Recent advances in MXene for terahertz applications

Yongzhi Zhang, Jiuxing Jiang, Yongtao Yao, Xunjun He

Optoelectronics Letters ›› 2024, Vol. 20 ›› Issue (5) : 272-288.

Optoelectronics Letters ›› 2024, Vol. 20 ›› Issue (5) : 272-288. DOI: 10.1007/s11801-024-3091-8
Article

Recent advances in MXene for terahertz applications

Author information +
History +

Abstract

Since first synthesized in 2011, MXenes have attracted extensive attention in many scientific fields as a new two-dimensional (2D) material because of the unique physical and chemical properties. Over the past decade, in particular, MXenes have obtained numerous exciting achievements in the field of terahertz applications. In this review, we first briefly introduce the MXene materials, such as the basic structure and main fabrication processes of MXenes. Then, we summarize the recent applications of MXene materials in various terahertz research areas, including terahertz modulation, terahertz absorption, terahertz shielding, terahertz communication, terahertz detection and terahertz generation, in which the representative results are presented. Finally, we give an outlook on the future research directions of MXene materials and their potential applications.

Cite this article

Download citation ▾
Yongzhi Zhang, Jiuxing Jiang, Yongtao Yao, Xunjun He. Recent advances in MXene for terahertz applications. Optoelectronics Letters, 2024, 20(5): 272‒288 https://doi.org/10.1007/s11801-024-3091-8

References

[1]
XieQ, GuoL H, ZhangZ X, et al.. Versatile terahertz graphene metasurface based on plasmon-induced transparency. Applied surface science, 2022, 604: 154575 J]
CrossRef Google scholar
[2]
KumarP, YuS, ShahzadF, et al.. Ultrahigh electrically and thermally conductive self-aligned graphene/polymer composites using large-area reduced graphene oxides. Carbon, 2016, 101: 120-128 J]
CrossRef Google scholar
[3]
BatiA S R, HaoM, MacdonaldT J, et al.. 1D-2D synergistic MXene-nanotubes hybrids for efficient perovskite solar cells. Small, 2021, 17(32):2101925 J]
CrossRef Google scholar
[4]
GuoZ, GaoL, XuZ, et al.. High electrical conductivity 2D MXene serves as additive of perovskite for efficient solar cells. Small, 2018, 14(47): 1802738 J]
CrossRef Google scholar
[5]
WangJ, CaiZ, LinD, et al.. Plasma oxidized Ti3C2Tx MXene as electron transport layer for efficient perovskite solar cells. ACS applied materials & interfaces, 2021, 13(27): 32495-32502 J]
CrossRef Google scholar
[6]
HangyoM. Development and future prospects of terahertz technology. Japanese journal of applied physics, 2015, 54(12):120101 J]
CrossRef Google scholar
[7]
PawarA Y, SonawaneD D, ErandeK B, et al.. Terahertz technology and its applications. Drug invention today, 2013, 5(2): 157-163 J]
CrossRef Google scholar
[8]
GoossensS, NavickaiteG, MonasterioC, et al.. Broadband image sensor array based on graphene-CMOS integration. Nature photonics, 2017, 11(6):366-371 J]
CrossRef Google scholar
[9]
SunL, ZhaoL, PengR Y. Research progress in the effects of terahertz waves on biomacromolecules. Military medical research, 2021, 8(1):1-8 J]
CrossRef Google scholar
[10]
KoenigS, Lopez-DiazD, AntesJ, et al.. Wireless sub-THz communication system with high data rate. Nature photonics, 2013, 7(12):977-981 J]
CrossRef Google scholar
[11]
GongA, QiuY, ChenX, et al.. Biomedical applications of terahertz technology. Applied spectroscopy reviews, 2020, 55(5):418-438 J]
CrossRef Google scholar
[12]
TangX, GuoX, WuW, et al.. 2D metal carbides and nitrides (MXenes) as high-performance electrode materials for lithium-based batteries. Advanced energy materials, 2018, 8(33):1801897 J]
CrossRef Google scholar
[13]
HantanasirisakulK, GogotsiY. Electronic and optical properties of 2D transition metal carbides and nitrides (MXenes). Advanced materials, 2018, 30(52): 1804779 J]
CrossRef Google scholar
[14]
BarsoumM W, Rl-RaghyT. The MAX phases: unique new carbide and nitride materials: ternary ceramics turn out to be surprisingly soft and machinable, yet also heat-tolerant, strong and light weight. American scientist, 2001, 89(4): 334-343 J]
CrossRef Google scholar
[15]
SunZ M. Progress in research and development on MAX phases: a family of layered ternary compounds. International materials reviews, 2011, 56(3):143-166 J]
CrossRef Google scholar
[16]
NaguibM, MashtalirO, CarleJ, et al.. Two-dimensional transition metal carbides. ACS nano, 2012, 6(2):1322-1331 J]
CrossRef Google scholar
[17]
ZhanX, SiC, ZhouJ, et al.. MXene and MXene-based composites: synthesis, properties and environment-related applications. Nanoscale horizons, 2020, 5(2):235-258 J]
CrossRef Google scholar
[18]
NaguibM, KurtogluM, PresserV, et al.. Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2. Advanced materials, 2011, 23(37):4248-4253 J]
CrossRef Google scholar
[19]
NaguibM, MochalinV N, BarsoumM W, et al.. 25th anniversary article: MXenes: a new family of two-dimensional materials. Advanced materials, 2014, 26(7):992-1005 J]
CrossRef Google scholar
[20]
LuJ, PerssonI, LindH, et al.. Tin+1Cn MXenes with fully saturated and thermally stable Cl terminations. Nanoscale advances, 2019, 1(9):3680-3685 J]
CrossRef Google scholar
[21]
KamysbayevV, FilatovA S, HuH, et al.. Covalent surface modifications and superconductivity of two dimensional metal carbide MXenes. Science (New York, N.Y.), 2020, 369(6506):979-983 J]
CrossRef Google scholar
[22]
JhonT I, LeeJ H, JhonY M. Surface termination effects on the terahertz-range optical responses of two-dimensional MXenes: density functional theory study. Materials today communications, 2022, 32: 103917 J]
CrossRef Google scholar
[23]
KhazaeiK, AraiM, SasakiT, et al.. OH-terminated two-dimensional transition metal carbides and nitrides as ultralow work function materials. Physical review B, 2015, 92(7):075411 J]
CrossRef Google scholar
[24]
LiuY, XiaoH, WilliamA G. Schottky-barrier-free contacts with two-dimensional semiconductors by surface-engineered MXenes. Journal of the American chemical society, 2016, 138(49): 15853-15856 J]
CrossRef Google scholar
[25]
KuangP Y, LowJ X, ChengB, et al.. MXene-based photocatalysts. Journal of materials science & technology, 2020, 56: 18-44 J]
CrossRef Google scholar
[26]
JiangX, LiuS, LiangW, et al.. Broadband nonlinear photonics in few-layer MXene Ti3C2Tx (T=F, O, or OH). Laser & photonics reviews, 2018, 12(2):1700229 J]
CrossRef Google scholar
[27]
ZhangT, ChuH, LiY, et al.. Third-order optical nonlinearity in Ti2C MXene for Q-switching operation at 1–2 µm. Optical materials, 2022, 124: 112054 J]
CrossRef Google scholar
[28]
HuT, ZhangH, WangJ, et al.. Anisotropic electronic conduction in stacked two-dimensional titanium carbide. Scientific reports, 2015, 5(1): 16329 J]
CrossRef Google scholar
[29]
RenC E, ZhaoM Q, MakaryanT, et al.. Porous two-dimensional transition metal carbide (MXene) flakes for high-performance Li-ion storage. ChemElectroChem, 2016, 3(5): 689-693 J]
CrossRef Google scholar
[30]
ZhangT, PanL, TangH, et al.. Synthesis of two-dimensional Ti3C2Tx MXene using HCl+LiF etchant: enhanced exfoliation and delamination. Journal of alloys and compounds, 2017, 695: 818-826 J]
CrossRef Google scholar
[31]
FengT, HuangW, ZhuH, et al.. Optical-transparent self-assembled MXene film with high-efficiency terahertz reflection modulation. ACS applied materials & interfaces, 2021, 13(8):10574-10582 J]
CrossRef Google scholar
[32]
ShuiW, LiJ, WangH, et al.. Ti3C2Tx MXene sponge composite as broadband terahertz absorber. Advanced optical materials, 2020, 8(21):2001120 J]
CrossRef Google scholar
[33]
LinZ, LiuJ, PengW, et al.. Highly stable 3D Ti3C2Tx MXene-based foam architectures toward high-performance terahertz radiation shielding. ACS nano, 2020, 14(2): 2109-2117 J]
CrossRef Google scholar
[34]
LiuF, ZhouA, ChenJ, et al.. Preparation of Ti3C2 and Ti2C MXenes by fluoride salts etching and methane adsorptive properties. Applied surface science, 2017, 416: 781-789 J]
CrossRef Google scholar
[35]
ShahzadF, AlhabebM, HatterM, et al.. Electromagnetic interference shielding with 2D transition metal carbides (MXenes). Science, 2016, 353: 1137-1140 J]
CrossRef Google scholar
[36]
TitovaL V, LiG, NatuV, et al.. 2D MXenes: Terahertz properties and applications. 2020 45th International Conference on Infrared, Millimeter, and Terahertz Waves (IRMMW-THz), November 8–13, 2020, 2020, New York, IEEE: 1-2[C]
[37]
ChoiG, ShahazadF, BahkY M, et al.. Enhanced terahertz shielding of MXenes with nano-metamaterials. Advanced optical materials, 2018, 6(5):1701076 J]
CrossRef Google scholar
[38]
AnishaA, KumarD S. Performance analysis of Ta4C3 MXene based optically transparent patch antenna for terahertz communications. Optik, 2022, 260: 168959 J]
CrossRef Google scholar
[39]
JhonY I, SeoM, JhonY M. First-principles study of a MXene terahertz detector. Nanoscale, 2018, 10(1): 69-75 J]
CrossRef Google scholar
[40]
LiG, MontazeriK, IsmailM K, et al.. Terahertz polarizers based on 2D Ti3C2Tz MXene: spin cast from aqueous suspensions. Advanced photonics research, 2020, 1(2):2000084 J]
CrossRef Google scholar
[41]
ZhangM, WangX X, CaoW Q, et al.. Electromagnetic functions of patterned 2D materials for micro-nano devices covering GHz, THz, and optical frequency. Advanced optical materials, 2019, 7(19): 1900689 J]
CrossRef Google scholar
[42]
ChenZ, ChenX, TaoL, et al.. Graphene controlled Brewster angle device for ultra broadband terahertz modulation. Nature communications, 2018, 9(1): 4909 J]
CrossRef Google scholar
[43]
WenQ Y, TianW, MaoQ, et al.. Graphene based all-optical spatial terahertz modulator. Scientific reports, 2014, 4(1): 7409 J]
CrossRef Google scholar
[44]
DingY, ZhuX, XiaoS, et al.. Effective electro-optical modulation with high extinction ratio by a graphene-silicon microring resonator. Nano letters, 2015, 15(7): 4393-4400 J]
CrossRef Google scholar
[45]
TangT, LiJ, LuoL, et al.. Magneto-optical modulation of photonic spin Hall effect of graphene in terahertz region. Advanced optical materials, 2018, 6(7):1701212 J]
CrossRef Google scholar
[46]
TasolamprouA C, KoulouklidisA D, DaskalakiC, et al.. Experimental demonstration of ultrafast THz modulation in a graphene-based thin film absorber through negative photoinduced conductivity. ACS photonics, 2019, 6(3): 720-727 J]
CrossRef Google scholar
[47]
LiJ, LiJ, ZhengC. Dynamic control of reflective chiral terahertz metasurface with a new application developing in full grayscale near field imaging. Carbon, 2021, 172: 189-199 J]
CrossRef Google scholar
[48]
LiuY, LiX, YangT, et al.. Flexible broadband terahertz modulation based on strain-sensitive MXene material. Frontiers in physics, 2021, 9: 670972 J]
CrossRef Google scholar
[49]
FengT, HuY, ChangX, et al.. Highly flexible Ti3C2Tx MXene/waterborne polyurethane membranes for high-efficiency terahertz modulation with low insertion loss. ACS applied materials & interfaces, 2023, 15(5):7592-7601 J]
CrossRef Google scholar
[50]
ThomassinJ, LouX, PagnoulleC, et al.. Multiwalled carbon nanotube/poly (ε-caprolactone) nanocomposites with exceptional electromagnetic interference shielding properties. The journal of physical chemistry C, 2007, 111(30):11186-11192 J]
CrossRef Google scholar
[51]
MaW, ChenH, HouS, et al.. Compressible highly stable 3D porous MXene/GO foam with a tunable high-performance stealth property in the terahertz band. ACS applied materials & interfaces, 2019, 11(28):25369-25377 J]
CrossRef Google scholar
[52]
ChenM, LiuJ, ChaoD, et al.. Porous α-Fe2O3 nanorods supported on carbon nanotubes-graphene foam as superior anode for lithium ion batteries. Nano energy, 2014, 9: 364-372 J]
CrossRef Google scholar
[53]
XiaoX, WangH, UrbankowskiP, et al.. Topochemical synthesis of 2D materials. Chemical society reviews, 2018, 47(23):8744-8765 J]
CrossRef Google scholar
[54]
ZhangX T, LiuD Y, MaY L, et al.. Super-hydrophobic graphene coated polyurethane (GN@PU) sponge with great oil-water separation performance. Applied surface science, 2017, 422: 116-124 J]
CrossRef Google scholar
[55]
SmithR M, ArnoldM A. Terahertz time-domain spectroscopy of solid samples: principles, applications, and challenges. Applied spectroscopy reviews, 2011, 46(8):636-679 J]
CrossRef Google scholar
[56]
LuoM, GuoJ, ShuiW, et al.. Ti3C2Tx MXene-based superhydrophobic broadband terahertz absorber with large pore-size foam architecture. Advanced materials interfaces, 2023, 10(2):2201767 J]
CrossRef Google scholar
[57]
BaiY, QinF, LuY. Flexible and lightweight Ni/MXene decorated polyurethane sponge composite with sensitive strain sensing performance for ultrahigh terahertz absorption. Advanced optical materials, 2022, 10(4): 2101868 J]
CrossRef Google scholar
[58]
FeiY, WangX, WangF, et al.. Covalent coupling induced-polarization relaxation in MXene-based terahertz absorber for realizing dual band absorption. Chemical engineering journal, 2023, 461: 142049 J]
CrossRef Google scholar
[59]
LiS, XuS, PanK, et al.. Ultra-thin broadband terahertz absorption and electromagnetic shielding properties of MXene/rGO composite film. Carbon, 2022, 194: 127-139 J]
CrossRef Google scholar
[60]
BaahM, PaddubskayaA, NovitskyA, et al.. All-graphene perfect broadband THz absorber. Carbon, 2021, 185: 709-716 J]
CrossRef Google scholar
[61]
WanH, LiuN, TangJ, et al.. Substrate-independent Ti3C2Tx MXene waterborne paint for terahertz absorption and shielding. ACS nano, 2021, 15(8):13646-13652 J]
CrossRef Google scholar
[62]
NaseerA, MumtazM, RaffiM, et al.. Reinforcement of electromagnetic wave absorption characteristics in PVDF-PMMA nanocomposite by intercalation of carbon nanofibers. Electronic materials letters, 2019, 15: 201-207 J]
CrossRef Google scholar
[63]
LiuL, DasA, MegaridisC M. Terahertz shielding of carbon nanomaterials and their composites-a review and applications. Carbon, 2014, 69: 1-16 J]
CrossRef Google scholar
[64]
MaY, ChenY. Three-dimensional graphene networks: synthesis, properties and applications. National science review, 2015, 2: 40-53 J]
CrossRef Google scholar
[65]
CongH P, ChenJ F, YuS H, et al.. Graphene-based macroscopic assemblies and architectures: an emerging material system. Chemical society reviews, 2014, 43(21):7295-7325 J]
CrossRef Google scholar
[66]
ShiS, QianB, WuX, et al.. Self-assembly of MXene-surfactants at liquid-liquid interfaces: from structured liquids to 3D aerogels. Angewandte chemie international edition, 2019, 58(50):18171-18176 J]
CrossRef Google scholar
[67]
ZhuY, LiuJ, GuoT, et al.. Multifunctional Ti3C2Tx MXene composite hydrogels with strain sensitivity toward absorption-dominated electromagnetic-interference shielding. ACS nano, 2021, 15(1):1465-1474 J]
CrossRef Google scholar
[68]
WuZ, ShangT, DengY, et al.. The assembly of MXenes from 2D to 3D. Advanced science, 2020, 7: 1903077 J]
CrossRef Google scholar
[69]
LiuJ, ZhangH B, XieX, et al.. Multifunctional, superelastic, and lightweight MXene/polyimide aerogels. Small, 2018, 14: 1802479 J]
CrossRef Google scholar
[70]
SunJ Y, ZhaoX, IlleperumaW R K, et al.. Highly stretchable and tough hydrogels. Nature, 2012, 489: 133-136 J]
CrossRef Google scholar
[71]
FeigV R, TranH, LeeM, et al.. Mechanically tunable conductive interpenetrating network hydrogels that mimic the elastic moduli of biological tissue. Nature communication, 2018, 9: 2740 J]
CrossRef Google scholar
[72]
ZouH, YiP, XuW, et al.. Rapid room-temperature polymerization strategy to prepare organic/inorganic hybrid conductive organohydrogel for terahertz wave responsiveness. Chemical engineering journal, 2023, 461: 141856 J]
CrossRef Google scholar
[73]
ZouQ, ShiC, LiuB, et al.. Enhanced terahertz shielding by adding rare Ag nanoparticles to Ti3C2Tx MXene fiber membranes. Nanotechnology, 2021, 32(41):415204 J]
CrossRef Google scholar
[74]
ZouQ, GuoW, ZhangL, et al.. MXene-based ultra-thin film for terahertz radiation shielding. Nanotechnology, 2020, 31(50): 505710 J]
CrossRef Google scholar
[75]
HussainK, MehboobS, AhmadI, et al.. Terahertz time-domain spectroscopy of thin and flexible CNT-modified MXene/polymer composites. Applied physics A, 2021, 127(5): 1-8 J]
CrossRef Google scholar
[76]
LiG, AmerN, HafezH A, et al.. Dynamical control over terahertz electromagnetic interference shielding with 2D Ti3C2Ty MXene by ultrafast optical pulses. Nano letters, 2019, 20(1):636-643 J]
CrossRef Google scholar
[77]
TonouchiM. Cutting-edge terahertz technology. Nature photonics, 2007, 1(2):97-105 J]
CrossRef Google scholar
[78]
AnandS, DarakM S, KumarD S. Investigations on indium tin oxide based optically transparent terahertz E-shaped patch antenna. Advances in signal processing and intelligent, 2014, 264: 195-202[J]
[79]
DongL, ChuH, LiY, et al.. Surface functionalization of Ta4C3 MXene for broadband ultrafast photonics in the near-infrared region. Applied materials today, 2022, 26: 101341 J]
CrossRef Google scholar
[80]
RAFIEERAD A, AMIRI A, SEQUIERA G L, et al. Development of fluorine-free tantalum carbide MXene hybrid structure as a biocompatible material for supercapacitor electrodes[J]. Advanced functional materials, 2021: 2100015.
[81]
LinH, WangY, GaoS, et al.. Theranostic 2D tantalum carbide (MXene). Advanced materials, 2018, 30(4):1703284 J]
CrossRef Google scholar
[82]
FengW, LuoH, YuW, et al.. Ti3C2 MXene: a promising microwave absorbing material. RSC advances, 2018, 8(5): 2398-2403 J]
CrossRef Google scholar
[83]
BaigS E, BolandJ L, DamryD A, et al.. An ultrafast switchable terahertz polarization modulator based on III-V semiconductor nanowires. Nano letters, 2017, 17(4):2603-2610 J]
CrossRef Google scholar

Accesses

Citations

Detail

Sections
Recommended

/