Cathodes with MnO2 catalysts for metal fuel battery
Songbo WEI, He LIU, Ran WEI, Lin CHEN
Cathodes with MnO2 catalysts for metal fuel battery
A series of cathodes with MnO2 catalysts of metal fuel battery were prepared. The catalyst slurry was treated by ultrasonic dispersion under the ultrasonic time of 20 min, 40 min and 60 min. The cathodes were also dried with the temperature of 90°C, 120°C and 150°C. Besides, the microstructures of the cathodes and discharging performance were investigated. The results indicated that the ultrasonic time and drying temperature had a remarkable influence on the electric current densities, but had little effect on the open-circuit voltage. The effects of oxygen on the current density and voltage of cathode were also studied, and it was found that the method of blowing oxygen to cathode could increase the current density of the metal fuel battery.
metal fuel battery / cathode / current density / ultrasonic dispersion / oxygen supply
[1] |
Liu Y, Sun Q, Li W, Adair K R, Li J, Sun X. A comprehensive review on recent progress in aluminum air batteries. Green Energy & Environment, 2017, 2(3): 246–277
CrossRef
Google scholar
|
[2] |
Pollet B G, Staffell I, Shang J L. Current status of hybrid, battery and fuel cell electric vehicles: from electrochemistry to market prospects. Electrochimica Acta, 2012, 84: 235–249
CrossRef
Google scholar
|
[3] |
Dunn B, Kamath H, Tarascon J M. Electrical energy storage for the grid: a battery of choices. Science, 2011, 334(6058): 928–935
CrossRef
Google scholar
|
[4] |
Li Q, Bjerrum N J. Aluminum as anode for energy storage and conversion: a review. Journal of Power Sources, 2002, 110(1): 1–10
CrossRef
Google scholar
|
[5] |
Bruce P G, Freunberger S A, Hardwick L J, Tarascon J M. Li-O2 and Li-S batteries with high energy storage. Nature Materials, 2012, 11(1): 19–29
CrossRef
Google scholar
|
[6] |
Haneda T, Ono Y, Ikegami T, Akisawa A. Technological assessment of residential fuel cells using hydrogen supply systems for fuel cell vehicles. International Journal of Hydrogen Energy, 2017, 42(42): 26377–26388
CrossRef
Google scholar
|
[7] |
Eriksson E L V, Gray E M. Optimization and integration of hybrid renewable energy hydrogen fuel cell energy systems –– a critical review. Applied Energy, 2017, 202: 348–364
CrossRef
Google scholar
|
[8] |
Wu G. Current challenge and perspective of PGM-free cathode catalysts for PEM fuel cells. Frontiers in Energy, 2017, 11(3): 286–298
CrossRef
Google scholar
|
[9] |
Moghaddam R B, Shahgaldi S, Li X. A facile synthesis of high activity cube-like Pt/carbon composites for fuel cell application. Frontiers in Energy, 2017, 11(3): 245–253
CrossRef
Google scholar
|
[10] |
Zhang C, Shen X, Pan Y, Peng Z. A review of Pt-based electrocatalysts for oxygen reduction reaction. Frontiers in Energy, 2017, 11(3): 268–285
CrossRef
Google scholar
|
[11] |
Rahman M A, Wang X, Wen C. High energy density metal-air batteries: a review. Journal of the Electrochemical Society, 2013, 160(10): A1759–A1771
CrossRef
Google scholar
|
[12] |
Cheng F, Chen J. Metal-air batteries: from oxygen reduction electrochemistry to cathode catalysts. Chemical Society Reviews, 2012, 41(6): 2172–2192
CrossRef
Google scholar
|
[13] |
Danner T, Eswara S, Schulz V P, Latz A. Characterization of gas diffusion electrodes for metal-air batteries. Journal of Power Sources, 2016, 324: 646–656
CrossRef
Google scholar
|
[14] |
Mokhtar M, Talib M Z M, Majlan E H, Tasirin S M, Ramli W M F W, Daud W R W, Sahari J. Recent developments in materials for aluminum–air batteries: a review. Journal of Industrial and Engineering Chemistry, 2015, 32: 1–20
CrossRef
Google scholar
|
[15] |
Liu Y, Sun Q, Li W, Adair K R, Li J, Sun X. A comprehensive review on recent progress in aluminum air batteries. Green Energy & Environment, 2017, 2(3): 246–277
CrossRef
Google scholar
|
[16] |
Liu K, Peng Z, Wang H, Ren Y, Liu D, Li J, Tang Y, Zhang N. Fe3C@Fe/N doped graphene-like carbon sheets as a highly efficient catalyst in al-air batteries. Journal of the Electrochemical Society, 2017, 164(6): F475–F483
CrossRef
Google scholar
|
[17] |
Wang X, Sebastian P J, Smit M A, Yang H, Gamboa S A. Studies on the oxygen reduction catalyst for zinc–air battery electrode. Journal of Power Sources, 2003, 124(1): 278–284
CrossRef
Google scholar
|
[18] |
Mori R. Electrochemical properties of a rechargeable aluminum–air battery with a metal–organic framework as air cathode material. RSC Advances, 2017, 7(11): 6389–6395
CrossRef
Google scholar
|
[19] |
Lima F H B, Calegaro M L, Ticianelli E A. Electrocatalytic activity of manganese oxides prepared by thermal decomposition for oxygen reduction. Electrochimica Acta, 2007, 52(11): 3732–3738
CrossRef
Google scholar
|
[20] |
Cheng F, Su Y, Liang J, Tao Z, Chen J. MnO2-based nanostructures as catalysts for electrochemical oxygen reduction in alkaline media. Chemistry of Materials, 2010, 22(3): 898–905
CrossRef
Google scholar
|
[21] |
Byon H R, Suntivich J, Shao-Horn Y. Graphene-based non-noble-netalcatalysts for oxygen reduction reaction in acid. Chemistry of Materials, 2011, 23(15): 3421–3428
CrossRef
Google scholar
|
[22] |
Yu L. Preparation of PTFE microporous fiber with catalytic capability. Dissertation for the Master’s Degree. Hangzhou: Zhejiang Sci-Tech University, 2009 (in Chinese)
|
[23] |
Yang W, Li Y, Li B. Influence of ultrasonic pretreatment on modification effect of nano-sized titanium dioxide. Inorganic Chemicals Industry, 2008, 40(8): 27–29
|
[24] |
Wang Y, Zeng X, Liu H, Song S. Effect of preparation conditions of catalyst in on the electrochemical properties of Pt/C catalyst. Chinese Journal of Catalysis, 2011, 32(1): 184–188
|
[25] |
Cui C. Research and preparation of air electrode for zinc-air battery. Dissertation for the Master’s Degree. Harbin: Harbin Institute of Technology, 2013 (in Chinese)
|
[26] |
Wang X, Sebastian P J, Smit M A, Yang H, Gamboa S A. Studies on the oxygen reduction catalyst for zinc–air battery electrode. Journal of Power Sources, 2003, 124(1): 278–284
CrossRef
Google scholar
|
[27] |
Yan B. Preparation and characterization of air cathode for aluminum-air battery. Dissertation for the Master’s Degree. Harbin: Harbin Institute of Technology, 2010 (in Chinese)
|
/
〈 | 〉 |