoJH, MaysR, DesaiS, BarnesWR, PourdeyhimiB, DickeyMD. Ultrastretchable fibers with metallic conductivity using a liquid metal alloy core. Adv. Funct. Mater., 2013, 23: 2308.

[50] LuC, ParkS, RichnerTJ, DerryA, BrownI, HouC, RaoS, KangJ, MoritzCT, FinkY, AnikeevaP. Flexible and stretchable nanowire-coated fibers for optoelectronic probing of spinal cord circuits. Sci. Adv., 2017, 3: e1600955.

[51] ManocchiAK, DomachukP, OmenettoFG, YiH. Facile fabrication of gelatin-based biopolymeric optical waveguides. Biotechnol. Bioeng., 2009, 103: 725.

[52] SordoF, JanecekER, QuY, MichaudV, StellacciF, EngmannJ, WoosterTJ, SorinF. Microstructured fibers for the production of food. Adv. Mater., 2019, 31: 1807282.

[53] QinH, OwyeungRE, SonkusaleSR, PanzerMJ. Highly stretchable and nonvolatile gelatin-supported deep eutectic solvent gel electrolyte-based ionic skins for strain and pressure sensing. J. Mater. Chem. C., 2019, 7: 601.

[54] ShanD, ZhangC, KalabaS, MehtaN, KimGB, LiuZ, YangJ. Flexible biodegradable citrate-based polymeric step-index optical fiber. Biomaterials., 2017, 143: 142.

[55] NizamogluS, GatherMC, HumarM, ChoiM, KimS, KimKS, HahnSK, ScarcelliG, RandolphM, RedmondRW. Bioabsorbable polymer optical waveguides for deep-tissue photomedicine. Nat. Commun., 2016, 7: 1.

[56] FuR, LuoW, NazempourR, TanD, DingH, ZhangK, YinL, GuanJ, ShengX. Implantable and biodegradable poly (l-lactic acid) fibers for optical neural interfaces. Adv. Opt. Mater., 2018, 6: 1700941.

[57] ParkerST, DomachukP, AmsdenJ, BressnerJ, LewisJA, KaplanDL, OmenettoFG. Biocompatible silk printed optical waveguides. Adv. Mater., 2009, 21: 2411.

[58] HubyN, ViéV, RenaultA, BeaufilsS, LefevreT, Paquet-MercierF, PézoletM, BêcheB. Native spider silk as a biological optical fiber. Appl. Phys. Lett., 2013, 102: 123702.

[59] ApplegateMB, PerottoG, KaplanDL, OmenettoFG. Biocompatible silk step-index optical waveguides. Biomedical. Opt. express., 2015, 6: 4221.

[60] ChenG, MatsuhisaN, LiuZ, QiD, CaiP, JiangY, WanC, CuiY, LeowWR, LiuZ. Plasticizing silk protein for on-skin stretchable electrodes. Adv. Mater., 2018, 30: 1800129.

[61] Loke G., Yan W., Khudiyev T., Noel G., Fink Y. Recent progress and perspectives of thermally drawn multimaterial fiber electronics. Adv. Mater. 2019, 1904911.

[62] LokeG, YuanR, ReinM, KhudiyevT, JainY, JoannopoulosJ, FinkY. Structured multimaterial filaments for 3D printing of optoelectronics. Nat. Commun., 2019, 10: 4010.

[63] YangZ, DengJ, SunX, LiH, PengH. Stretchable, wearable dye-sensitized solar cells. Adv. Mater., 2014, 26: 2643.

[64] YangZ, DengJ, ChenX, RenJ, PengH. A highly stretchable, fiber-shaped supercapacitor. Angew. Chem. Int. Ed., 2013, 52: 13453.

[65] SunH, FuX, XieS, JiangY, PengH. Electrochemical capacitors with high output voltages that mimic electric eels. Adv. Mater., 2016, 28: 2070.

[66] GuoJ, ZhouB, ZongR, PanL, LiX, YuX, YangC, KongL, DaiQ. Stretchable and highly sensitive optical strain sensors for human-activity monitoring and healthcare. ACS Appl. Mater. Interfaces., 2019, 11: 33589.

[67] SimHJ, LeeDY, KimH, ChoiY-B, KimH-H, BaughmanRH, KimSJ. Stretchable fiber biofuel cell by rewrapping multiwalled carbon nanotube sheets. Nano Lett., 2018, 18: 5272.

[68] ZhangB, LeiJ, QiD, LiuZ, WangY, XiaoG, WuJ, ZhangW, HuoF, ChenX. Stretchable conductive fibers based on a cracking control strategy for wearable electronics. Adv. Funct. Mater., 2018, 28: 1801683.

[69] WangL, XieS, WangZ, LiuF, YangY, TangC, WuX, LiuP, LiY, SaiyinH, ZhengS, SunX, XuF, YuH, PengH. Functionalized helical fibre bundles of carbon nanotubes as electrochemical sensors for long-term in vivo monitoring of multiple disease biomarkers. Nat. Bio. Eng., 2020, 4: 159.

[70] YangX, LiL, YangD, NieJ, MaG. Electrospun core-Shell fibrous 2D scaffold with biocompatible poly(glycerol sebacate) and poly-l-lactic acid for wound healing. Adv. Fiber Mater., 2020, 2: 105.

[71] HeoYJ, ShibataH, OkitsuT, KawanishiT, TakeuchiS. Long-term in vivo glucose monitoring using fluorescent hydrogel fibers. Proc. Natl. Acad. Sci., 2011, 108: 13399.

[72] XuB, MaS, XiangY, ZhangJ, ZhuM, WeiL, TaoG, DengD. In-Fiber structured particles and filament arrays from the perspective of fluid instabilities. Adv. Fiber Mater., 2020, 2: 1.

[73] KanikM, OrgucS, VarnavidesG, KimJ, BenavidesT, GonzalezD, AkintiloT, TasanCC, ChandrakasanAP, FinkY, AnikeevaP. Strain-programmable fiber-based artificial muscle. Science., 2019, 365: 145.

[74] FengZ, YangS, JiaS, ZhangY, JiangS, YuL, LiR, SongG, WangA, MartinT, ZuoL, JiaX. Scalable, washable and lightweight triboelectric-energy-generating fibers by the thermal drawing process for industrial loom weaving. Nano Energy., 2020, 74: 104805.

[75] DongC, LeberA, DasGupta T, ChandranR, VolpiM, QuY, Nguyen-DangT, BartolomeiN, YanW, SorinF. High-efficiency super-elastic liquid metal based triboelectric fibers and textiles. Nat. Commun., 2020, 11: 3537.

Funding

Singapore Ministry of Education Academic Research Fund Tier 2(MOE2019-T2-2-127)

Singapore Ministry of Education Academic Research Fund Tier 2(T2EP50120-0005)

A*STAR under AME IRG(A2083c0062)

Singapore Ministry of Education Academic Research Fund Tier 1(RG90/19)

Singapore Ministry of Education Academic Research Fund Tier 1(RG73/19)

Singapore National Research Foundation Competitive Research Program(NRF-CRP18-2017-02)

RIGHTS & PERMISSIONS

Donghua University, Shanghai, China