Durability of Cement-Ferronickel Slag Composite Mortar under Different Excitation Methods: Frost Resistance, Carbonation Resistance and Chloride Ion Permeability

Hongxia Qiao , Yanning Song , Qiong Feng , Xiaoxia Sun , Chao Wei , Jianghua Zheng

Journal of Wuhan University of Technology Materials Science Edition ›› 2026, Vol. 41 ›› Issue (3) : 745 -756.

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Journal of Wuhan University of Technology Materials Science Edition ›› 2026, Vol. 41 ›› Issue (3) :745 -756. DOI: 10.1007/s11595-026-3290-1
Cementitious Materials
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Durability of Cement-Ferronickel Slag Composite Mortar under Different Excitation Methods: Frost Resistance, Carbonation Resistance and Chloride Ion Permeability
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Abstract

In order to explore the influence of different activation methods on the durability of cement-ferro nickel slag composite mortar, the durability of the composite mortar was evaluated by measuring the performance indexes of the composite mortar in the environment of freeze-thaw cycle, accelerated carbonization, and chloride ion penetration. The results show that the mechanical activation and alkali activator improve the reactivity of the cementitious system, and the enhancement of the filling effect and the increase of the hydration products improve the compactness of the internal structure, which not only enhances its frost resistance, but also slows down the transmission rate of CO2 in the accelerated carbonization environment and the ion penetration rate in the chloride ion erosion environment.

Keywords

ferronickel slag / reactivity activation / freeze-thaw cycles / carbonization / chloride ion permeability

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Hongxia Qiao, Yanning Song, Qiong Feng, Xiaoxia Sun, Chao Wei, Jianghua Zheng. Durability of Cement-Ferronickel Slag Composite Mortar under Different Excitation Methods: Frost Resistance, Carbonation Resistance and Chloride Ion Permeability. Journal of Wuhan University of Technology Materials Science Edition, 2026, 41 (3) : 745-756 DOI:10.1007/s11595-026-3290-1

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References

[1]

Carvalho I C, Neto J S A, de Matos P R, et al. The Role of Foreign Ions in Portland Cement Production and Properties: A State-of-the-art Review on Phase Formation, Polymorphism and Hydration[J]. Cement and Concrete Composites, 2025: 105 989

[2]

Amran M, Makul N, Fediuk R, et al.. Global Carbon Recoverability Experiences from the Cement Industry. Case Studies in Construction Materials, 2022, 17: e01 439. J].

[3]

Liu J, Liu B, Li Q, et al. Review of Solid Waste-based Geopolymers: Preparation, Deterioration and Durability[J]. Materials Today Communications, 2025: 111 820

[4]

Wang X, Li Y H, He L H, et al.. Analysis on the Emissions of Carbon Dioxide and Air Pollutants in China’s Cement Industry from 2011 to 2022. Environmental Monitoring in China, 2024, 40(2): 8-18. [J].

[5]

Liu Q, Liu Y, Cai W, et al.. Multi-Dimensional Building Carbon Emissions Echelon Peak Target Setting in China Based on Building Types, Sources, and Indicators. Applied Energy, 2025, 386: 125 532. J].

[6]

de Queiroz Lamas W, Palau J C F, De Camargo J R. Waste Materials Co-processing in Cement Industry: Ecological Efficiency of Waste Reuse. Renewable and Sustainable Energy Reviews, 2013, 19: 200-207. J].

[7]

Choy K K H, Ko D C K, Cheung W H, et al.. Municipal Solid Waste Utilization for Integrated Cement Processing with Waste Minimization: A Pilot Scale Proposal. Process Safety and Environmental Protection, 2004, 82(3): 200-207. J].

[8]

Tsiliyannis C A. Alternative Fuels in Cement Manufacturing: Modeling for Process Optimization under Direct and Compound Operation. Fuel, 2012, 99: 20-39. J].

[9]

Mac Dowell N, Fennell P S, Shah N, et al.. The Role of CO2 Capture and Utilization in Mitigating Climate Change. Nature Climate Change, 2017, 7(4): 243-249. J].

[10]

Monteiro J, Roussanaly S. CCUS scenarios for the cement industry: Is CO2 Utilization Feasible. Journal of CO2 Utilization, 2022, 61: 102 015. J].

[11]

Srivastava S, Cerutti M, Nguyen H, et al.. Carbonated Steel Slags as Supplementary Cementitious Materials: Reaction Kinetics and Phase Evolution. Cement and Concrete Composites, 2023, 142: 105 213. J].

[12]

Chen B, Li B, Pang L, et al.. Study on the Synergistic Preparation of Supplementary Cementitious Materials from Multiple Solid Wastes: Bayer Red Mud and Gold Tailings. Journal of Environmental Chemical Engineering, 2024, 12(3): 112 599. J].

[13]

Silveira V A L, de Resende D S, da Silva Bezerra A C. Sanitary Ware Waste in Eco-friendly Portland Blended Cement: Potential Use as Supplementary Cementitious Material. Cement, 2025, 19: 100 126. J].

[14]

Wang L, Gao Z, Jin Q, et al.. Synergistic Effect of Waste Glass and Steel Slag on Mechanical Property and Microstructure of Cementbased Materials. Powder Technology, 2025, 451: 120 479. J].

[15]

Ndahirwa D, Zmamou H, Lenormand H, et al.. The Role of Supplementary Cementitious Materials in Hydration, Durability and Shrink- age of Cement-based Materials, Their Environmental and Economic Benefits: A Review. Cleaner Materials, 2022, 5: 100 123. J].

[16]

Yang T, Yao X, Zhang Z. Geopolymer Prepared with High-magnesium Nickel Slag: Characterization of Properties and Microstructure. Construction and Building Materials, 2014, 59: 188-194. J].

[17]

Petousis M, Kalderis D, Michailidis N, et al.. Sustainable High-density Polyethylene Ferronickel Slag Composites for Material Extrusion Additive Manufacturing: Engineering, Morphological, Rheological, Thermal, and Chemical Aspects. Sustainable Materials and Technologies, 2025, 43: e01 227. J].

[18]

Maragkos I, Giannopoulou I P, Panias D. Synthesis of Ferronickel Slag-based Geopolymers. Minerals Engineering, 2009, 22(2): 196-203. J].

[19]

Choi Y C, Choi S. Alkali–silica Reactivity of Cementitious Materials using Ferro-nickel Slag Fine Aggregates Produced in Different Cooling Conditions. Construction and Building Materials, 2015, 99: 279-287. J].

[20]

Zhai M, Zhu H, Liang G, et al.. Enhancing the Recyclability of Aircooled High-magnesium Ferronickel Slag in Cement-based Materials: A Study of Assessing Soundness through Modifying Method. Construction and Building Materials, 2020, 261: 120 523. J].

[21]

Liu T, Duan X, Lu S, et al.. Mineral Phase Reconstruction Mechanism of Forsterite Refractory Prepared from Ferronickel Slag. Construction and Building Materials, 2025, 464: 140 191. J].

[22]

Wang D, Wang Q, Zhuang S, et al.. Evaluation of Alkali-activated Blast Furnace Ferronickel Slag as a Cementitious Material: Reaction Mechanism, Engineering Properties and Leaching Behaviors. Construction and Building Materials, 2018, 188: 860-873. J].

[23]

Yanning S, Qiao H, Qiong F, et al.. Application of Metallurgical Ferronickel Slag in Building Materials: A Review. Journal of Building Engineering, 2024, 96: 110 632. J].

[24]

Gao F, Huang Z, Li H, et al.. Recovery of Magnesium from Ferronickel Slag to Prepare Hydrated Magnesium Sulfate by Hydrometallurgy Method. Journal of Cleaner Production, 2021, 303: 127 049. J].

[25]

Wu Q, Wang S, Yang T, et al.. Effect of High-magnesium Nickel Slag on Hydration Characteristics of Portland Cement. Journal of Materials in Civil Engineering, 2019, 31(5): 04 019 051. J].

[26]

Saha A K, Sarker P K. Sustainable use of Ferronickel Slag Fine Aggregate and Fly Ash in Structural Concrete: Mechanical Properties and Leaching Study. Journal of Cleaner Production, 2017, 162: 438-448. J].

[27]

Sun J, Feng J, Chen Z. Effect of Ferronickel Slag as Fine Aggregate on Properties of Concrete. Construction and Building Materials, 2019, 206: 201-209. J].

[28]

Karamanov A, Paunović P, Ranguelov B, et al.. Vitrification of Hazardous Fe-Ni Wastes into Glass-ceramic with Fine Crystalline Structure and Elevated Exploitation Characteristics. Journal of Environmental Chemical Engineering, 2017, 5(1): 432-441. J].

[29]

Peng Z, Shen D, Wang X, et al.. Preparation of Lightweight Thermal Insulation Materials from Municipal Solid Waste Incineration Fly Ash and Ferronickel Slag. Ceramics International, 2025, 51(12): 15 171-15 180. J].

[30]

Chi L, Lu S, Li Z, et al.. Recycling of Ferronickel Slag Tailing in Cementitious Materials: Activation and Performance. Science of the Total Environment, 2023, 861: 160 706. J].

[31]

Huang Z, Wang Q, Lu J. The Effects of Cations and Concentration on Reaction Mechanism of Alkali-activated Blast Furnace Ferronickel Slag. Composites Part B: Engineering, 2022, 236: 109 825. J].

[32]

Wu F, Li H, Yang K. Effects of Mechanical Activation on Physical and Chemical Characteristics of Coal-Gasification Slag. Coatings, 2021, 11(8): 902. J].

[33]

Sobolev K, Lin Z, Flores-Vivian I, et al.. Nano-Engineered Cements with Enhanced Mechanical Performance. Journal of the American Ceramic Society, 2016, 99(2): 564-572. J].

[34]

Fernández-Jiménez A, Puertas F. Alkali-activated Slag Cements: Kinetic Studies. Cement and Concrete Research, 1997, 27(3): 359-368. J].

[35]

Bao J, Zheng R, Yu Z, et al.. Freeze-thaw Resistance of Recycled Aggregate Concrete Incorporating Ferronickel Slag as Fine Aggregate. Construction and Building Materials, 2022, 356: 129 178. J].

[36]

Liu X, Li T, Tian W, et al.. Study on the Durability of Concrete with FNS Fine Aggregate. Journal of Hazardous Materials, 2020, 381: 120 936. J].

[37]

Yanning S, Qiong F, Hongxia Q, et al.. Study on Mechanically Activated Ferrous Extraction Tailing of Nickel Slag as Cementitious Materials: Physical and Chemical Properties, Mechanical Properties and Reaction Mechanism. Construction and Building Materials, 2024, 422: 135 748. J].

[38]

Yanning S, Hongxia Q, Qiong F, et al.. Effect of Ball Milling-Ca(OH)2 Coupling Activation on the Cementitious Properties of Ferrous Extraction Tailing of Nickel slag: Basic Properties, Hydration Mechanism and Heavy Metal Safety. Materials Today Communications, 2024, 39: 109 376. J].

[39]

Song Y, Qiao H, Feng Q, et al.. Feasibility Study of Adding Alkali Activator Ca(OH)2 into Ferrous Extraction Tailing of Nickel Slag-ordinary Portland Cement Composite Cementitious System: Working Performance, Mechanical Properties, and Reaction Mechanism. Advances in Cement Research, 2024, 37(3): 172-185. J].

[40]

Phung Q T, Frederickx L, Nguyen T N, et al.. Resistance of Ordinary and Low-carbon Cements to Carbonation: Microstructural and Mineralogical Alteration. Cement and Concrete Composites, 2023, 143: 105 260. J].

[41]

Phung Q T, Maes N, Jacques D, et al.. Effect of Limestone Fillers on Ca-leaching and Carbonation of Cement Pastes. Key Engineering Materials, 2016, 711: 269-276. J].

[42]

Morandeau A, Thiéry M, Dangla P. Impact of Accelerated Carbonation on OPC Cement Paste Blended with Fly Ash. Cement and Concrete Research, 2015, 67: 226-236. J].

[43]

Wang Q, Yan P, Yang J, et al.. Influence of Steel Slag on Mechanical Properties and Durability of Concrete. Construction and Building Materials, 2013, 47: 1 414-1 420. J].

[44]

Sun J, Chen Z. Influences of Limestone Powder on the Resistance of Concretes to the Chloride Ion Penetration and Sulfate Attack. Powder Technology, 2018, 338: 725-733. J].

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