Highly Penetrable Silicone Emulsion for Water-Repellent Concrete with Reserved Surface Recoatability

Qian Zhang , Guozheng Zhang , Jun You , Qunchao Zhang , Haizheng Tao

Journal of Wuhan University of Technology Materials Science Edition ›› 2022, Vol. 37 ›› Issue (1) : 58 -65.

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Journal of Wuhan University of Technology Materials Science Edition ›› 2022, Vol. 37 ›› Issue (1) : 58 -65. DOI: 10.1007/s11595-022-2499-x
Cementitious Material

Highly Penetrable Silicone Emulsion for Water-Repellent Concrete with Reserved Surface Recoatability

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Abstract

Highly stable and permeable silicone emulsions were prepared by encapsulating N-octyl triethoaysilane microdroplets into micelles of NH2-PDMS/SiO2. The conversion of siloxane to sub-1 µm emulsions, on one hand, endows the concrete with a highly hydrophobic internal surface. While, its outside surface maintains relatively high surface energy, which is beneficial for the post-coating of other polymers. As a result, the coated concreted can simultaneously acquire water repellency and low permeability. The utilization of water-dispersed silicone emulsions, on the other hand, is beneficial for the environmental protection. Thus, this work offered a green procedure for the comprehensive protection of concrete.

Keywords

concrete / silicone / waterproof / recoatability / emulsions

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Qian Zhang, Guozheng Zhang, Jun You, Qunchao Zhang, Haizheng Tao. Highly Penetrable Silicone Emulsion for Water-Repellent Concrete with Reserved Surface Recoatability. Journal of Wuhan University of Technology Materials Science Edition, 2022, 37(1): 58-65 DOI:10.1007/s11595-022-2499-x

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References

[1]

Zhang W, Di B, Song D. Research Progress of Anti-penetration Yaw Technology for Concrete Protective Structures. IOP. Conference Series Materials Science and Engineering, 2020, 768: 032 017.

[2]

Smith S H, Qiao C, Suraneni P, et al. Service-life of Concrete in Freeze-thaw Environments: Critical Degree of Saturation and Calcium Oxychloride Formation. Cement and Concrete Research, 2019, 122: 93-106.

[3]

Chi J, Zhang G, Xie Q, et al. High Performance Epoxy Coating with Cross-linkable Solvent via Diels-Alder Reaction for Anti-corrosion of Concrete. Prog. Org.Coat., 2020, 139: 105 473.

[4]

Chen J, Ma X, Wang H, et al. Experimental Study on Anti-icing and Deicing Performance of Polyurethane Concrete as Road Surface Layer. Constr. Build. Mater., 2018, 161: 598-605.

[5]

Diamant M V, Brennai A, Bolzoni F, et al. Effect of Polymer Modified Cementitious Coatings on Water and Chloride Permeability in Concrete. Constr. Build. Mater., 2013, 49: 720-728.

[6]

Zheng W, Chen W G, Feng T, et al. Enhancing Chloride Ion Penetration Resistance into Concrete by Using Graphene Oxide Reinforced Waterborne Epoxy Coating. Prog. Org. Coat., 2020, 138: 105 389.

[7]

Chruściel J J, Leśniak E. Modification of Epoxy Resins with Functional Silanes, Polysiloxanes, Silsesquioxanes, Silica and Silicates. Prog. Polym. Sci., 2015, 41: 67-121.

[8]

Sangermano M, Foix D, Kortaberria G, et al. Multifunctional Antistatic and Scratch Resistant UV-cured Acrylic Coatings. Prog. Org. Coat., 2013, 76: 1 191-1 196.

[9]

Lewis O D, Critchlow G W, Wilcox G D, et al. A Study of the Corrosion Resistance of a Waterborne Acrylic Coating Modified with Nano-sized Titanium Dioxide. Prog. Org. Coat., 2012, 73: 88-94.

[10]

Toutanji H A, Choi H, Wong D, et al. Applying a Polyurea Coating to High-performance Organic Cementitious Materials. Constr. Build. Mater., 2013, 38: 1 170-1 179.

[11]

Pan X, Shi Z, Shi C, et al. A Review on Concrete Surface Treatment Part I: Types and Mechanisms. Constr. Build. Mater., 2017, 132: 578-590.

[12]

Vipulanandan C, Liu J. Performance of Polyurethane-coated Concrete in Sewer Environment. Cem. Concr. Res., 2005, 35: 1 754-1 763.

[13]

MacMullen J, Zhang Z, Radulovic J, et al. An Investigation of Hydroxyl End-terminated Polydimethylsiloxane (PDMS) in Exterior Oilin-water (O/W) Emulion Treatments. Constr. Build. Mater., 2012, 37: 283-290.

[14]

Song J, Zhao D, Han Z, et al. Super Robust Superhydrophobic Concrete. Mater. Chem., 2017, A5: 14 542-14 550.

[15]

Khanzadeh M, Sudbrink B, Ley M T. Determining the Effective Service Life of Silane Treatments in Concrete Bridged Decks. Constr. Build. Mater., 2016, 116: 121-127.

[16]

Sun Z, Wen J, Wang W, et al. Polyurethane Covalently Modified Polydimethylsiloxane (PDMS) Coating with Increased Surface Energy and Recoatability. Prog. Org.Coat., 2020, 146: 105 744.

[17]

Li Y, Hu T, Li B, et al. Totally Waterborne and Highly Durable Superamphiphobic Coatings for Anti-icing and Anti-corrosion[J]. Advanced Materials Interfaces, 2019: 1 901 255

[18]

Zhang Y, Li S, Zhang W, et al. Preparation and Mechanism of Graphene Oxide/isobutyltriethoxysilane Composite Emulsion and Its Effects on Waterproof Performance of Concrete. Constr. Build. Mater., 2019, 208: 343-349.

[19]

Shen Y, Wu Y, Tao J, et al. Spraying Fabrication of Durable and Transparent Coatings for Anti-icing Application: Dynamic Water Repellency, Icing Delay, and Ice Adhesion. ACS Appl. Mater. Interfaces., 2019, 11: 3 590-3 598.

[20]

Wu X, Zhao X, Ho J W C, et al. Design and Durability Study of Environmental Friendly Room Temperature Processable Icephobic Coatings. Chem. Eng., 2019, 355: 901-909.

[21]

Chen J, Zhou Y, Zhou C, et al. A Durable Underwater Superoleophobic and Underoil Superhydrophobic Fabric for Versatile Oil/water Separation. Chem. Eng., 2019, 370: 1 218-1 227.

[22]

Musikavanhu B, Hu Z, Dzapata R L, et al. Facile Method for the Preparation of Superhydrophobic Cellulosic Paper. Appl. Surf. Sci., 2019, 496: 143 648.

[23]

Zhu X, Zhang F, Zhang L, et al. A Highly Stretchable Cross-linked Polyacrylamide Hydrogel as an Effective Binder for Silicon and Sulfur Electrodes toward Durable Lithium-Ion Storage. Adv. Funct. Mater., 2018, 28: 1 705.

[24]

Zhao H, She W, Shi D, et al. Polyurethane/POSS Nanocomposites for Superior Hydrophobicity and High Ductility. Composites Part B Engineering, 2019, 177: 107 441.

[25]

Qu M, Ma L, Wang J, et al. Multifunctional Superwettable Material with Smart pH Responsiveness for Efficient and Controllable Oil/water Separation and Emulsified Wastewater Purification. ACS. Appl. Mater. Interfaces, 2019, 11: 24 668-24 682.

[26]

Yang H, Pi P, Yang Z, et al. Design of a Superhydrophobic and Superoleeophilic film Using Cured Fluoropolymer @Silica Hybrid. Appl. Surf. Sci., 2016, 388: 2 268-2 273.

[27]

Dong B, Wang F, Abadikhah H, et al. Simple Fabrication of Concrete with Remarkable Self-cleaning Ability, Robust Superhydrophobicity, Tailored Porosity, and Highly the Thermal and Sound Insulation. ACS Appl. Mater. Interfaces., 2019, 11: 42 801-42 807.

[28]

Brown G L. Formation of Films from Polymer Dispersions. Journal of Polymer Science, 1956, 22: 42 3-434.

[29]

Winnik M A. Latex Film Formation, Current Opinion in Colloid & Interface Science. Appl. Surf., 1997, 2: 192-199.

[30]

Erkselius S, Wadsö L, Karlsson O J. Drying Rate Variations of Latex Dispersions due to Salt Induced Skin Formation. Colloid Interface Sci, 2008, 317: 83-95.

[31]

Voogt B, Venema P, Sagis L, et al. Surface Characterization of Drying Acrylic Latex Dispersions with Variable Methacrylic Acid Content Using Surface Dilatational Rheology. Colloid Interface Science, 2019, 556: 584-591.

[32]

Mesic B, Cairns M, Järnstrom L, et al. Film Formation and Barrier Performance of Latex Based Coating: Impact of Dying Temperature in a Flexographic Process. Prog. Org. Coat., 2019, 129: 43-51.

[33]

Du S. Effect of Curing Conditions on Properties of Cement Asphalt Emulsion Mixture. Constr. Build. Mater., 2018, 164: 84-93.

[34]

Hu C. Microstructure and Mechanical Propertirties of Fly Ash Blended Cement Pastes. Construction and Building Materials, 2014, 73: 618-625.

[35]

Yoobanpot N, Jamsawang P, Krairan K, Jongpradist P, et al. Laboratory Investigation of the Properties of Cement Fly Ash Gravel for Use as a Column-supported Embankment. Constr. Build. Mater., 2020, 257: 119 493.

[36]

Chindaprasirt P, Jaturapitakkul C, Sinsiri T. Effect of Fly Ash Fineness on Microstructure of Blended Cement Paste. Constr. Build. Mater., 2007, 21: 1 534-1 541.

[37]

Han X, Yang J, Feng J, et al. Research on Hydration Mechanism of Ultrafine Fly Ash and Cement Composite. Constr. Build. Mater., 2019, 227: 116 697.

[38]

Carrascosa L A M, Zarzuela R, Badreldin N, et al. A Simple, Long-lasting Treatment for Concrete by Combining Hydrophobic Performance with a Photoinduced Superhydrophilic Surface for Easy Temoval of Oily Pollutants. ACS Appl. Mater. Interfaces., 2020, 12: 19 974-19 987.

[39]

Zhang Z, Gao Z, Wang Y, et al. Eco-friendly, Self-healing Hydrogels for Adhesive and Elastic Strain Sensors, Circuit Repairing, and Flexible Electronic Devices. Macromolecules, 2019, 52: 2 531-2 541.

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