KGM Derived CNTs Foam/Epoxy Composites with Excellent Microwave Absorbing Performance

Xiaoyan Zhang , Yan Zhao , Shuang Li , Kai Wang

Journal of Wuhan University of Technology Materials Science Edition ›› 2022, Vol. 37 ›› Issue (2) : 155 -162.

PDF
Journal of Wuhan University of Technology Materials Science Edition ›› 2022, Vol. 37 ›› Issue (2) : 155 -162. DOI: 10.1007/s11595-022-2512-4
Advanced Materials

KGM Derived CNTs Foam/Epoxy Composites with Excellent Microwave Absorbing Performance

Author information +
History +
PDF

Abstract

We adopted a green, economical and simple method in which konjac glucomannan (KGM) was used as a carrier to support CNTs to construct a three-dimensional structure filled with epoxy resin to improve the absorbing performance of epoxy resin. Through the reflection of the internal multi-level pore structure and the dielectric loss effect of CNTs, the dissipation and absorption of electromagnetic waves are realized. This KGM derived CNTs foam exhibits high specific microwave absorption performance with a minimum absorption of −25.2 dB at 11.3 GHz and a qualified bandwidth of around 2.89 GHz (RL⩽ −10 dB), which is achieved by KDCF5/Epoxy with the coating layer thickness of 1.8 mm. We provide a novel and cost-effective method to achieve excellent absorbing performance under thin thickness and low load. The CNTs foam also has a lower density (6.5 mg/cm3) and can improve the absorbing properties of the epoxy while maintaining its various advantages, thereby expanding the application range of the epoxy resin.

Keywords

microwave absorption performance / CNTs / KGM / carbon foam

Cite this article

Download citation ▾
Xiaoyan Zhang, Yan Zhao, Shuang Li, Kai Wang. KGM Derived CNTs Foam/Epoxy Composites with Excellent Microwave Absorbing Performance. Journal of Wuhan University of Technology Materials Science Edition, 2022, 37(2): 155-162 DOI:10.1007/s11595-022-2512-4

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

Viau G, Ravel F, Ache O, et al. Preparation and Microwave Characterization of Spherical and Monodisperse Co Ni Particles[J]. J. of Mag. and Mag., 1995, 140: 377-378.

[2]

Mdarhri A, Carmona F, Brosseau C, et al. Direct Current Electrical and Microwave Properties of Polymer-multiwalled Carbon Nanotubes Composites[J]. J. of App. Phy., 2008, 103(5): 054303

[3]

Hou T, Wang B, Jia Z, et al. A Review of Metal Oxide-related Microwave Absorbing Materials from the Dimension and Morphology Perspective[J]. J. of Mat. Sci., 2019, 30(12): 10961-10984.

[4]

Gupta S, Tai NH. Carbon Materials and Their Composites for Electromagnetic Interference Shielding Effectiveness in X-band[J]. Carbon, 2019, 152: 159-187.

[5]

Qi X, Qin C, Zhong W, et al. Large-scale Synthesis of Carbon Nanomaterials by Catalytic Chemical Vapor Deposition: A Review of the Effects of Synthesis Parameters and Magnetic Properties[J]. Materials., 2010, 3(8): 4142-4174.

[6]

Munir A. Microwave Radar Absorbing Properties of Multiwalled Carbon Nanotubes Polymer Composites: A Review[J]. Adv. in Pol. Tec., 2017, 36(3): 362-370.

[7]

Alegaonkar AP, Alegaonkar PS. Nanocarbons: Preparation, Assessments, and Applications in Structural Engineering, Spintronics, Gas sensing, EMI shielding, and Cloaking in X-band[J]. In Nano. and Its Com., 2019:171–285

[8]

Wang C, Murugadoss V, Kong J, et al. Overview of Carbon Nanostructures and Nanocomposites for Electromagnetic Wave Shielding[J]. Carbon, 2018, 140: 696-733.

[9]

Abbasi H, Antunes M, Velasco JI. Recent Advances in Carbon-based Polymer Nanocomposites for Electromagnetic Interference Shielding[J]. Pro. in Mat. Sci., 2019, 103: 319-373.

[10]

Sankaran S, Deshmukh K, Ahamed MB, et al. Recent Advances in Electromagnetic Interference Shielding Properties of Metal and Carbon Filler Reinforced Flexible Polymer Composites: A Review[J]. Com. Part A: App. Sci. and Man., 2018, 114: 49-71.

[11]

Micheli D, Apollo C, Pastore R, et al. X-Band Microwave Characterization of Carbon-based Nanocomposite Material, Absorption Capability Comparison and RAS Design Simulation[J]. Com. Sci. and Tec., 2010, 70(2): 400-409.

[12]

Choi BG, Yang M, Hong WH, et al. 3D Macroporous Graphene Frameworks for Supercapacitors with High Energy and Power Densities[J]. ACS Nano., 2012, 6(5): 4020-4028.

[13]

Liu J, Zhang HB, Sun R, et al. Hydrophobic, Flexible, and Lightweight MXene Foams for High-performance Electromagnetic-interference Shielding[J]. Adv. Mat., 2017, 29(38): 1702367

[14]

Liu Z, Zhao N, Shi C, et al. Synthesis of Three-dimensional Carbon Networks Decorated with Fe3O4 Nanoparticles as Lightweight and Broadband Electromagnetic Wave Absorber[J]. J. of All. and Com., 2019, 776: 691-701.

[15]

Qiu X, Wang L, Zhu H, et al. Lightweight and Efficient Microwave Absorbing Materials Based on Walnut Shell-derived Nano-porous Carbon[J]. Nan., 2017, 9(22): 7408-7418.

[16]

Lai Y, Wang S, Qian D, et al. Tunable Electromagnetic Wave Absorption Properties of Nickel Microspheres Decorated Reduced Graphene Oxide[J]. Cer. Int., 2017, 43(15): 12904-12914.

[17]

Qiu J, Qiu T. Fabrication and Microwave Absorption Properties of Magnetite Nanoparticle-carbon Nanotube-hollow Carbon Fiber Composites[J]. Carbon, 2015, 81: 20-28.

[18]

Makeiff DA, Huber T. Microwave Absorption by Polyaniline-carbon Nanotube Composites[J]. Syn. Met., 2006, 156(7–8): 497-505.

[19]

Wang L, Liu M, Wang G, et al. An Ultralight Nitrogen-doped Carbon Aerogel Anchored by Ni-NiO Nanoparticles for Enhanced Microwave Adsorption Performance[J]. J. of All. and Com., 2019, 776: 43-51.

[20]

Zhu H, Lin H, Guo H, et al. Microwave Absorbing Property of Fe-filled Carbon Nanotubes Synthesized by a Practical Route[J]. Mat. Sci. and Eng., 2007, 138(1): 101-104.

[21]

Ate M, Eker AA, Eker B. Carbon Nanotube-based Nanocomposites and Their Applications[J]. J. of Adh. Sci. and Tec., 2017, 31(18): 1977-1997.

[22]

Wang Y, Mi H, Zheng Q, et al. Flexible Infrared Responsive Multi-walled Carbon Nanotube/Form-stable Phase Change Material Nanocomposites[J]. ACS App. Mat. & Int., 2015, 7(38): 21602-21609.

[23]

Poduval RK, Noimark S, Colchester RJ, et al. Optical Fiber Ultrasound Transmitter with Electrospun Carbon Nanotube-polymer Composite[J]. App. Phy. Let., 2017, 110(22): 223701

[24]

Novoselov KS, Geim AK, Morozov SV, et al. Two-dimensional Gas of Massless Dirac Fermions in Graphene[J]. Nature, 2005, 438(7065): 197-200.

[25]

Abbasi H, Antunes M, Velasco J. Graphene Nanoplatelets-reinforced Polyetherimide Foams Prepared by Water Vapor-induced Phase Separation[J]. Exp. Pol. Let., 2015, 9(5): 412-423.

[26]

Kotov NA. Carbon Sheet Solutions[J]. Nature, 2006, 442(7100): 254-255.

[27]

Sebastián D, Baglio V, Girolamo M, et al. Carbon Nanofiber-based Counter Electrodes for Low Cost Dye-sensitized Solar Cells[J]. J.of Pow. Sou., 2014, 250: 242-249.

[28]

Harris PJ. Carbon Nanotubes and Related Structures: New Materials for the Twenty-first Century[J]. Ame. Ass. of Phy. Tea., 2004: 414–416

[29]

Brown JM, Anderson DP, Justice RS, et al. Hierarchical Morphology of Carbon Single-walled Nanotubes during Ssonication in an Aliphatic Diamine[J]. Polymer, 2005, 46(24): 10854-10865.

[30]

Li Y, Wei B, Liang J, et al. Transformation of Carbon Nanotubes to Nanoparticles by Ball Milling Process[J]. Carbon, 1999, 37(3): 493-497.

[31]

Park C, Ounaies Z, Watson KA, et al. Dispersion of Single Wall Carbon Nanotubes by in situ Polymerization under Sonication[J]. Che. Phy. Let., 2002, 364(3–4): 303-308.

[32]

McNally T, Pötschke P, Halley P, et al. Polyethylene Multiwalled Carbon Nanotube Composites[J]. Polymer, 2005, 46(19): 8222-8232.

[33]

Kumar R, Dhakate SR, Gupta T, et al. Effective Improvement of the Properties of Light Weight Carbon Foam by Decoration with Multiwall Carbon Nanotubes[J]. J. of Mat. Che., 2013, 1(18): 5727-5735.

[34]

Yang Y, Gupta MC, Dudley KL, et al. Novel Carbon Nanotube-polystyrene Foam Composites for Electromagnetic Interference Shielding[J]. Nano Letters, 2005, 5(11): 2131-2134.

[35]

Shi L, Zhao Y, Li Y, et al. Octahedron Fe3O4 Particles Supported on 3D MWCNT/Graphene Foam: In-situ Method and Application as a Comprehensive Microwave Absorption Material[J]. App. Sur. Sci., 2017, 416: 329-337.

[36]

Saib A, Bednarz L, Daussin R, et al. Carbon Nanotube Composites for Broadband Microwave Absorbing Materials[J]. IEEE Tra. on Mic. The., 2006, 54(6): 2745-2754.

[37]

Ghanbari F, Dehaghi SM, Mahdavi H. Epoxy-based Multilayered Coating Containing Carbon Nanotube (CNT), Silicon Carbide (SiC), and Carbonyl Iron (CI) Particles: As Efficient Microwave Absorbing Materials[J]. J. of Co. Tec., 2020: 1–12

[38]

Fu C, Huang H, Li X, et al. Adjusting the Microwave Absorption Properties of Carbon Nanotube Composites with Ferrocene by Annealing under Different Conditions[J]. J. of All.s and Com., 2020, 845: 156226.

[39]

Xu H, Yin X, Li M, et al. Ultralight Cellular Foam from Cellulose Nanofiber/Carbon Nanotube Self-assemblies for Ultrabroad-band Microwave Absorption[J]. ACS App. Mat. & Int., 2019, 11(25): 22628-22636.

[40]

Zhong B, Cheng Y, Wang M, et al. Three Dimensional Hexagonal Boron Nitride Nanosheet/Carbon Nanotube Composites with Light Weight and Enhanced Microwave Absorption Performance[J]. Com. Part A., 2018, 112: 515-524.

[41]

Shu R, Wan Z, Zhang J, et al. Facile Design of Three-dimensional Nitrogen-doped Reduced Graphene Oxide/multi-walled Carbon Nanotube Composite Foams as Lightweight and Highly Efficient Microwave Absorbers[J]. ACS App. Mat. & Int., 2019, 12(4): 4689-4698.

[42]

Zhang T, Xiao B, Zhou P, et al. Porous-carbon-nanotube Decorated Carbon Nanofibers With Effective Microwave Absorption Properties[J]. Nanotechnology, 2017, 28(35): 355708

[43]

Yang Z, Che Y, Sun X, et al. Broadband Polarization-insensitive Microwave-Absorbing Composite Material based on Carbon Nanotube Film Metamaterial and Ferrite[J]. J. of App. Phy., 2019, 125(18): 185103

[44]

Li Y, Li S, Zhang T, et al. 3D Hierarchical Co3O4/Reduced Graphene oxide/Melamine Derived Carbon Foam as a Comprehensive Microwave Absorbing Material[J]. J. of All. and Com., 2019, 792: 424-431.

[45]

Wu G, He Y, Zhan H, et al. A novel Fe3O4/Carbon Nanotube Composite Film With a Cratered Surface Structure for Effective Microwave Absorption[J]. J. of Mat. Sci., 2020, 31: 11508-11519.

[46]

Haritha T, Ramji K, Subrahmanyam C, et al. Microwave-absorption Characteristics of Polyaniline-coated Multi-walled Carbon Nanotube Composites[J]. Pla. Rub. and Com., 2020: 1–9

[47]

Savi P, Giorcelli M, Quaranta S. Multi-walled Carbon Nanotubes Composites for Microwave Absorbing Applications[J]. App. Sci., 2019, 9(5): 851

[48]

Kuang J, Hou X, Xiao T, et al. Three-dimensional Carbon Nanotube/SiC Nanowire Composite Network Structure for High-efficiency Electromagnetic Wave Absorption[J]. Cer. Int., 2019, 45(5): 6263-6267.

[49]

Jia Z, Lin K, Wu G, et al. Recent Progresses of High-temperature Microwave-Absorbing Materials[J]. Nano, 2018, 13(06): 1830005

[50]

Yan J, Huang Y, Han X, et al. Metal Organic Framework (ZIF-67)-derived Hollow CoS2/N-doped Carbon Nanotube Composites for Extraordinary Electromagnetic Wave Absorption[J]. Com. Part B., 2019, 163: 67-76.

AI Summary AI Mindmap
PDF

109

Accesses

0

Citation

Detail

Sections
Recommended

AI思维导图

/