Innovative Porous Alumina Ceramics with Dual Wettability for Efficent Oil/Water Separaton

Zhengyi Zhang , Jiajie Yu , Huanhuan Su , Lifen Shi , Shuqing Fang , Tianhe Wang , Xiaobo Peng

Journal of Wuhan University of Technology Materials Science Edition ›› 2025, Vol. 40 ›› Issue (6) : 1632 -1641.

PDF
Journal of Wuhan University of Technology Materials Science Edition ›› 2025, Vol. 40 ›› Issue (6) :1632 -1641. DOI: 10.1007/s11595-025-3200-y
Advanced Materials
research-article
Innovative Porous Alumina Ceramics with Dual Wettability for Efficent Oil/Water Separaton
Author information +
History +
PDF

Abstract

We presented a novel porous alumina ceramics (PACs) with superoleophilicity and superoleophobicity when immersed in different oil-water environments. The wettability, separation efficiency, permeation flux and reusability of the PACs for oil/water separation were investigated and characterized via extensive experiments. The PACs material had favourable properties including mechanical strength and chemical durability compared with fabric-based materials and organic sponge-based materials previously reported in literature for oil/water separation. It is believed that the PACs material and methodology presented in this work may provide wastewater remediation industry with a promising alternative for dealing with the catastrophic ocean oil pollution and other oil contamination.

Keywords

porous alumina ceramics / oil/water separation / dual wettability / superoleophilicity and superoleophobicity / high compression strength

Cite this article

Download citation ▾
Zhengyi Zhang, Jiajie Yu, Huanhuan Su, Lifen Shi, Shuqing Fang, Tianhe Wang, Xiaobo Peng. Innovative Porous Alumina Ceramics with Dual Wettability for Efficent Oil/Water Separaton. Journal of Wuhan University of Technology Materials Science Edition, 2025, 40(6): 1632-1641 DOI:10.1007/s11595-025-3200-y

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

Gao X, Xu L, Xue Z, et al. . Dual-Scaled Porous Nitrocellulose Membranes with Underwater Superoleophobicity for Highly Efficient Oil/Water Separation. Adv. Mater.. 2014, 26: 1 771-1 775 J]

[2]

Yu Y, Liu P, Wang F, et al. . Preparation of Hydrophobic Fly Ash by Surface Modification and Oil-Water Separation Devices. J. Wuhan Univ. Technol.. 2023, 23(3): 695-700 J]

[3]

Xi M, Yong J, Chen F, et al. . A Femtosecond Laser-Induced Superhygrophobic Surface: Beyond Superhydrophobicity and Repelling Various Complex Liquids. RSC Adv.. 2019, 9(12): 6 650-6 657 J]

[4]

Ma W, Zhang Q, Hua D, et al. . Electrospun Fibers for Oil-Water Separation. RSC Adv.. 2016, 6(16): 12 868-12 884 J]

[5]

Fan H, Cai Y, Bai P, et al. . Preparation of Silica Nanosphere with Vertical Pore and Its Application in Oil-Water Separation. J. Wuhan. Univ. Technol.. 2023, 38(2): 299-303 J]

[6]

Li J, Guan P, Zhang Y, et al. . A Diatomite Coated Mesh with Switchable Wettability for On-Demand Oil/Water Separation and Methylene Blue Adsorption. Sep. Purif. Technol.. 2017, 174: 275-281 J]

[7]

Wang B, Liang W, Guo Z, et al. . Biomimetic Super-Lyophobic and Super-Lyophilic Materials Applied for Oil/Water Separation: A New Strategy Beyond Nature. Chem. Soc. Rev.. 2015, 44: 336-361 J]

[8]

Gaaseidnes K, Turbeville J. Separation of Oil and Water in Oil Spill Recovery Operations. Pure. Appl. Chem.. 1999, 71: 95-101 J]

[9]

Cheryan M, Rajagopalan N. Membrane Processing of Oily Streams. Wastewater Treatment and Waste Reduction. J. Membrane. Sci.. 1998, 151: 13-28 J]

[10]

Rasouli S, Rezaei N, Hamedi H, et al. . Design, Fabrication, and Characterization of a Facile Superhydrophobic and Superoleophilic Mesh-Based Membrane for Selective Oil-Water Separation. Chem. Eng. Sci.. 2021, 236: 116 354 J]

[11]

Hu Y, Zhou F, Zhang N, et al. . Green Synthesis of Iron (II, III)-Polyphenol Nanoparticles and their Adsorption of Malachite Green. J. Wuhan. Univ. Technol.. 2024, 39(04): 1 025-1 030 J]

[12]

Gobbi LCA, Nascimento IL, Muniz EP, et al. . Electrocoagulation with Polarity Switch for Fast Oil Removal from Oil in Water Emulsions. J. Environ. Manag.. 2018, 213: 119-125 J]

[13]

Zhang W, Shi Z, Zhang F, et al. . Superhydrophobic and Superoleophilic PVDF Membranes for Effective Separation of Water-In-Oil Emulsions with High Flux. Adv. Mater.. 2013, 25: 2 071-2 076 J]

[14]

Liu M, Zheng Y, Zha J, et al. . Bioinspired Super-Antiwetting Interfaces with Special Liquid-Solid Adhesion. Accounts. Chem. Res.. 2009, 43: 368-377 J]

[15]

Yu T, Lu S, Xu W. A Reliable Filter for Oil-Water Separation: Bismuth Coated Superhydrophobic/Superoleophilic Iron Mesh. J. Alloys Compd.. 2018, 769: 576-587 J]

[16]

Onda T, Shibuichi S, Satoh N, et al. . Super-Water-Repellent Fractal Surfaces. Langmuir. 1996, 12: 2 125-2 127 J]

[17]

Tseng HH, Wu J, Lin Y, et al. . Superoleophilic and Superhydrophobic Carbon Membranes for High Quantity and Quality Separation of Trace Water-In-Oil Emulsions. J. Membr. Sci.. 2018, 559: 148-158 J]

[18]

Feng L, Zhang Z, Mai Z, et al. . A Super-Hydrophobic and Super-Oleophilic Coating Mesh Film for the Separation of Oil and Water. Angew. Chem.. 2014, 116: 2 046-2 048 J]

[19]

Wen N, Miao X, Chen H, et al. . An Alternative Fabrication of Underoil Superhydrophobic or Underwater Superoleophobic Stainless Steel Meshes for Oil-Water Separation: Originating from One-Step Vapor Deposition of Polydimethylsiloxane. Sep. Purif. Technol.. 2018, 204: 116-126 J]

[20]

Li A, Sun H, Tan D, et al. . Superhydrophobic Conjugated Microporous Polymers for Separation and Adsorption. Energ. Environ. Sci.. 2011, 4: 2 062-2 065 J]

[21]

Yu J, Liu S, Chen S, et al. . Simultaneous Preparation of Mesoporous/Macroporous Graphene Aerogels and Bright Green Photoluminescent Graphene Quantum Dots by a Simple Solvothermal Method. Ind. Eng. Chem. Res.. 2017, 56: 10 028-10 035 J]

[22]

Jin M, Wang J, Yao X, et al. . Underwater Oil Capture by a Three-Dimensional Network Architectured Organosilane Surface. Adv. Mater.. 2011, 23: 2 861-2 864 J]

[23]

Tang H, Hao L, Chen J, et al. . Surface Modification to Fabricate Superhydrophobic and Superoleophilic Alumina Membranes for Oil/Water Separation. Energy. Fuel.. 2018, 32(3): 3 627-3 636 J]

[24]

Xu L, Jing Z, Su B, et al. . An Ion-Induced Low-Oil-Adhesion Organic/Inorganic Hybrid Film for Stable Superoleophobicity in Seawater. Adv. Mater.. 2013, 25: 606-611 J]

[25]

Xue Z, Wang S, Lin L, et al. . A Novel Superhydrophilic and Underwater Superoleophobic Hydrogel-Coated Mesh for Oil/Water Separation. Adv. Mater.. 2011, 23: 4 270-4 273 J]

[26]

Wen Q, Di J, Jiang L, et al. . Zeolite-Coated Mesh Film for Efficient Oil-Water Separation. Chem. Sci.. 2013, 4: 591-595 J]

[27]

Zhang L, Zhong Y, Cha D, et al. . A Self-Cleaning Underwater Superoleophobic Mesh for Oil-Water Separation. Sci. Rep-UK. 2013, 3: 2 326 J]

[28]

Du Z, Ding P, Tai X, et al. . Facile Preparation of Ag-Coated Superhydrophobic/Superoleophilic Mesh for Efficient Oil/Water Separation with Excellent Corrosion Resistance. Langmuir. 2018, 34(23): 6 922-6 929 J]

[29]

Wang J, Geng G. Simple and Eco-Friendly Fabrication of Superhydrophobic Textile for Oil/Water Separation. Environ. Technol.. 2016, 37(13): 1 591-1 596 J]

[30]

Li Y, Pan Y, Zhao X. Interface Conditions of Roughness-Induced Superoleophilic and Superoleophobic Surfaces Immersed in Hexadecane and Ethylene Glycol. Beilstein J. Nanotechnol.. 2017, 8(1): 2 504-2 514 J]

[31]

Wu H, Wu L, Lu S, et al. . Robust Superhydrophobic and Superoleophilic Filter Paper via Atom Transfer Radical Polymerization for Oil/Water Separation. Carbohydr. Polym.. 2018, 181: 419-425 J]

[32]

Yu J, Yang J, Sun D, et al. . A novel Nanoporous Surface for Immobilization and Expression of Functional Chemicals. Mater. Lett.. 2016, 180: 148-152 J]

[33]

Yu J, Shen M, Liu S, et al. . A Simple Technique for Direct Growth of Au into a Nanoporous Alumina Layer on Conductive Glass as a Reusable SERS Substrate. Appl. Surf. Sci.. 2017, 406: 285-293 J]

[34]

Cai Y, Li S, Cheng Z, et al. . Facile Fabrication of Superhydrophobic FAS Modified Electroless Ni-P Coating Meshes for Rapid Water-Oil Separation. Colloids. Surf. A. 2018, 540: 224-232 J]

[35]

Li L, Li B, Dong J, et al. . Roles of Silanes and Silicones in Forming Superhydrophobic and Superoleophobic Materials. J. Mater. Chem. A. 2016, 4(36): 13 677-13 725 J]

[36]

Young T. An Essay on the Cohesion of Fluids. Philos. Trans. R. Soc. London.. 1805, 95: 65-87 J]

[37]

Jung YC, Bhushan B. Wetting Behavior of Water and Oil Droplets in Three-Phase Interfaces for Hydrophobicity/Philicity and Oleophobicity/Philicity. Langmuir. 2009, 25: 14 165-14 173 J]

[38]

Wenzel RN. Resistance of Solid Surfaces to Wetting by Water. Ind. Eng. Chem.. 1936, 28: 988-994 J]

[39]

Cassie ABD, Baxter S. Wettability of Porous Surfaces. Trans. Faraday. soc.. 1944, 40: 546-551 J]

[40]

Xiao C, Si L, Liu Y, et al. . Ultrastable Coaxial Cable-Like Superhydrophobic Mesh with Self-Adaption Effect: Facile Synthesis and Oil/Water Separation Application. J. Mater. Chem. A. 2016, 4(21): 8 080-8 090 J]

[41]

Latthe SS, Demirel AL. Polystyrene/Octadecyltrichlorosilane Superhydrophobic Coatings with Hierarchical Morphology. Polym. Chem-UK.. 2013, 4: 246-249 J]

[42]

Gan W, Gao L, Sun Q, et al. . Multifunctional Wood Materials with Magnetic, Superhydrophobic and Anti-Ultraviolet Properties. Appl. Surf. Sci.. 2015, 332: 565-572 J]

[43]

Lv J, Gong Z, He Z, et al. . 3D Printing of a Mechanically Durable Superhydrophobic Porous Membrane for Oil-Water Separation. J. Mater. Chem. A. 2017, 5(24): 12 435-12 444 J]

RIGHTS & PERMISSIONS

Wuhan University of Technology and Springer-Verlag GmbH Germany, Part of Springer Nature

PDF

0

Accesses

0

Citation

Detail

Sections
Recommended

/