The Combined Impact of Magnetic Field and Chloride Ion Concentration on Corrosion Behavior of Al-Mg Alloys

Xin Zhang , Lianpeng Huang , Jiahao Tao , Zehua Wang , Zehua Zhou , Xin Cai , Tao Wen

Journal of Wuhan University of Technology Materials Science Edition ›› 2023, Vol. 37 ›› Issue (6) : 1192 -1203.

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Journal of Wuhan University of Technology Materials Science Edition ›› 2023, Vol. 37 ›› Issue (6) : 1192 -1203. DOI: 10.1007/s11595-022-2652-6
Metallic Materials

The Combined Impact of Magnetic Field and Chloride Ion Concentration on Corrosion Behavior of Al-Mg Alloys

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Abstract

The impact of magnetic field on the corrosion behavior of Al-Mg-xRE/Fe alloys in NaCl solutions with concentrations of 1.5wt%, 3.5wt%, and 5.5wt% were studied by microstructure observation, immersion test, and electrochemical test. The combined impacts of magnetic field and chloride ion concentration on the corrosion behavior of Al-Mg alloys with various electrode potential phases were discussed. The results indicate that Al-3.0Mg-xRE/Fe alloys corrode faster and have a higher pitting corrosion potential in the NaCl solution with a higher concentration. In addition, a magnetic field can lower the pitting sensitivity and corrosion rate of Al-3.0Mg and Al-3.0Mg-0.2RE/Fe alloys in NaCl solution with different concentrations. However, at a higher concentration of NaCl solution, the magnetic field has a weaker inhibiting effect on corrosion rate and pitting sensitivity. In NaCl solutions with concentrations of 1.5wt% and 3.5wt%, the corrosion rate and pitting sensitivity of Al-3.0Mg-1.0RE/Fe alloys can be reduced by a magnetic field. However, in NaCl solution with the concentration of 5.5wt%, the corrosion rate of the alloys is increased by a magnetic field.

Keywords

magnetic field / corrosion behavior / chloride ion concentration / different electrode potential phases

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Xin Zhang, Lianpeng Huang, Jiahao Tao, Zehua Wang, Zehua Zhou, Xin Cai, Tao Wen. The Combined Impact of Magnetic Field and Chloride Ion Concentration on Corrosion Behavior of Al-Mg Alloys. Journal of Wuhan University of Technology Materials Science Edition, 2023, 37(6): 1192-1203 DOI:10.1007/s11595-022-2652-6

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References

[1]

Cho CH, Son HW, Lee JC, et al. Effect of High Mg Content and Processing Parameters on Portevin-Le Chatelier and Negative Strain Rate Sensitivity Effects in Al-Mg Alloys[J]. Mater. Sci. Eng., 2020, 779: 139 151.

[2]

Saravanan S, Raghukandan K. Microstructure and Mechanical Strength Predicative Modeling in Al 5052-Trapezoidal Grooved SS 304 Explosive Cladding[J]. J. Wuhan Univ. Technol., 2020, 35(5): 958-966.

[3]

Gao TJ, Yao YJ, Wang XK, et al. Effect of Interface Friction on Overlapping Sheets Bulging Formability and Microstructure of 5A02 Aluminum Alloy[J]. J. Wuhan Univ. Technol., 2019, 34(4): 919-924.

[4]

Beura VK, Kale C, Srinivasan S, et al. Corrosion Behavior of a Dynamically Deformed Al-Mg Alloy[J]. Electrochim. Acta, 2020, 384: 136 695.

[5]

Zhang H, Gu DD, Dai DH, et al. Influence of Heat Treatment on Corrosion Behavior of Rare Earth Element Sc Modified Al-Mg Alloy Processed by Selective Laser Melting[J]. Appl. Surf. Sci., 2020, 509: 145 330.

[6]

Fan LT, Ma JJ, Zou CX, et al. Reveling Foundations of the Intergranular Corrosion of 5xxx and 6xxx Al Alloys[J]. Mater. Lett., 2020, 271: 127 767.

[7]

Zhang Q, Zhang PL, Yu ZS, et al. Microstructure and Properties of an Al 6061/Galvanized Plate Fabricated by CMT Welding[J]. J. Wuhan Univ. Technol., 2020, 35(5): 937-945.

[8]

Qi X, Sun B, Chen XM, et al. Localized Corrosion and Stress Corrosion Cracking Behavior of AA7003 in a 3.5wt% NaCl Aqueous Solution[J]. J. Wuhan Univ. Technol., 2020, 35(5): 986-995.

[9]

Jiang G, Bai ZH, Luo BH, et al. Effects of Different Electrolytes on Stress Corrosion Properties of 2A12 Aluminum Alloy[J]. J. Wuhan Univ. Technol., 2021, 36(3): 400-406.

[10]

Cui TF, Liu DX, Shi PA, et al. Effect of Stress and Galvanic Factors on the Corrosion Behave of Aluminum Alloy[J]. J. Wuhan Univ. Technol., 2018, 33(3): 688-696.

[11]

Hinds G, Coey JMD, Lyons MEG. Influence of Magnetic Forces on Electrochemical Mass Transport[J]. Electrochem. Commun., 2001, 3: 215-218.

[12]

Aaboubi O, Chopart JP, Douglade J, et al. Magnetic Field Effects on Mass Transport[J]. J. Electrochem. Soc., 1990, 137: 1 796-1 804.

[13]

Zhang P, Zhu Q, Su Q, et al. Corrosion Behavior of T2 Copper in 3.5% Sodium Chloride Solution Treated by Rotating Electromagnetic Field[J]. Trans. Nonferrous Metals Soc. China, 2016, 26: 1 439-1 446.

[14]

Hu J, Dong CF, Li XG, et al. Effects of Applied Magnetic Field on Corrosion of Beryllium Copper in NaCl Solution[J]. J. Mater. Sci. Technol., 2010, 26: 355-361.

[15]

Chiba A, Ogawa T. Effects of Magnetic Field Direction on the Dissolution of Copper, Zinc, and Brass in Nitric Acid[J]. Corros. Eng., 1989, 38: 523-528.

[16]

Devos O, Aaboubi O, Chopart JP, et al. EIS Investigation of Zinc Electrodeposition in Basic Media at Low Mass Transfer Rates Induced by a Magnetic Field[J]. J. Phys. Chem. B, 1999, 103: 496-501.

[17]

Sueptitz R, Koza J, Uhlemann M, et al. Magnetic Field Effect on the Anodic Behavior of a Ferromagnetic Electrode in Acidic Solution[J]. Electrochim. Acta, 2009, 54: 2 229-2 233.

[18]

Espina-Hernandez JH, Caleyo F, Venegas V, et al. Pitting Corrosion in Low Carbon Steel Influenced by Remanent Magnetization[J]. Corrosion Sci., 2011, 53: 3 100-3 107.

[19]

Zhang X, Wang ZH, Zhou ZH, et al. Effects of Magnetic Field and Rare Earth Addition on Corrosion Behavior of Al-3.0wt% Mg Alloy[J]. J. Alloys Compd., 2017, 698: 241-249.

[20]

Zhang X, Wang ZH, Zhou ZH, et al. Corrosion Behavior of Al-3.0 wt.%Mg Alloy in NaCl Solution under Magnetic Field[J]. Rare Met., 2017, 36: 627-634.

[21]

Zhang X, Wang ZH, Zhou ZH, et al. Impact of Magnetic Field on Corrosion Performance of Al-Mg Alloy with Different Electrode Potential Phases[J]. Intermetallics, 2021, 129: 107 037.

[22]

Li XJ, Zhang M, Yuan BY, et al. Effect of Magnetic Field on the Corrosion Dissolution of the 304 SSFeCl3 System[J]. Electrochim. Acta, 2016, 222: 619-626.

[23]

Lu Z, Huang C, Huang D, et al. Effects of a Magnetic Field on the Anodic Dissolution, Passivation and Transpassivation Behavior of Iron in Weakly Alkaline Solutions with or without Halides[J]. Corrosion Sci., 2006, 48: 3 049-3 077.

[24]

Lu Z, Yang W. In situ Monitoring the Effects of a Magnetic Field on the Opencircuit Corrosion States of Iron in Acidic and Neutral Solutions[J]. Corrosion Sci., 2008, 50: 510-522.

[25]

Sueptitz R, Tschulik K, Uhlemann M, et al. Impact of Magnetic Field Gradients on the Free Corrosion of Iron[J]. Electrochim. Acta, 2010, 55: 5 200-5 203.

[26]

Kelly E J. Magnetic Field Effects on Electrochemical Reactions Occurring at Metal/Flowing-electrolyte Interfaces[J]. Electrochim. Soc., 1977, 124: 987-994.

[27]

Despic AR. Electrochemical Properties of Aluminum Alloys Containing Indium, Gallium and Thallium[J]. J. Appl. Electrochem., 1976, 6: 527-542.

[28]

Zhang X, Wang ZH, Zhou ZH, et al. Effects of Cerium and Lanthanum on the Corrosion Behavior of Al-3.0wt%Mg Alloy[J]. J. Mater. Eng. Perform., 2016, 25: 1 122-1 128.

[29]

Zhang X, Wang ZH, Zhou ZH, et al. Influence of Rare Earth (Ce and La) Addition on the Performance of Al-3.0wt%Mg Alloy[J]. J. Wuhan Univ Technol., 2017, 32: 611-618.

[30]

Huang ZH, Guo XF, Zhang ZM, et al. Effects of Ce on Corrosion Resistance of AZ91D Magnesium Alloy[J]. Acta Metall. Sin., 2005, 18: 129-136.

[31]

Despic AR. Electrochemical Properties of Aluminum Alloys Containing Indium, Gallium and Thallium[J]. J. Appl. Electrochem., 1976, 6: 527-542.

[32]

Ford FP, Burstein GT, Hoar TP. Bare Surface Reaction Rates and Their Relation to Environment Controlled Cracking of Aluminum Alloys[J]. J. Electrochem. Soc., 1980, 127: 1 325-1 331.

[33]

O’Brien RN, Santhanam KSV. Electrochemical Hydrodynamics in Magnetic Fields with Laser Interferometry: Influence of Paramagnetic Ions[J]. J. Appl. Electrochem., 1990, 20: 427-437.

[34]

Waskaas M, Kharkats YI. Effect of Magnetic Fields on Convection in Solutions Containing Paramagnetic Ions[J]. J. Electron. Chem., 2001, 502: 51-57.

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