Highly Tough, Anti-freezing, Sensitive Polyvinyl Alcohol-based Organic Hydrogel for Wearable Flexible Strain Sensor

Peng Liu , Qiangfei Shi , Qilin Sun , Feicong Liu , Yuli Yang , Zhongdan Shang , Xiangrong Du , Changxiu Chen , Yuanhang Li , Hanzhi Zhang

Journal of Wuhan University of Technology Materials Science Edition ›› 2026, Vol. 41 ›› Issue (4) : 1123 -1133.

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Journal of Wuhan University of Technology Materials Science Edition ›› 2026, Vol. 41 ›› Issue (4) :1123 -1133. DOI: 10.1007/s11595-026-3328-4
Organic Materials
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Highly Tough, Anti-freezing, Sensitive Polyvinyl Alcohol-based Organic Hydrogel for Wearable Flexible Strain Sensor
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Abstract

A novel PVA/EG/GE/LiCl (PEGL) multifunctional hydrogel was developed by using a binary of ethylene glycol (EG)/water as solvent, with gelatin (GE) and PVA as the skeletons and lithium chloride (LiCl) for conductivity. The experimental results indicate that, compared to four other hydrogels, the PEGL hydrogel exhibits the best tensile strength (3.92 ± 0.12 MPa), a good elongation at break (375.22 ± 11.25%), and excellent anti-freezing properties, being able to withstand approximately 6 500 times its own weight without breaking. Moreover, the PEGL organic hydrogel sensor has high sensitivity and rapid response characteristics, capable of transforming body movements into repeatable and stable electrical signals. This study provides new ideas for the development of new types of high-performance wearable flexible strain sensors.

Keywords

strain sensor / hydrogel / polyvinyl alcohol / anti-freezing

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Peng Liu, Qiangfei Shi, Qilin Sun, Feicong Liu, Yuli Yang, Zhongdan Shang, Xiangrong Du, Changxiu Chen, Yuanhang Li, Hanzhi Zhang. Highly Tough, Anti-freezing, Sensitive Polyvinyl Alcohol-based Organic Hydrogel for Wearable Flexible Strain Sensor. Journal of Wuhan University of Technology Materials Science Edition, 2026, 41 (4) : 1123-1133 DOI:10.1007/s11595-026-3328-4

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References

[1]

Ma J, Shen L, Jiang Y, et al. . Wearable Self-Powered Smart Sensors for Portable Nutrition Monitoring[J]. Anal. Chem., 2022, 94(4): 2 333-2 340

[2]

Guo W, Ma M. Conductive Nanocomposite Hydrogels for Flexible Wearable Sensors[J]. J. Mater. Chem. A, 2024, 12: 9 371-9 399

[3]

He Y, Han Z, Ren J, et al. . An Overview of Flexible Sensing Nanocomposites[J]. Adv. Compos. Hybrid. Mater, 2024, 7: 142

[4]

Karimzadeh Z, Mahmoudpour M, Rahimpour E, et al. . Nanomaterial Based PVA Nanocomposite Hydrogels for Biomedical Sensing: Advances Toward Designing the Ideal Flexible/Wearable Nanoprobes[J]. Advances in Colloid and Interface Science, 2022, 305: 102 705

[5]

Dutta T, Chaturvedi P, Llamas-Garro I, et al. . Smart materials for Flexible Electronics and Devices: Hydrogel[J]. RSC Adv., 2024, 14: 12 984-13 004

[6]

Khan M, Shah LA, Rahman TU, et al. . Multiple-Language-Responsive Conductive Hydrogel Composites for Flexible Strain and Epidermis Sensors[J]. ACS Appl. Polym. Mater., 2024, 6: 4 233-4 243

[7]

Li X, Jiang M, Du Y, et al. . Self-healing Liquid Metal Hydrogel for Human-Computer Interaction and Infrared Camouflage[J]. Mater. Horiz., 2023, 10: 2 945-2 957

[8]

Luo J, Hu Y, Luo S, et al. . Strong and Multifunctional Lignin/Liquid Metal Hydrogel Composite as Flexible Strain Sensors[J]. ACS Sustainable Chem. Eng., 2024, 12(18): 7 105-7 114

[9]

Cui C, Fu Q, Meng L, et al. . Recent Progress in Natural Biopolymers Conductive Hydrogels for Flexible Wearable Sensors and Energy Devices: Materials, Structures, and Performance[J]. ACS Appl. Bio Mater., 2021, 4(1): 85-121

[10]

Li Z, Liu P, Chen S, et al. . Polyvinyl Alcohol/Chitosan-Based Nanocomposite Organohydrogel Flexible Wearable Strain Sensors for Sports Monitoring and Underwater Communication Rescue[J]. International Journal of Biological Macromolecules, 2024, 258: 129 054

[11]

Li Z, Liu P, Chen S, et al. . High-Strength, Freeze-Resistant, Recyclable, and Biodegradable Polyvinyl Alcohol/Glycol/Wheat Protein Complex Organohydrogel for Wearable Sensing Devices[J]. Biomacromolecules, 2023, 24(8): 3 557-3 567

[12]

Li H, Li J, Li T, et al. . Macro-porous Polyvinyl Alcohol-Tannic Acid Hydrogel with High Strength and Toughness for Cartilage Replacement[J]. J. Mater. Sci., 2022, 57(17): 8 262-8 275

[13]

Li X, Zhang S, Li X, et al. . Starch/Polyvinyl Alcohol with Ionic Liquid/Graphene Oxide Enabled Highly Tough, Conductive and Freezing-Resistance Hydrogels for Multimodal Wearable Sensors[J]. Carbohydr. Polym., 2023, 320: 121 262

[14]

Long K, Zhang Y, Gao X, et al. . A Flexible, Conductive Hydrogel for Strain Sensor and Triboelectric Nanogenerator toward Human Motion Monitoring[J]. ACS Appl. Electron. Mater., 2024, 6(8): 5 496-5 506

[15]

Yu S, Zhang X, Lin X, et al. . The Dual Transportation Channel of Ionic Strain Sensor Constructed by Amorphous Polymer Chains and two Dimensional Nanoplatelets[J]. Eur. Polym. J., 2024, 204: 112703

[16]

Rong Q, Lei W, Liu M. Conductive Hydrogels as Smart Materials for Flexible Electronic Devices[J]. Chemistry-A European Journal, 2018, 24(64): 16 930-16 943

[17]

Jiang Y, Hu A, Feng W, et al. . Non-covalent Crosslinked Hydrogels to Realize Renewable and Re-Moldable Strain Sensors with Excellent Sensing Behavior[J]. Polymer, 2024, 290: 126 588

[18]

Li Z, Liu P, Chen S, et al. . Highly Elastic, Frost-Resistant and Antimicrobial Flexible Sensor Inspired by Ramen Noodles for Human Motion Detection And Deep Learning of Handwritten Content[J]. Microchemical Journal, 2024, 196: 109 614

[19]

Li Z, Liu P, Chen S, et al. . High-strength, Anti-Freeze, Transparent and Recyclable Composite Organohydrogel for Flexible Strain Sensor[J]. Reactive and Functional Polymers, 2023, 190: 105 644

[20]

Li Z, Liu P, Li X, et al. . Design Strategies for Environmentally Friendly Polyvinyl Alcohol Hydrogel Sensors: Research Progress and Perspectives[J]. Materials Today Communications, 2024, 39: 109 401

[21]

Li Z, Yin F, He W, et al. . Anti-freezing, Recoverable and Transparent Conductive Hydrogels Co-Reinforced by Ethylene Glycol as Flexible Sensors for Human Motion Monitoring[J]. International Journal of Biological Macromolecules, 2023, 230: 123 117

[22]

Xu Y, Tan C, He Y, et al. . Chitin Nanocrystals Stabilized Liquid Metal for Highly Stretchable and Anti-Freeze Hydrogels as Flexible Strain Sensor[J]. Carbohydr. Polym., 2024, 328: 121 728

[23]

Jiao Q, Cao L, Zhao Z, et al. . Zwitterionic Hydrogel with High Transparency, Ultrastretchability, and Remarkable Freezing Resistance for Wearable Strain Sensors[J]. Biomacromolecules, 2021, 22(3): 1 220-1 230

[24]

Chen L, Guo M. Highly Transparent, Stretchable, and Conductive Supramolecular Ionogels Integrated with Three-Dimensional Printable, Adhesive, Healable, and Recyclable Character[J]. ACS Applied Materials & Interfaces, 2021, 13(21): 25 365-25 373

[25]

Zhang J, Wang Y, Wei Q, et al. . 3D Printable, Stretchable, Anti-freezing and Rapid Self-Healing Organogel-Based Sensors for Human Motion Detection[J]. J. Colloid Interface Sci., 2024, 653: 1 514-1 525

[26]

Peng S, Zhao Y, Liang C, et al. . Conductive Ionically Cross-Linked Gluten/Poly(vinyl alcohol) Composite Organohydrogel with Freezing and Water Resistance for Wearable Sensors[J]. ACS Appl. Polym. Mater., 2023, 5(11): 9 515-9 524

[27]

Yang C, Liu D, Wang S, et al. . Strain Sensors Enhanced By a Flexible, Conductive Hydrogel with Superior Transparency, Frost Resistance, and Water Retention[J]. Materials Today Communications, 2024, 40: 110 235

[28]

Yang C, Liu J, Liu P, et al. . Strain Sensors Enhanced by a Flexible, Conductive Hydrogel with Superior Transparency, Frost Resistance, and Water Retention[J]. Chemical Engineering Journal, 2024, 40: 110 235

[29]

Li F, Liu P, Li X, et al. . High Tough, Self-Adhesive, Conductive Double Network Hydrogel for Flexible Strain Sensors[J]. Journal Polymer Science, 2024, 62(18): 4 165-4 176

[30]

Zhang X, Kong X, Zhou X, et al. . Antimicrobial and Anti-Freezing Conductive Hydrogels Driven by Quaternary Ammonium Chitosan Salt for Flexible Strain Sensors[J]. Eur. Polym. J., 2024, 202: 112 601

[31]

Sun S, Xu Y, Maimaitiyiming X. Tough Polyvinyl Alcohol-Gelatin Biological Macromolecules Ionic Hydrogel Temperature, Humidity, Stress and Strain, Sensors[J]. Int. J. Biol. Macromol., 2023, 249: 125 978

[32]

Zhang W, Wen J, Ma M G, et al. . Anti-freezing, Water-Retaining, Conductive, and Strain-Sensitive Hemicellulose/Polypyrrole Composite Hydrogels for Flexible Sensors[J]. Journal of Materials Research and Technology, 2021, 14: 555-566

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Wuhan University of Technology and Springer-Verlag GmbH Germany, Part of Springer Nature

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