Tailoring Carbon Distribution in α/γ Phase of Ductile Iron and Its Effects on Thermal Conductivity

Chen Liu , Yuzhou Du , Tao Ying , Liandong Zhang , Xinyu Zhang , Dan Dong , Bailing Jiang

Journal of Wuhan University of Technology Materials Science Edition ›› 2023, Vol. 38 ›› Issue (3) : 645 -651.

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Journal of Wuhan University of Technology Materials Science Edition ›› 2023, Vol. 38 ›› Issue (3) : 645 -651. DOI: 10.1007/s11595-023-2740-2
Metallic Materials

Tailoring Carbon Distribution in α/γ Phase of Ductile Iron and Its Effects on Thermal Conductivity

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Abstract

The effects of carbon distribution on the microstructure and thermal conductivity of ductile iron were investigated in the present study. The microstructure of as-cast and quenched ductile iron were characterized by OM and SEM. Results showed that the microstructure of as-cast ductile iron was composed of spheroidal graphite, ferrite with the volume of 80%, and a small amount of pearlite, and quenched ductile iron was composed of spheroidal graphite, coarse/fine acicular martensite (α M phase) and high-carbon retained austenite (γ phase). The volume fraction of retained austensite and its carbon content for direct quenched ductile iron and tepmered ductile iron were quantitatively analysed by XRD. Results revealed that carbon atoms diffused from α M phase to γ phase during tempering at low temperatures, which resulted in carbon content in retained γ phase increasing from 1.2 wt% for the direct quenched sample to about 1.9 wt% for the tempered samples. Consequently, the lattice distortion was significantly reduced and gave rise to an increase of thermal conductivity for ductile iron.

Keywords

ductile iron / carbon distribution / retained austenite / thermal conductivity / lattice distortion

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Chen Liu, Yuzhou Du, Tao Ying, Liandong Zhang, Xinyu Zhang, Dan Dong, Bailing Jiang. Tailoring Carbon Distribution in α/γ Phase of Ductile Iron and Its Effects on Thermal Conductivity. Journal of Wuhan University of Technology Materials Science Edition, 2023, 38(3): 645-651 DOI:10.1007/s11595-023-2740-2

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References

[1]

Dhanasekaran S, Vadiraj A, Balachandran G, et al. Mechanical Behaviour of an Austempered Ductile Iron[J]. T. Indian I. Metals, 2010, 63(5): 779-785.

[2]

Ghassemali E, Hernando J C, Stefanescu D M, et al. Revisiting the Graphite Nodule in Ductile Iron[J]. Scripta Mater., 2019, 161: 66-69.

[3]

Chen L S, Hu B J, Xu J H, et al. Cu Partitioning Behavior and Its Effect on Microstructure and Mechanical Properties of 0.12C-1.33Mn-0.55Cu Q&P Steel[J]. J. Wuhan. Univ. Technol. -Materials Science Edition, 2017, 32(5): 1179-1185.

[4]

Dakre V, Peshwe D R, Pathak S U, et al. Mechanical Characterization of Austempered Ductile Iron Obtained by two Step Austempering Process[J]. T. Indian I. Metals, 2017, 70(9): 2381-2387.

[5]

Zhang M Y, Zhu F X, Duan Z T, et al. Characteristics of Retained Austenite in TRIP Steels with Bainitic Ferrite Matrix[J]. J. Wuhan. Univ. Technol. -Materials Science Edition, 2011, 26(6): 1148-1151.

[6]

Nishikawa A S, Miyamoto G, Furuhara T, et al. Phase Transformation Mechanisms during Quenching and Partitioning of a Ductile Cast Iron[J]. Acta Mater., 2019, 179: 1-16.

[7]

Wang X, Du Y, Liu B, et al. Enhanced Plasticity of Austempered Ductile Iron (ADI) by Partitioning Treatment[J]. Mater. Sci. Eng. A, 2021, 804: 140 513.

[8]

Melado A C, Nishikawa A S, Goldenstein H, et al. Effect of Microstructure on Fatigue Behaviour of Advanced High Strength Ductile Cast Iron Produced by Quenching and Partitioning Process[J]. Int. J. Fatigue, 2017, 104: 397-407.

[9]

Akinribide O J, Akinwamide S O, Obadele B A, et al. Tribological Behaviour of Ductile and Austempered Grey Cast Iron under Dry Environment[J]. Materials Today: Proceedings, 2020, 38: 1174-1182.

[10]

Du Y, Wang X, Zhang D, et al. A Superior Strength and Sliding-Wear Resistance Combination of Ductile Iron with Nanobainitic Matrix[J]. J. Mater. Res. Technol., 2021, 11: 1175-1183.

[11]

Sazegaran H, Kiani-Rashid A-R, Khaki J V. Effects of Sphere Size on the Microstructure and Mechanical Properties of Ductile Iron-Steel Hollow Sphere Syntactic Foams[J]. Int. J. Min. Met. Mater., 2016, 23(6): 676-682.

[12]

Quinn T F J. The Effect of “Hot-Spot” Temperatures on the Unlubricated Wear of Steel[J]. A S L E Trans., 1967, 10(2): 158-168.

[13]

Holmgren D. Review of Thermal Conductivity of Cast Iron[J]. Inter. J. Cast Metals Res., 2005, 18(6): 331-345.

[14]

Rukadikar M C, Reddy G P. Influence of Chemical Composition and Microstructure on Thermal Conductivity of Alloyed Pearlitic Flake Graphite Cast Irons[J]. J. Mater. Sci., 1986, 21(12): 4403-4410.

[15]

Williams R K, Yarbrough D W, Masey J W, et al. Experimental Determination of the Phonon and Electron Components of the Thermal Conductivity of Bcc Iron[J]. J. Appl. Phys., 1981, 52(8): 5167-5175.

[16]

Xiao L, Fan Z, Jinxiu Z, et al. Lattice-Parameter Variation with Carbon Content of Martensite: X-ray-diffraction Experimental Study[J]. Phys. Rev. B, 1995, 52(14): 9970-9978.

[17]

Zhang K, Zhang M, Guo Z, et al. A New Effect of Retained Austenite on Ductility Enhancement in High-strength Quenching-Partitioning-Tempering Martensitic Steel[J]. Mater. Sci. Eng. A, 2011, 528(29): 8486-8491.

[18]

Yan G, Xu Y, Jiang B. The Production of High-density Hollow Cast-Iron Bars by Vertically Continuous Casting[J]. J. Mater. Process. Technol., 2012, 212(1): 15-18.

[19]

Wang C Y, Shi J, Cao W Q, et al. Characterization of Microstructure Obtained by Quenching and Partitioning Process in Low Alloy Martensitic Steel[J]. Mater. Sci. Eng. A, 2010, 527(15): 3442-3449.

[20]

Wen F, Zhao J, Zheng D, et al. The Role of Bainite in Wear and Friction Behavior of Austempered Ductile Iron[J]. Materials, 2019, 12(5): 767-779.

[21]

Roberts C S. Effect of Carbon on the Volume Fractions and Lattice Parameters of Retained Austenite and Martensite[J]. J. Metalcast., 1953, 5(2): 203-204.

[22]

Selin M. Tensile and Thermal Properties in Compacted Graphite Irons at Elevated Temperatures[J]. Metall. Mater. Trans. A, 2010, 41(12): 3100-3109.

[23]

Holmgren D M, Diószegi A, Svensson I L. Effects of Transition from Lamellar to Compacted Graphite on Thermal Conductivity of Cast Iron[J]. Inter. J. Cast Metals Res., 2006, 19(6): 303-313.

[24]

Shinde V D, Ravi B, Narasimhan K. Solidification Behaviour and Mechanical Properties of Ductile Iron Castings with Varying Thickness[J]. Inter. J. Cast Metals Res., 2012, 25(6): 364-373.

[25]

De Moor E, Lacroix S, Clarke A J, et al. Effect of Retained Austenite Stabilized via Quench and Partitioning on the Strain Hardening of Martensitic Steels[J]. Metall. Mater. Trans. A, 2008, 39(11): 2586-2595.

[26]

Vélez J M, Garboggini A, Tschiptschin A P. Effect of Silicon on Kinetics of Bainitic Reaction in Austempered Ductile Cast Iron[J]. Mater. Sci. Technol., 1996, 12(4): 329-337.

[27]

Williams R K, Graves R S, Weaver F J, et al. Effect of Point Defects on the Phonon Thermal Conductivity of Bcc Iron[J]. J. Appl. Phys., 1987, 62(7): 2778-2783.

[28]

Fan H Y, Tang Z H, Li W, et al. The Influence of Temperature on the Thermal Conductivity of Cast Irons[J]. Mater. Rev., 1996, 3: 23-25.

[29]

Matsushita T, Saro A G, Elmquist L, et al. On the Specific Heat and Thermal Diffusivity of CGI and SGI Cast Irons[J]. Int. J. Cast Metals Res., 2017, 30(5): 276-282.

[30]

Çelik G A, Tzini M-I T, Polat Ş, et al. Thermal and Microstructural Characterization of a Novel Ductile Cast iron Modified by Aluminum Addition[J]. Int. J. Min. Met. Mater., 2020, 27(2): 190-199.

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