Influence of Sewage Sludge Ash and Superabsorbent Polymer on Volume Deformation of Cement Paste with Low Water/binder Ratio

Chunping Gu , Zhe Yu , Jiahui Zhang , Zhenan Bao , Haixia Wei , Yanwen Xu , Qiannan Wang , Cong Ding , Deyu Kong

Journal of Wuhan University of Technology Materials Science Edition ›› 2026, Vol. 41 ›› Issue (3) : 768 -777.

PDF
Journal of Wuhan University of Technology Materials Science Edition ›› 2026, Vol. 41 ›› Issue (3) :768 -777. DOI: 10.1007/s11595-026-3292-z
Cementitious Materials
research-article
Influence of Sewage Sludge Ash and Superabsorbent Polymer on Volume Deformation of Cement Paste with Low Water/binder Ratio
Author information +
History +
PDF

Abstract

In order to facilitate the recycling of sewage sludge ash (SSA), and to reveal the effects of SSA and super absorbent polymers (SAP) on the volumetric deformation of the high performance cement-based materials, the separate and coupled effects of SSA and SAP on the volumetric deformation of the cement pastes with a low water/binder ratio (0.25) under different environmental conditions (sealed, drying, and water immersion environments) were studied. The results showed that the addition of SSA or SAP reduced the autogenous and drying shrinkage, and increased the water immersion expansion strain of the cement pastes. The addition of SSA and SAP together further reduced the autogenous and drying shrinkage, and increased the water immersion expansion. The synergistic effect of SSA and SAP on the volumetric deformation of the cement pastes was observed under a sealed environment. It was less significant under a water immersion environment. Under drying environment, the reduction in shrinkage caused by the combined addition of SSA and SAP was lower than the sum of the reduced shrinkages caused by SSA and SAP alone. These findings provided a new potential approach for the recycling and utilization of SSA.

Keywords

cement paste / sewage sludge ash / super absorbent polymer / volumetric deformation

Cite this article

Download citation ▾
Chunping Gu, Zhe Yu, Jiahui Zhang, Zhenan Bao, Haixia Wei, Yanwen Xu, Qiannan Wang, Cong Ding, Deyu Kong. Influence of Sewage Sludge Ash and Superabsorbent Polymer on Volume Deformation of Cement Paste with Low Water/binder Ratio. Journal of Wuhan University of Technology Materials Science Edition, 2026, 41 (3) : 768-777 DOI:10.1007/s11595-026-3292-z

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

Zhou X, Zhou X, He L, et al.. Effect of Sewage Sludge Ash on Mechanical Properties, Drying Shrinkage and High-temperature Resistance of Cement Mortar. Case Studies in Construction Materials, 2024, 20: e03 101. J].

[2]

Yang Y, Wu Z, Hu X, et al.. Performance and Microstructure of Sintered Sludge Ash-Modified Cement Paste. Journal of Building Engineering, 2024, 91: 109 503. J].

[3]

Zdeb T, Tracz T, Adamczyk M. Physical, Mechanical Properties and Durability of Cement Mortars Containing Fly Ash from the Sewage Sludge Incineration Process. Journal of Cleaner Production, 2022, 345: 131 055. J].

[4]

Donatello S, Cheeseman C R. Recycling and Recovery Routes for Incinerated Sewage Sludge Ash (ISSA): A Review. Waste Management, 2013, 33(11): 2 328-2 340. J].

[5]

Garcés P, Pérez Carrión M, García-Alcocel E, et al.. Mechanical and Physical Properties of Cement Blended with Sewage Sludge Ash. Waste Management, 2008, 28(12): 2 495-2 502. J].

[6]

Motisariya K, Agrawal G, Baria M, et al.. Experimental Analysis of Strength and Durability Properties of Cement Binders and Mortars with Addition of Microfine Sewage Sludge Ash (SSA) Particles. Materials Today: Proceedings, 2023, 85: 24-28. [J].

[7]

Tipraj, Shanmugapriya T. A Comprehensive Analysis on Optimization of Sewage Sludge Ash as a Binding Material for a Sustainable Construction Practice: A State of the Art Review. Materials Today: Proceedings, 2022, 64: 1 094-1 101. [J].

[8]

Guo S, Dong R, Chang Z, et al.. Performance and Microstructure of Sustainable Cementitious Materials Mixed by Municipal Sewage Sludge Ash, Slag, and Fly Ash. Construction and Building Materials, 2023, 367: 130 028. J].

[9]

Krejcirikova B, Rode C, Peuhkuri R. Determination of Hygrothermal Properties of Cementitious Mortar: The Effect of Partial Replacement of Cement by Incinerated Sewage Sludge Ash. Journal of Building Physics, 2019, 42(6): 771-787. J].

[10]

Mejdi M, Saillio M, Chaussadent T, et al.. Hydration Mechanisms of Sewage Sludge Ashes Used as Cement Replacement. Cement and Concrete Research, 2020, 135: 106 115. J].

[11]

Rucińska T, Głowacka A, Sidełko R. The Influence of Incinerated Sewage Sludge as an Aggregate on the Selected Properties of Cement Mortars. Materials, 2021, 14(19): 5 846. J].

[12]

Chen Z, Poon C S. Comparative Studies on the Effects of Sewage Sludge Ash and Fly Ash on Cement Hydration and Properties of Cement Mortars. Construction and Building Materials, 2017, 154: 791-803. J].

[13]

Sasaoka N, Yokoi K, Yamanaka T. Basic Study of Concrete Made Using Ash Derived from the Incinerating Sewage Sludge. International Journal of Modern Physics B, 2006, 20(25n27): 3 716-3 721. J].

[14]

Chen Z, Poon C S. Comparing the Use of Sewage Sludge Ash and Glass Powder in Cement Mortars. Environmental Technology, 2017, 38(11): 1 390-1 398. J].

[15]

Tay J H. Sludge Ash as Filler for Portland Cement Concrete. Journal of Environmental Engineering (United States), 1987, 113(2): 345-351. [J].

[16]

Gu C, Shuang Y, Ji Y, et al.. Effect of Environmental Conditions on the Volume Deformation of Cement Mortars with Sewage Sludge Ash. Journal of Building Engineering, 2023, 65: 105 720. J].

[17]

Gu C, Ji Y, Zhang Y, et al.. Recycling Use of Sulfate-Rich Sewage Sludge Ash (SR-SSA) in Cement-Based Materials: Assessment on the Basic Properties, Volume Deformation and Microstructure of SR-SSA Blended Cement Pastes. Journal of Cleaner Production, 2021, 282: 124 511. J].

[18]

Gu C, Ji Y, Yao J, et al.. Feasibility of Recycling Sewage Sludge Ash in Ultra-High Performance Concrete: Volume Deformation, Microstructure and Ecological Evaluation. Construction and Building Materials, 2022, 318: 125 823. J].

[19]

Zhang J, Cao X. Stabilization of Expansive Soil by Lime and Fly Ash. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2002, 17(4): 73-77. J].

[20]

Li P, Ran X, Su X, et al.. Optimizing Ternary Blended Sustainable Binder and Water Content in UHPC: Strength, Chloride Resistance and Nanoscale Properties. Journal of Building Engineering, 2024, 85: 108 722. J].

[21]

Wang F, Yang J, Hu S, et al.. Influence of Superabsorbent Polymers on the Surrounding Cement Paste. Cement and Concrete Research, 2016, 81: 112-121. J].

[22]

Li Y, Zhang C, Li T, et al.. Exploring the Role of SAP Chemical Composition in the Internal Curing of High-Performance Cementitious Materials. Construction and Building Materials, 2024, 451: 138 784. J].

[23]

Mechtcherine V, Schröfl C, Reichardt M, et al.. Recommendations of Rilem Tc 260-Rsc for Using Superabsorbent Polymers (SAP) for Improving Freeze–Thaw Resistance of Cement-Based Materials. Materials and Structures, 2019, 52(4): 75. J].

[24]

Mechtcherine V, Wyrzykowski M, Schröfl C, et al.. Application of Super Absorbent Polymers (SAP) in Concrete Construction—Update of Rilem State-of-the-Art Report. Materials and Structures, 2021, 54(2): 80. J].

[25]

Zhong P, Hu Z, Griffa M, et al.. Mechanisms of Internal Curing Water Release from Retentive and Non-Retentive Superabsorbent Polymers in Cement Paste. Cement and Concrete Research, 2021, 147: 106 494. J].

[26]

Justs J, Wyrzykowski M, Bajare D, et al.. Internal Curing by Superabsorbent Polymers in Ultra-High Performance Concrete. Cement and Concrete Research, 2015, 76: 82-90. J].

[27]

State Administration for Market Regulation, Standardization Administration of China. Common Portland Cement, 2020. [S]. GB 175-2020.

[28]

Zheng S, Chen H, Xiao Y, et al.. Water Distribution Characteristics of Capillary Absorption in Internally Cured Concrete with Superabsorbent Polymers. Construction and Building Materials, 2024, 418: 135 446. J].

[29]

State Administration for Market Regulation, Standardization Administration of China. Test Method of Cement Mortar Strength(ISO Method), 2021. [S]. GB/T 17671-2021.

[30]

ASTM International. Standard Test Method for Autogenous Strain of Cement Paste and Mortar, 2009. [S]. ASTM C1698-2009(2014).

[31]

National Development and Reform Commission. Standard Test Method for Drying Shrinkage of Mortar, 2004. [S]. JC/T 603-2004.

[32]

Lynn C J, Dhir R K, Ghataora G S, et al.. Sewage Sludge Ash Characteristics and Potential for Use in Concrete. Construction and Building Materials, 2015, 98: 767-779. J].

[33]

Ding Y, Zhang M, Yang X, et al.. Mechanical Property and Microstructure of Cement Mortar with Carbonated Recycled Powder. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2024, 39(3): 689-697. J].

[34]

Schröfl C, Mechtcherine V, Gorges M. Relation Between the Molecular Structure and the Efficiency of Superabsorbent Polymers (SAP) as Concrete Admixture to Mitigate Autogenous Shrinkage. Cement and Concrete Research, 2012, 42(6): 865-873. J].

[35]

Said M, Shanour A S, Mustafa T S, et al.. Experimental Flexural Performance of Concrete Beams Reinforced with an Innovative Hybrid Bars. Engineering Structures, 2021, 226: 111 348. J].

[36]

Snoeck D, Jensen O M, De Belie N. The Influence of Superabsorbent Polymers on the Autogenous Shrinkage Properties of Cement Pastes with Supplementary Cementitious Materials. Cement and Concrete Research, 2015, 74: 59-67. J].

[37]

He G, Kong D, Chen X, et al.. Preparation of C-S-H Gels by Mechano-chemistry and Its Influences on Properties of Super-Retarded Cement-Based Materials with Sucros. Cement and Concrete Composites, 2024, 153: 105 734. J].

[38]

Urgessa G, Choi KB, Yeon JH. Internal Relative Humidity, Autogenous Shrinkage, and Strength of Cement Mortar Modified with Superabsorbent Polymers. Polymers, 2018, 10(10): 1 074. J].

[39]

Zhang M, Gao S, Liu T, et al.. High-Performance Materials Improve the Early Shrinkage, Early Cracking, Strength, Impermeability, and Microstructure of Manufactured Sand Concrete. Materials (Basel, Switzerland), 2024, 17(10): 2 465. J].

[40]

Liu L, Wang X, Chen H, et al.. Numerical Modeling of Drying Shrinkage Deformation of Cement-Based Composites by Coupling Multi-scale Structure Model with 3D Lattice Analyses. Computers & Structures, 2017, 178: 88-104. J].

[41]

Yang J, Liu L, Liao Q, et al.. Effect of Superabsorbent Polymers on the Drying and Autogenous Shrinkage Properties of Self-Leveling Mortar. Construction and Building Materials, 2019, 201: 401-407. J].

[42]

Mao Q, Chen J, Wu W, et al.. Multiple Self-Healing Effects of Water-Absorbing Microcapsules in Cementitious Materials. Polymers, 2023, 15(2): 428. J].

[43]

Mehta P K, Monteiro P. Concrete: Microstructure, Properties, and Materials, 2013, 4th ed., New York, McGraw-Hill. [M].

[44]

Maruyama I, Lura P. Properties of Early-Age Concrete Relevant to Cracking in Massive Concrete. Cement and Concrete Research, 2019, 123: 105 770. J].

[45]

Lura P, Jensen O M, van Breugel K. Autogenous Shrinkage in High-Performance Cement Paste: An Evaluation of Basic Mechanisms. Cement and Concrete Research, 2003, 33(2): 223-232. J].

[46]

Zhang M, Li W, Li M, et al. Mesoscopic Simulation of Concrete Drying Shrinkage with Hydration Kinetics[J]. International Journal of Mechanical Sciences, 2024: 109 716

[47]

Tang C, Dong R, Tang Z, et al.. Effect of SAP on the Properties and Microstructure of Cement-Based Materials in the Low Humidity Environment. Case Studies in Construction Materials, 2024, 20: e03 001. J].

[48]

Kang S H, Hong S G, Moon J. Importance of Monovalent Ions on Water Retention Capacity of Superabsorbent Polymer in Cement-Based Solutions. Cement and Concrete Composites, 2018, 88: 64-72. J].

[49]

Tutkun B, Barlay E S, Yalçınkaya Ç, et al.. Effect of Internal Curing on Shrinkage and Cracking Potential Under Autogenous and Drying Conditions. Construction and Building Materials, 2023, 409: 134 078. J].

[50]

Wan Z, He T, Chang N, et al.. Effect of Super Absorbent Polymer (SAP) on Volume Stability and Application Performance of Cement Mortar with Accelerator. Journal of Building Engineering, 2024, 82: 108 238. J].

[51]

Kazemian M, Shafei B. Investigation of Type, Size, and Dosage Effects of Superabsorbent Polymers on the Hydration Development of High-Performance Cementitious Materials. Construction and Building Materials, 2024, 422: 135 801. J].

[52]

Liu J, Shi C, Ma X, et al.. An Overview on the Effect of Internal Curing on Shrinkage of High Performance Cement-Based Materials. Construction and Building Materials, 2017, 146: 702-712. J].

[53]

Ma Y, Jin M, Wang F, et al.. Heating-Induced Transformations in Calcium Silicate Hydrate (C-S-H): In-Situ Investigations of Composition, Structure, and Morphology. Cement and Concrete Research, 2025, 190: 107 819. J].

[54]

Qian R, Fu C, Zhang Y, et al.. Investigations on Water Vapor Adsorption-Desorption of Cementitious Materials and Its Induced Permeability under Isothermal Steady-State Flow. Journal of Materials in Civil Engineering, 2024, 36(1): 04 023 527. J].

RIGHTS & PERMISSIONS

Wuhan University of Technology and Springer-Verlag GmbH Germany, Part of Springer Nature

PDF

0

Accesses

0

Citation

Detail

Sections
Recommended

/