A novel epoxy-based silicon (VECSR) was synthesized from polymethylhydrosiloxane (PMHS) and 1,2-epoxy-4-vinylcyclohexane (VEC) via the hydrosilylation reaction. The structure of VECSR was characterized by FT-IR and 1H-NMR. A series of UV-curable materials were prepared by blending different ratios of VECSR and alicyclic epoxy resin (2021P) and UV curing with triarylsulfonium hexafluoroantimonate salts solution (UVI-6976) as the photoinitiator, and then were tested for performance. The experimental results showed that when the content of VECSR was 10%, the comprehensive mechanical properties of the UV-curable material were the best, i e, the UV-curable sample with a tensile strength of 48.55 MPa, an elongation at break of 3.2%, the UV-curable film with a flexibility of 3 mm, and an impact strength of 20 kg·cm. Compared to a single 2021P system in the absence of VECSR, the UV-curable materials containing VECSR exhibited better hydrophobicity and thermal stability.
| [1] |
Tuo Y, Luo X, Xiong Y, et al.. A Novel Polyfunctional Polyurethane Acrylate Derived from Castor Oil-Based Polyols for Waterborne UV-Curable Coating Application. Polymers, 2024, 16(7): 949. J].
|
| [2] |
Dai X, Li J. Study on the Performances of Toughening UV-LED-Cured Epoxy Electronic Encapsulants. Coatings, 2024, 14(11): 1 347. J].
|
| [3] |
Yang L, Wang J, Li R, et al.. Preparation of UV Curable Acrylamide Modified Epoxy Resin and Performance in 3D Printing. Reactive and Functional Polymers, 2024, 205: 106 093. J].
|
| [4] |
Deng J, Kong R, Liu Z, et al.. Preparation of Fluorescent UV-curable Adhesives Containing AIEgen-Modified Monomer. Dyes and Pigments, 2023, 220: 111 761. J].
|
| [5] |
Chen M m, Wang C y, Toyoda M, et al.. Amphiphilic Carbonaceous Materials: Preparation Methods and Applications. RSC Adv., 2025, 15(22): 17 049-17 079. J].
|
| [6] |
Wu Z, Huang B, Liu Y, et al.. Fabrication and Properties of a New Reactive Diluent for Cationic UV Curing. J. Wuhan Univ. Technol. - Mat. Sci. Edit., 2024, 39(4): 1 053-1 060. J].
|
| [7] |
Guo W, Hu J, Yan X. Influence of Process Parameters on the Characteristics of Electrohydrodynamic-printed UV-curing Conductive Lines on the Fabric. J. Micromech. Microeng., 2022, 32(3): 035 003. J].
|
| [8] |
Hu X, Yao B, Liu J, et al.. Preparation and Properties of High Refractive Index UV-cured Titanium Hybrid Optical Materials. Materials Letters, 2020, 265: 127 466. J].
|
| [9] |
Luo X, Li X, Bao Z, et al.. Preparation of SiCN Ceramic Fibres via UV Irradiation Curing Polysilazane. Bull. Mater. Sci., 2023, 46(2): 111. J].
|
| [10] |
Liu Y, Huang B, Zhou W, et al.. Preparation of Bis[(3-ethyl-3-methoxyoxetane)propyl]diphenylsilane and Investigation of Its Cationic UV-Curing Material Properties. Polymers, 2021, 13(15): 2 573. J].
|
| [11] |
Atif M, Bongiovanni R, Yang J. Cationically UV-Cured Epoxy Composites. Polymer Reviews, 2015, 55(1): 90-106. J].
|
| [12] |
Huang B, Han L, Wu B, et al.. Synthesis of Diepoxycyclohexylethyl Tetramethyldisiloxane and Its Application to Stereolithography 3D Printing. RPJ, 2020, 26(9): 1 515-1 524. J].
|
| [13] |
Sasaki H. Curing Properties of Cycloaliphatic Epoxy Derivatives. Progress in Organic Coatings, 2007, 58(2–3): 227-230. J].
|
| [14] |
Noè C, Hakkarainen M, Sangermano M. Cationic UV-Curing of Epoxidized Biobased Resins. Polymers, 2020, 13(1): 89. J].
|
| [15] |
Liu Y, Lin Y, Wang Y, et al.. Simultaneously Improving Toughness and Hydrophobic Properties of Cycloaliphatic Epoxy Resin through Silicone Prepolymer. J. of Applied Polymer Sci., 2022, 139(32): e52 478. J].
|
| [16] |
Yu Z, Cui A, Zhao P, et al.. Preparation and Properties Studies of UV-curable Silicone Modified Epoxy Resin Composite System. Journal of Applied Biomaterials & Functional Materials, 2018, 16(1_suppl): 170-176. J].
|
| [17] |
Lv J, Hu D, Ma W. UV-thermal-cured Cycloaliphatic Epoxy Composites with Enhanced Mechanical Properties via Ca2+-modified Nanocrystalline Cellulose. Polymer International, 2021, 70(12): 1 692-1 700. J].
|
| [18] |
Zhang P, Long J, Xue K, et al.. Preparation of Degradable Bio-based Silicone/epoxy Hybrid Resins towards Low Dielectric Composites. European Polymer Journal, 2022, 181: 111 691. J].
|
| [19] |
Qian D, Zhou J, Zheng J, et al.. Synthesis, Curing Behaviors and Properties of a Bio-Based Trifunctional Epoxy Silicone Modified Epoxy Thermosets. Polymers, 2022, 14(20): 4 391. J].
|
| [20] |
Yu M, Chen Z, Li J, et al.. High-Branched Organosilicon Epoxy Resin with Low Viscosity, Excellent Toughness, Hydrophobicity, and Dielectric Property. Molecules, 2023, 28(6): 2 826. J].
|
| [21] |
He L, Wang J, Yang L, et al.. Preparation and Characterization of Waterborne Silicone Modified Epoxy Resin. Polymer Engineering & Sci., 2025, 65(1): 149-160. J].
|
| [22] |
Shon M, Kwon H. Effects of Surface Modification with Amino Branched Polydimethylsiloxane (ABP) on the Corrosion Protection of Epoxy Coating. Corrosion Science, 2007, 49(11): 4 259-4 275. J].
|
| [23] |
Pawar SS, Naik RB, Rath SK, et al.. Pigmented Silicone/epoxy Novel Blends for Preparation of Stratified Nontoxic Foul Release Coatings. J. Coat Technol. Res., 2022, 19(4): 1 269-1 285. J].
|
| [24] |
Lemesle C, Bellayer S, Duquesne S, et al.. Self-stratified Bio-based Coatings: Formulation and Elucidation of Critical Parameters Governing Stratification. Applied Surface Science, 2021, 536: 147 687. J].
|
| [25] |
Zheng J, Cai Y, Hu Y, et al.. Bio-based Epoxy Functionalized MQ Silicone Resins: from Synthesis to Toughened Epoxy Composites with Good Mechanical Properties, Thermal Resistance and Transparency. Polym. Chem., 2022, 13(37): 5 325-5 336. J].
|
| [26] |
Ren Q, Zou H, Liang M. The Preparation and Properties Study of Methoxy Functionalized Silicone-modified Epoxy Resins. J. of Applied Polymer Sci., 2014, 131(9): 40 212. J].
|
| [27] |
Shen Z, Xia Z, Zhang Y. Characterization and Properties of Epoxy Resin (E-20) Modified with Silicone Intermediate RSN-6018. Progress in Organic Coatings, 2018, 114: 115-122. J].
|
RIGHTS & PERMISSIONS
Wuhan University of Technology and Springer-Verlag GmbH Germany, Part of Springer Nature
PDF
