Simultaneous determination of brilliant blue and indigotine by derivative fluorescence spectrometry combined with WT-RBFNN

Abstract

The mixed solutions of brilliant blue and indigotine are prepared and the fluorescence spectra of them are experimentally measured. The serious overlapping spectra of brilliant blue and indigotine are solved by means of the first-derivative fluorescence spectrometry. The wavelet coefficients, obtained by compressing the spectral data using wavelet transformation (WT), are taken as inputs to establish the radial basis function neural network (RBFNN). The neural network model can realize simultaneous determination of brilliant blue and indigotine, and the mean relative errors of both compounds are 1.84% and 1.26%, respectively.

Keywords

Fluorescence Spectrum / Brilliant Blue / Wavelet Coefficient / Radial Basis Function Neural Network / Derivative Fluorescence

References

[1] KucharskaM., GrabkaJ.. Talanta, 2010, 80: 1045

[2] ChenH.-z.. Current Protein and Peptide Science, 2006, 7: 101

[3] ChenG.-q., WuY.-m., LiuH.-j., GaoS.-m., KongY., WeiB.-l., ZhuT.. Spectroscopy and Spectral Analysis, 2010, 30: 706

[4] ChenG.-q., SuZ.-p., WuY.-m., WangJ., WeiB., ZhuT.. IEEE Comput. Soc., 2009, 2: 17

[5] WeiB.-l., ChenG.-q., WangJ., XuJ.-c., YanG.-f., ZhuT., GaoS.-m.. Journal of Optoelectronics · Laser, 2009, 20: 1618

[6] ShanY., ZhuX.-r., XuQ.-s., LiangY.. Journal of Infrared and Millimeter Waves, 2010, 29: 128

[7] ZhangJ.-l., WangH.-c., ZhaoF.-s.. Journal of Optoelectronics · Laser, 2007, 18: 345

[8] GeZ., SunZ.. Neural Network Theory and Achievement by MATLAB R2007, 2007, Beijing, Publishing House of Electronics Industry: 117

[9] DincE., BaleanuD.. Computers and Mathematics with Applications, 2010, 59: 1701

[10] AfkhamiA., NematollahiD., MadrakianT., A-TarighatM., HajihadiM.. Journal of Hazardous Materials, 2009, 166: 770

[11] YangJ.. Wavelet Analysis and Its Engineering Applications, 2005, Beijing, China Machine Press

[12] XuJ., WangZ.. Fluorimetry, 2006, Third EditionBeijing, Science Press: 299

[13] WuB., LiuY., HanC., LuoX., LuJ., NiX.. Chinese Optics Letters, 2009, 7: 159

[14] KangR., WangY., YangH., LiG., TanX., XueJ., ZhangJ., YuanY., ShiL., XiaoX.. Analytica Chimica Acta, 2010, 658: 180

[15] TurabikM.. Journal of Hazardous Materials, 2008, 158: 52