Recent advances in multifaceted applications of MOF-based hydrogels

Rui He , Jiajun He , Jie Shen , Huide Fu , Yabin Zhang , Ben Wang

Soft Science ›› 2024, Vol. 4 ›› Issue (4) : 37

PDF
Soft Science ›› 2024, Vol. 4 ›› Issue (4) :37 DOI: 10.20517/ss.2024.32
Review Article

Recent advances in multifaceted applications of MOF-based hydrogels

Author information +
History +
PDF

Abstract

Metal-organic frameworks (MOFs) have recently garnered attention due to their intriguing physiochemical properties; however, their instability and unsatisfactory processability have limited them from achieving a wide range of applications. Therefore, structural new MOFs and MOF-based hydrogels have been developed to address associated drawbacks (such as inherent brittleness and instability in the crystalline state). The development of MOF-based hydrogels has been the focus of some recent attempts. Compared to the original MOFs, they have several better properties (such as improved mechanical strengths). This review will provide the latest overviews of current research developments on MOF-based hydrogels. We primarily focus on the classification of these hydrogels and their associated synergistic effects. We also emphasize microscale composite design, macroscale performance, and extended applications in catalysis, water treatment and biomedicine. Further, we anticipate that this review will be valuable for individuals seeking insights into the applications of MOFs-based hydrogels.

Keywords

Metal-organic frameworks / hydrogel / water remediation / targeted delivery

Cite this article

Download citation ▾
Rui He, Jiajun He, Jie Shen, Huide Fu, Yabin Zhang, Ben Wang. Recent advances in multifaceted applications of MOF-based hydrogels. Soft Science, 2024, 4(4): 37 DOI:10.20517/ss.2024.32

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

Mane PV,Yap PL,Kurkuri MD.Unveiling cutting-edge advances in high surface area porous materials for the efficient removal of toxic metal ions from water.Prog Mater Sci2024;146:101314

[2]

Yang Q,Jiang HL.Metal-organic frameworks meet metal nanoparticles: synergistic effect for enhanced catalysis.Chem Soc Rev2017;46:4774-808

[3]

Uthappa UT,Arvind OR.Engineering MIL-100(Fe) on 3D porous natural diatoms as a versatile high performing platform for controlled isoniazid drug release, Fenton’s catalysis for malachite green dye degradation and environmental adsorbents for Pb2+ removal and dyes.Appl Surf Sci2020;528:146974

[4]

Li D,Zhao J,Lu JY.Metal-organic frameworks based upon non-zeotype 4-connected topology.Coordin Chem Rev2014;261:1-27

[5]

Chen Y,Pei X.A solvent-free hot-pressing method for preparing metal-organic-framework coatings.Angew Chem Int Ed Engl2016;55:3419-23

[6]

Wang B,Guo Z.Recent advances in atmosphere water harvesting: design principle, materials, devices, and applications.Nano Today2021;40:101283

[7]

Ding Y,Halder S.Emerging semiconductors and metal-organic-compounds-related photocatalysts for sustainable hydrogen peroxide production.Matter2022;5:2119-67

[8]

Li R,Lu H.Metal-organic frameworks as platforms for the removal of per- and polyfluoroalkyl substances from contaminated waters.Matter2022;5:3161-93

[9]

Sun J,Ho KWK.“Slow walk” mimetic tensile loading maintains human meniscus tissue resident progenitor cells homeostasis in photocrosslinked gelatin hydrogel. Bioact Mater 2023;25:256-72.

[10]

Zhang J.Metal-organic gels: from discrete metallogelators to coordination polymers.Coordin Chem Rev2013;257:1373-408

[11]

Miao Q,Yang J.MOF/hydrogel composite-based adsorbents for water treatment: a review.J Water Process Eng2022;50:103348

[12]

Tanaka S,Ikenaga N,Nakagawa K.Recent progress and challenges in the field of metal–organic framework-based membranes for gas separation.Compounds2024;4:141-71

[13]

Lu Y,Wang C,Liu Y.Enhancing hydrogel-based long-lasting chemiluminescence by a platinum-metal organic framework and its application in array detection of pesticides and d-amino acids.Nanoscale2020;12:4959-67

[14]

Mohan B,Gupta RK.Hydrogen-bonded organic frameworks (HOFs): multifunctional material on analytical monitoring.TrAC Trend Anal Chem2024;170:117436

[15]

Park J,Lee S,Lee E.Conductive hydrogel constructs with three-dimensionally connected graphene networks for biomedical applications.Chem Eng J2022;446:137344

[16]

Zhao L,Wang J.Boosting solar-powered interfacial water evaporation by architecting 3D interconnected polymetric network in CNT cellular structure.Chem Eng J2023;451:138676

[17]

Liu X,Lin S.Hydrogel machines.Mater Today2020;36:102-24

[18]

Neves P,Amarante TR.Incorporation of a dioxomolybdenum(VI) complex in a ZrIV-based metal–organic framework and its application in catalytic olefin epoxidation.Micropor Mesopor Mat2015;202:106-14

[19]

Zhang W,Ge J,Yu SH.A facile and general coating approach to moisture/water-resistant metal-organic frameworks with intact porosity.J Am Chem Soc2014;136:16978-81

[20]

Assi H,Steunou N,Serre C.Titanium coordination compounds: from discrete metal complexes to metal-organic frameworks.Chem Soc Rev2017;46:3431-52

[21]

Lin Z,Zhou J.Direct synthesis of amorphous coordination polymers and metal-organic frameworks.Nat Rev Chem2023;7:273-86

[22]

Zhang CL,Li YQ.Microenvironment modulation of metal-organic frameworks (MOFs) for coordination olefin oligomerization and (co)polymerization.Small2023;19:e2205898

[23]

Lin RB,Xing H,Chen B.Exploration of porous metal-organic frameworks for gas separation and purification.Coord Chem Rev2019;378:87-103 PMCID:PMC11467812

[24]

Ma K,Wang X.Near-instantaneous catalytic hydrolysis of organophosphorus nerve agents with zirconium-based MOF/hydrogel composites.Chem Catal2021;1:721-33

[25]

Yao MS,Wu AQ.A dual-ligand porous coordination polymer chemiresistor with modulated conductivity and porosity.Angew Chem Int Ed Engl2020;59:172-6

[26]

Yang H,Chan A.Catalytically active bimetallic nanoparticles supported on porous carbon capsules derived from metal-organic framework composites.J Am Chem Soc2016;138:11872-81

[27]

Yang X,Wang R.Harvesting clean energy from moisture.Device2023;1:100016

[28]

Luo R,Li Y.In situ fabrication of metal–organic framework thin films with enhanced pervaporation performance.Adv Funct Mater2023;33:2213221

[29]

Shao Z,Lv H.High-performance solar-driven MOF AWH device with ultra-dense integrated modular design and reflux synthesis of Ni2Cl2(BTDD).Device2023;1:100058

[30]

Healy C,Wilson BH.The thermal stability of metal-organic frameworks.Coordin Chem Rev2020;419:213388

[31]

Guo H,Xu K.Self-templated conversion of metallogel into heterostructured TMP@carbon quasiaerogels boosting bifunctional electrocatalysis.Adv Funct Mater2019;29:1903660

[32]

Hu Y,Fang Z.MOF supraparticles for atmosphere water harvesting at low humidity.J Mater Chem A2022;10:15116-26

[33]

Lenzen D,Reinsch H.Scalable green synthesis and full-scale test of the metal-organic framework CAU-10-H for use in adsorption-driven chillers.Adv Mater2018;30:1705869

[34]

Feng Y,Ge T.Full passive MOF water harvester in a real desert climate.Device2023;1:100054

[35]

Hu C,Hou M.Defect-induced activity enhancement of enzyme-encapsulated metal-organic frameworks revealed in microfluidic gradient mixing synthesis.Sci Adv2020;6:eaax5785 PMCID:PMC6989138

[36]

Fu H,Zhu J,Yang J.Enhanced protein adsorption in fibrous substrates treated with zeolitic imidazolate framework-8 (ZIF-8) nanoparticles.ACS Appl Nano Mater2019;2:7626-36

[37]

Xu X,Hoogenboom R.Bioinspired double network hydrogels: from covalent double network hydrogels via hybrid double network hydrogels to physical double network hydrogels.Mater Horiz2021;8:1173-88

[38]

Huang X,Shen Z.Super-stretchable and self-healing hydrogel with a three-dimensional silver nanowires network structure for wearable sensor and electromagnetic interference shielding.Chem Eng J2022;446:137136

[39]

Li M,Li C.Self-powered hydrogel sensors.Device2023;1:100007

[40]

Mao X,Gu S.Synthesis of a three-dimensional network sodium alginate–poly(acrylic acid)/attapulgite hydrogel with good mechanic property and reusability for efficient adsorption of Cu2+ and Pb2+.Environ Chem Lett2018;16:653-8

[41]

Zhu B,Wang J.Structure and properties of semi-interpenetrating network hydrogel based on starch.Carbohydr Polym2015;133:448-55

[42]

Jongprasitkul H,Turunen S.pH-responsive gallol-functionalized hyaluronic acid-based tissue adhesive hydrogels for injection and three-dimensional bioprinting.ACS Appl Mater Interfaces2023;15:33972-84 PMCID:PMC10360037

[43]

Hu K,Zhao Z.Nature-inspired self-powered cellulose nanofibrils hydrogels with high sensitivity and mechanical adaptability.Carbohydr Polym2021;264:117995

[44]

Feng L,Yuan S.Porphyrinic metal–organic frameworks installed with Brønsted acid sites for efficient tandem semisynthesis of artemisinin.ACS Catal2019;9:5111-8

[45]

Logar NZ.Nanoporous materials: from catalysis and hydrogen storage to wastewater treatment.Acta Chim Slov2006;53:117-35Available from: https://www.researchgate.net/profile/Natasa-Zabukovec-Logar/publication/228639201_Nanoporous_Materials_From_Catalysis_and_Hydrogen_Storage_to_Wastewater_Treatment/links/0046353ac2d2c6c818000000/Nanoporous-Materials-From-Catalysis-and-Hydrogen-Storage-to-Wastewater-Treatment.pdf. [Last accessed on 25 Oct 2024]

[46]

Li M,Liu X,Cui X.Synthesis of a 2D phosphorus material in a MOF-based 2D nano-reactor.Chem Sci2018;9:5912-8 PMCID:PMC6050534

[47]

Huang H,Li J.Super-stretchable, elastic and recoverable ionic conductive hydrogel for wireless wearable, stretchable sensor.J Mater Chem A2020;8:10291-300

[48]

Zhu L,Sakai E.A high modulus hydrogel obtained from hydrogen bond reconstruction and its application in vibration damper.RSC Adv2017;7:43755-63

[49]

Cavka JH,Olsbye U.A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability.J Am Chem Soc2008;130:13850-1

[50]

Chen W.Precise control of the structure of synthetic hydrogel networks for precision medicine applications.Matter2022;5:18-9

[51]

Jin C.Synthetic methods, properties and controlling roles of synthetic parameters of zeolite imidazole framework-8: a review.J Solid State Chem2021;297:122040

[52]

Park J,Park D.Therapeutic-gas-responsive hydrogel.Adv Mater2017;29:1702859

[53]

Yao X,Yang C.Hydrogel paint.Adv Mater2019;31:e1903062

[54]

Guo Y,Fang Z,Zhao F.Hydrogels and hydrogel-derived materials for energy and water sustainability.Chem Rev2020;120:7642-707

[55]

Appel EA,Jones ST,Scherman OA.Sustained release of proteins from high water content supramolecular polymer hydrogels.Biomaterials2012;33:4646-52

[56]

Li J.Designing hydrogels for controlled drug delivery.Nat Rev Mater2016;1:16071 PMCID:PMC5898614

[57]

Peers S,Ladavière C.Chitosan hydrogels for sustained drug delivery.J Control Release2020;326:150-63

[58]

Han Z,Mao G.Dual pH-responsive hydrogel actuator for lipophilic drug delivery.ACS Appl Mater Interfaces2020;12:12010-7

[59]

Peers S,Ladavière C.Chitosan hydrogels incorporating colloids for sustained drug delivery.Carbohydr Polym2022;275:118689

[60]

Khuu N,Kumacheva E.Structurally anisotropic hydrogels for tissue engineering.Trend Chem2021;3:1002-26

[61]

Kim SH,Yeon YK.4D-bioprinted silk hydrogels for tissue engineering.Biomaterials2020;260:120281

[62]

Motealleh A.Nanocomposite hydrogels and their applications in tissue engineering.Adv Healthc Mater2017;6:1600938

[63]

Zhao Y,Ren X,Lin Q.Supramolecular adhesive hydrogels for tissue engineering applications.Chem Rev2022;122:5604-40

[64]

Liang Y,Guo B.Functional hydrogels as wound dressing to enhance wound healing.ACS Nano2021;15:12687-722

[65]

Xu Y,Fang Y.Hydrogel combined with phototherapy in wound healing.Adv Healthc Mater2022;11:e2200494

[66]

Liu C,Feng SP.Portable green energy out of the blue: hydrogel-based energy conversion devices.Soft Sci2023;3:10

[67]

Lu Y,Mei C.Recent advances in metal organic framework and cellulose nanomaterial composites.Coordin Chem Rev2022;461:214496

[68]

Shijina K,Kurungot S.Chitosan intercalated metal organic gel as a green precursor of Fe entrenched and Fe distributed N-doped mesoporous graphitic carbon for oxygen reduction reaction.ChemistrySelect2017;2:8762-70

[69]

Wang H,Yin F,Fan T.Metal-organic gel-derived Fe-Fe2O3@nitrogen-doped-carbon nanoparticles anchored on nitrogen-doped carbon nanotubes as a highly effective catalyst for oxygen reduction reaction.Electrochim Acta2017;232:114-22

[70]

Wang X,Wang R,Zhao X.Porous Ni3S2-Co9S8 carbon aerogels derived from carrageenan/NiCo-MOF hydrogels as an efficient electrocatalyst for oxygen evolution in rechargeable Zn-air batteries.Langmuir2022;38:7280-9

[71]

Sikdar A,Gogoi A.Diffusion driven nanostructuring of metal–organic frameworks (MOFs) for graphene hydrogel based tunable heterostructures: highly active electrocatalysts for efficient water oxidation.J Mater Chem A2021;9:7640-9

[72]

Weng Y,Chen C.Hybrid hydrogel reactor with metal–organic framework for biomimetic cascade catalysis.Chem Eng J2021;425:131482

[73]

Duan C,Meng X.Facile synthesis of Ag NPs@MIL-100(Fe)/guar gum hybrid hydrogel as a versatile photocatalyst for wastewater remediation: Photocatalytic degradation, water/oil separation and bacterial inactivation.Carbohydr Polym2020;230:115642

[74]

Guo Y,Zhao F,Shi W.Biomass-derived hybrid hydrogel evaporators for cost-effective solar water purification.Adv Mater2020;32:e1907061

[75]

Fu W,Li C.Enhanced flux and fouling resistance forward osmosis membrane based on a hydrogel/MOF hybrid selective layer.J Colloid Interface Sci2021;585:158-66

[76]

Wang Y,Wang H,Zhao W.In-situ synthesis of MOF nanoparticles in double-network hydrogels for stretchable adsorption device.Chem Eng J2022;450:138216

[77]

Gao D,Cheng Z.Superhydrophilic and underwater superoleophobic in-situ derived 2D Ni-Fe MOF/HNTs composite-enhanced polyvinyl alcohol (PVA) hydrogel membrane for gravity-driven oil/water separation.J Environ Chem Eng2022;10:107904

[78]

Biswas S,Freitas C.Engineering of metal–organic frameworks/gelatin hydrogel composites mediated by the coacervation process for the capture of acetic acid.Chem Mater2022;34:9760-74

[79]

Luo Z,Wu S,Cheng J.Enhanced removal of bisphenol A from aqueous solution by aluminum-based MOF/sodium alginate-chitosan composite beads.Chemosphere2019;237:124493

[80]

Chai Y,Wang L.In situ one-pot construction of MOF/hydrogel composite beads with enhanced wastewater treatment performance.Sep Purif Technol2022;295:121225

[81]

Mao J,Huang J.Constructing multifunctional MOF@rGO hydro-/aerogels by the self-assembly process for customized water remediation.J Mater Chem A2017;5:11873-81

[82]

Chen Z,Zeng J.Preparation of polyethyleneimine-modified chitosan/Ce-UIO-66 composite hydrogel for the adsorption of methyl orange.Carbohydr Polym2023;299:120079

[83]

Zhu H,Zhu S.Alginate hydrogel: a shapeable and versatile platform for in situ preparation of metal-organic framework-polymer composites.ACS Appl Mater Interfaces2016;8:17395-401

[84]

Bai Z,Zhang H.Anti-biofouling and water-stable balanced charged metal organic framework-based polyelectrolyte hydrogels for extracting uranium from seawater.ACS Appl Mater Interfaces2020;12:18012-22

[85]

Song Y,Shan T.MOF-implanted poly (acrylamide-co-acrylic acid)/chitosan organic hydrogel for uranium extraction from seawater.Carbohydr Polym2023;302:120377

[86]

Cui AQ,Ye JB.“Two-in-one” dual-function luminescent MOF hydrogel for onsite ultra-sensitive detection and efficient enrichment of radioactive uranium in water.J Hazard Mater2023;448:130864

[87]

Zhang X,Zhang T,Ji W.Fabrication of an efficient ZIF-8 alginate composite hydrogel material and its application to enhanced copper(II) adsorption from aqueous solutions.New J Chem2021;45:15876-86

[88]

Mahmoud ME.Novel derived pectin hydrogel from mandarin peel based metal-organic frameworks composite for enhanced Cr(VI) and Pb(II) ions removal.Int J Biol Macromol2020;164:920-31

[89]

Lian X.Diagnosis of penicillin allergy: a MOFs-based composite hydrogel for detecting β-lactamase in serum.Chem Commun2018;55:241-4

[90]

Yu X,Pavlov DI,Potapov AS.Ln-MOF-based hydrogel films with tunable luminescence and afterglow behavior for visual detection of ofloxacin and anti-counterfeiting applications.Adv Mater2024;36:e2311939

[91]

Lian X,Wang J.Antineoplastic mitoxantrone monitor: a sandwiched mixed matrix membrane (MMM) based on a luminescent MOF-hydrogel hybrid.Inorg Chem2020;59:10304-10

[92]

Zhao L,Xia T.A luminescent metal–organic framework integrated hydrogel optical fibre as a photoluminescence sensing platform for fluorescence detection.J Mater Chem C2019;7:897-904

[93]

Jia W,Zhang J.Smart MOF-on-MOF hydrogel as a simple rod-shaped core for visual detection and effective removal of pesticides.Small2022;18:e2201510

[94]

Zhong N,Shen Y.Enzymes-encapsulated defective metal-organic framework hydrogel coupling with a smartphone for a portable glucose biosensor.Anal Chem2022;94:14385-93

[95]

Shen A,Zhang L.Solid-state degradation and visual detection of the nerve agent GB by SA@UiO-66-NH2@PAMAM hydrogel.Polym Chem2022;13:6205-12

[96]

Sun Y,Zhang Y.A stimuli-responsive colorimetric aptasensor based on the DNA hydrogel-coated MOF for fumonisin B1 determination in food samples.Food Chem2023;403:134242

[97]

Gwon K,Lee S,Lee DN.Novel metal-organic framework-based photocrosslinked hydrogel system for efficient antibacterial applications.ACS Appl Mater Interfaces2020;12:20234-42

[98]

Deng Z,Hu Y.Injectable biomimetic hydrogels encapsulating Gold/metal–organic frameworks nanocomposites for enhanced antibacterial and wound healing activity under visible light actuation.Chem Eng J2021;420:129668

[99]

Han D,Liu X.Rapid bacteria trapping and killing of metal-organic frameworks strengthened photo-responsive hydrogel for rapid tissue repair of bacterial infected wounds.Chem Eng J2020;396:125194

[100]

Yao X,Zhu P.Omniphobic ZIF-8@hydrogel membrane by microfluidic-emulsion-templating method for wound healing.Adv Funct Mater2020;30:1909389

[101]

Huang K,Wei W.Photothermal hydrogel encapsulating intelligently bacteria-capturing bio-MOF for infectious wound healing.ACS Nano2022;16:19491-508

[102]

Li Q,Jiang T.Injectable and self-healing chitosan-based hydrogel with MOF-loaded α-lipoic acid promotes diabetic wound healing.Mater Sci Eng C Mater Biol Appl2021;131:112519

[103]

Zhang W,Xiang G,Zhao X.Photodynamic alginate Zn-MOF thermosensitive hydrogel for accelerated healing of infected wounds.ACS Appl Mater Interfaces2023;15:22830-42

[104]

Qiu L,Zhang W.Zn-MOF hydrogel: regulation of ROS-mediated inflammatory microenvironment for treatment of atopic dermatitis.J Nanobiotechnology2023;21:163 PMCID:PMC10204188

[105]

Xiao J,Yi J,Ameer GA.A cooperative copper metal-organic framework-hydrogel system improves wound healing in diabetes.Adv Funct Mater2017;27:1604872 PMCID:PMC5513192

[106]

Yang L,Zhang X.Remodeling microenvironment based on MOFs-hydrogel hybrid system for improving diabetic wound healing.Chem Eng J2022;427:131506

[107]

Wang TL,Liu JF.Donut-like MOFs of copper/nicotinic acid and composite hydrogels with superior bioactivity for rh-bFGF delivering and skin wound healing.J Nanobiotechnology2021;19:275 PMCID:PMC8427876

[108]

Wang X,Bu T.Construction of a photothermal hydrogel platform with two-dimensional PEG@zirconium-ferrocene MOF nanozymes for rapid tissue repair of bacteria-infected wounds.Acta Biomater2021;135:342-55

[109]

Nie W,Wang Y.Temperature sensitive polyMOF hydrogel formed by in situ open-ring polymerization for infected chronic wound treatment.Chem Engi J2022;446:136948

[110]

Wu W,Gong P.Construction of core-shell nanoMOFs@microgel for aqueous lubrication and thermal-responsive drug release.Small2022;18:e2202510

[111]

Sun Y,Zhu Y.Tunable and controlled release of cobalt ions from metal-organic framework hydrogel nanocomposites enhances bone regeneration.ACS Appl Mater Interfaces2021;13:59051-66

[112]

Kaur N,Sharma P,Neelakandan PP.Plasmonically active supramolecular polymer–metal–organic framework hydrogel nanocomposite for localized chemo-photothermal therapy.ACS Appl Polym Mater2023;5:542-51

[113]

Li J,Liu Y.Encapsulation of liquid metal nanoparticles inside metal–organic frameworks for hydrogel-integrated dual functional biotherapy.Chem Eng J2023;457:141302

[114]

Zhang D,Song Y,Hu Z.Precision therapy through breaking the intracellular redox balance with an MOF-based hydrogel intelligent nanobot for enhancing ferroptosis and activating immunotherapy.Nanoscale2022;14:8441-53

[115]

Shao G,Zhao H.Tunable arrangement of hydrogel and cyclodextrin-based metal organic frameworks suitable for drug encapsulation and release.Carbohydr Polym2022;278:118915

[116]

Yang Z,Zhou L.Chem-inspired synthesis of injectable metal–organic hydrogels for programmable drug carriers, hemostasis and synergistic cancer treatment.Chem Eng J2021;423:130202

[117]

Liu W,Gracias DH.3D printing of an in situ grown MOF hydrogel with tunable mechanical properties.ACS Appl Mater Interfaces2020;12:33267-75

[118]

Zhang J,Kong YR.Efficiently boosting moisture retention capacity of porous superprotonic conducting MOF-802 at ambient humidity via forming a hydrogel composite strategy.ACS Appl Mater Interfaces2021;13:37231-8

[119]

Cui B,Zhang Z.Construction of a novel self-bleaching photochromic hydrogel embraced within the Zn-MOF@WO3 junction for assembling UV-irradiated smart rewritable device.Chem Eng J2023;455:140822

[120]

Nie J,Zhang M,Nie S.Effective and facile fabrication of MOFs/cellulose composite paper for air hazards removal by virtue of in situ synthesis of MOFs/chitosan hydrogel.Carbohydr Polym2020;250:116955

[121]

Wang W,Hong Y,Feng X.Hydrogel–metal–organic-framework nanoparticle composites for immobilization of active biomacromolecules.ACS Appl Nano Mater2022;5:2222-30

[122]

Tang L,Xu Y.Mechanically strong metal–organic framework nanoparticle-based double network hydrogels for fluorescence imaging.ACS Appl Nano Mater2022;5:1348-55

[123]

Kong Y,Zhang J.Microwave-assisted rapid synthesis of nanoscale MOF-303 for hydrogel composites with superior proton conduction at ambient-humidity conditions.ACS Appl Energy Mater2021;4:14681-8

[124]

Lin X,Shaghaleh H,Xu X.A TEMPO-oxidized cellulose nanofibers/MOFs hydrogel with temperature and pH responsiveness for fertilizers slow-release.Int J Biol Macromol2021;191:483-91

[125]

Xu J,Qiu Y,Zeng D.Novel elastically stretchable metal-organic framework laden hydrogel with pearl-net microstructure and freezing resistance through post-synthetic polymerization.Macromol Rapid Commun2020;41:e1900573

[126]

de Lima HHC,Kupfer VL.Synthesis of resilient hybrid hydrogels using UiO-66 MOFs and alginate (hydroMOFs) and their effect on mechanical and matter transport properties.Carbohydr Polym2021;251:116977

[127]

Jia P,Yang J.Dual–emission MOF–based ratiometric platform and sensory hydrogel for visible detection of biogenic amines in food spoilage.Sensor Actuat B Chem2023;374:132803

[128]

Kim B,Lim H,Kim J.Robust high thermoelectric harvesting under a self-humidifying bilayer of metal organic framework and hydrogel layer.Adv Funct Mater2019;29:1807549

[129]

Khan M,Shah LA,Fu J.Multi-role conductive hydrogels for flexible transducers regulated by MOFs for monitoring human activities and electronic skin functions.J Mater Chem B2024;12:6190-202

[130]

Xiao J,Zhong G,Zhang X.Self-sterilizing microneedle sensing patches for machine learning-enabled wound pH visual monitoring.Adv Funct Mater2024;34:2315067

[131]

Wang HS,Ding Y.Development of biological metal-organic frameworks designed for biomedical applications: from bio-sensing/bio-imaging to disease treatment.Nanoscale Adv2020;2:3788-97 PMCID:PMC9418943

[132]

Ma Q,Wang B.Shaping of metal-organic frameworks, a critical step toward industrial applications.Matter2022;5:1070-91

[133]

Ying B,Su Y,Gu Z.Theranostic gastrointestinal residence systems.Device2023;1:100053

[134]

Fan X,Sun H,Liu R.Polyelectrolyte-based conductive hydrogels: from theory to applications.Soft Sci2022;2:10

[135]

Sun W,Webb E,Zhang W.Advances in metal–organic framework-based hydrogel materials: preparation, properties and applications.J Mater Chem A2023;11:2092-127

AI Summary AI Mindmap
PDF

238

Accesses

0

Citation

Detail

Sections
Recommended

AI思维导图

/