Effect of Different Titanium Surface Treatments on the Adhesion Test Result: Dental Application

Abstract

The aim of the study was to investigate the effect of different surface treatment of titanium (Ti) on the adhesion test results for dental application. Ti substrates roughened by 400 to 1 500-grit SiC polish papers and alumina blasting, alkali treated by 5 molar (M) NaOH and KOH solutions and heat treated at the temperature range of 400–800 °C were used in this study. The treated samples were subjected to the adhesion test. According to the results of the adhesion test, the adhesive strength showed the highest value for the blasted titanium among all polished and blasted samples. The Ti samples heated at 650 °C showed the highest adhesive strength among all heat-treated samples. Further, the adhesion test results indicated the higher adhesive strength of chemically treated samples treated by NaOH rather than that by KOH. The polished and heated Ti samples showed the highest adhesive strength among all samples.

Keywords

titanium implant / surface treatment / bonding strength / anatase / rutile

References

[1] Wu J M, Wang M, Li Y W, et al. Crystallization of Amorphous Titania Gel by Hot Water Aging and Induction of in Vitro Apatite Formation by Crystallized Titania[J]. Surf. Coat. Technol., 2006, 201(3–4): 755-761.

[2] Pandit A, Planell J, Navarro A N. A-Titanium and Nitinol (NiTi)[M]. Biomat. Sci. (Third Edition), 2013 Amsterdam: Elsevier.

[3] Zavanelli R A, Pessanha Henriques G E, Ferreira I, et al. Corrosion-fatigue Life of Commercially Pure Titanium and Ti-6Al-4V Alloys in Different Storage Environments[J]. The J. Prost. Dent., 2000, 84(3): 274-279.

[4] Wei M, Kim H, Kokubo T, et al. Optimising the Bioactivity of Alkaline-treated Titanium Alloy[J]. Mater. Sci. Eng: C, 2002, 20(1–2): 125-134.

[5] Wu J M. Low-temperature Preparation of Titania Nanorods Through Direct Oxidation of Titanium with Hydrogen Peroxide[J]. J. Cryst. Growth, 2004, 269(2–4): 347-355.

[6] Khodaei M, Valanezhad A, Watanabe I, et al. Surface and Mechanical Properties of Modified Porous Titanium Scaffold[J]. Surf. Coat. Technol., 2017, 315: 61-66.

[7] Valanezhad A, Tsuru K, Maruta M, et al. A New Biocompatible Coating Layer Applied on Titanium Substrates Using a Modified Zinc Phosphatizing Method[J]. Surf. Coat. Technol., 2012, 206(8–9): 2 207-2 212.

[8] Khodaei M, Meratian M, Savabi O, et al. The Side Effects of Surface Modification of Porous Titanium Implant Using Hydrogen Peroxide: Mechanical Properties Aspects[J]. Mater. Lett., 2016, 178: 201-204.

[9] Kosmulski M. The Significance of the Difference in the Point of Zero Charge between Rutile and Anatase[J]. Adv. Colloid Interface Sci., 2002, 99(3): 255-264.

[10] Frauchiger V M. (ETH Zürich)[M], 1999 Zurikh: Swiss Federal Institute of Technology.

[11] Kim D J, Hahn S H, Oh S H, et al. Influence of Calcination Temperature on Structural and Optical Properties of TiO₂ Thin Films Prepared by Sol-gel Dip Coating[J]. Mater. Lett., 2002, 57(2): 355-360.

[12] Pattanayak D K, Yamaguchi S, Matsushita T, et al. Nanostructured Positively Charged Bioactive TiO₂ Layer Formed on Ti Metal by NaOH, Acid and Heat Treatments[J]. J. Mater. Med., 2011, 22(8): 1 803-1 812.

[13] Ohyama T. Adherence Test Uing Vertical Pull Instrument with Stud Pin[J]. J. Surf. Finish. Soc. Jpn., 2007, 58(5): 292

[14] Sykes J M, Brewis D M. Surface Analysis and Pretreatment of Plastics and Metals[J]. Applied Science London, 1982: 153

[15] Aero De Bruyne NA. Research Technical Notes[B]. Aero Research Ltd Cambridge.,1958

[16] Packham D E, Packham D E. Handbook of Adhesion[M], 1992 New York: Longman Group (FE) Ltd.

[17] Tanaka Y, Saito H, Tsusumi Y, et al. Active Hydroxyl Groups on Surface Oxide Film of Titanium, 316L Stainless Steel, and Cobalt-Chromium-Molybdenum Alloy and Its Effect on the Immobilization of Poly (Ethylene Glycol)[J]. Mater. Trans., 2008, 49(4): 805-811.

[18] Mardare D, Rusu G L. The Influence of Heat Treatment on the Optical Properties of Titanium Oxide Thin Films[J]. Materials Letters, 2002, 56(3): 210-214.

[19] Rohanizadeh R, Al-Sadeq M, Geros R Z L. Preparation of Different Forms of Titanium Oxide on Titanium Surface: Effects on Apatite Deposition[J]. J. Biomed. Mater. Res., Part A, 2004, 71: 343-352.

[20] Adachi M, Mackert J R Jr, Parry E E, et al. Oxide Adherence and Porcelain Bonding to Titanium and Ti-6A1–4V Alloy[J]. J. Dent. Res., 1990, 69(6): 1 230-1 235.

[21] Tubíoa C R, Guitián F, Salgueiro J R, et al. Anatase and Rutile TiO₂ Monodisperse Microspheres by Rapid Thermal Annealing: A Method to Avoid Sintering at High Temperatures[J]. Mater. Lett., 2015, 141: 203-206.

[22] Edalati K, Wang Q, Razavi-Khosroshahi H, et al. Low-temperature Anatase-to-rutile Phase Transformation and Unusual Grain Coarsening in Titanium Oxide Nanopowders by High-pressure Torsion Straining[J]. Scripta Mater., 2019, 162: 341-344.

[23] Medvids A, Varnagiris S, Letko E, et al. Phase Transformation from Rutile to Anatase with Oxygen Ion Dose in the TiO₂ Layer Formed on a Tiubstrate[J]. Mat. Sci. Semicon Proc., 2020, 106(104776): 1-6.