Synthesis and Performance Characterization of a Low Adsorption Clay-resistant Polycarboxylate Superplasticizer

Ying Zhang , Pengshuo Wang , Guowen Sun , Jianming Yang , Rui Gao

Journal of Wuhan University of Technology Materials Science Edition ›› 2021, Vol. 36 ›› Issue (3) : 446 -455.

PDF
Journal of Wuhan University of Technology Materials Science Edition ›› 2021, Vol. 36 ›› Issue (3) : 446 -455. DOI: 10.1007/s11595-021-2429-3
Organic Materials

Synthesis and Performance Characterization of a Low Adsorption Clay-resistant Polycarboxylate Superplasticizer

Author information +
History +
PDF

Abstract

A low adsorption clay-resistant polycarboxylate superplasticizer (KN-PC) was synthesized using acrylic acid and isopentenol polyoxyethylene ether as the main reaction materials. The structural characterization and clay-resistant mechanism of the KN-PC were explored using Fourier transform infrared spectroscopy and X-ray diffraction, and the effect of the KN-PC on the performance of composite paste with various montmorillonite (MMT) contents was analyzed. Compared with ordinary polycarboxylate superplasticizer (PC), the KN-PC has a low sensitivity to the MMT. By the action of the MMT, the adsorption dosage of the KN-PC on the MMT is much smaller than that of the PC.

Keywords

polycarboxylate superplasticizer / clay-resistant / montmorillonite / performance / synthesis

Cite this article

Download citation ▾
Ying Zhang, Pengshuo Wang, Guowen Sun, Jianming Yang, Rui Gao. Synthesis and Performance Characterization of a Low Adsorption Clay-resistant Polycarboxylate Superplasticizer. Journal of Wuhan University of Technology Materials Science Edition, 2021, 36(3): 446-455 DOI:10.1007/s11595-021-2429-3

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

Frank W, Stefan B, Joachim P. Effects of the Molecular Architecture of Comb-shaped Superplasticizers on their Performance in Cementitious Systems[J]. Cement and Concrete Composites, 2007, 29(4): 251-262.

[2]

Collepardi M. Admixtures Used to Enhance Placing Characteristics of Concrete[J]. Cement and Concrete Composites, 1998, 20(2): 103-112.

[3]

Zhang M H, Sisomphon K, Ng T S, et al. Effect of Superplasticizers on Workability Retention and Initial Setting Time of Cement Pastes[J]. Construction and Building Materials, 2010, 24(9): 1700-1707.

[4]

Lei L, Plank J. A Study on the Impact of Different Clay Minerals on the Dispersing Force of Conventional and Modified Vinyl Ether Based Polycarboxylate Superplasticizers[J]. Cement and Concrete Research, 2014, 60: 1-10.

[5]

Ng S, Plank J. Interaction Mechanisms between Na Montmorillonite Clay and MPEG-based Polycarboxylate Superplasticizers[J]. Cement and Concrete Research, 2012, 42(6): 847-854.

[6]

Plank J, Bian H. Method to Asses the Quality of Casein Used as Superplasticizer Inself-levelling Compounds[J]. Cement and Concrete Research, 2010, 40(5): 710-715.

[7]

Wang L, Wang D M. Effects of Clay on Properties of Polycarboxylate Superplasticizer and Solutions[J]. Journal of Wuhan University of Technology-Materials Science Edition, 2015, 30(6): 1167-1171.

[8]

Zhu H J, Zhang G H, He Z Q, et al. Preparation and Properties of Polycarboxylic Superplasticizer with High Tolerance to Clay[J]. Chemical Industry and Engineering Progress, 2016, 35(9): 2920-2925.

[9]

Hirata T, Yuasa T, Shiote K. Method for Dispersion of Cement[P]. US Patent 6048916, 2000

[10]

Tanaka Y, Ohta A, Hirata T. Cement Composition Using the Dispersant of (meth) Acrylic Esters,(Meth) Acrylic Acids Polymers[P]. US Patent 6187841, 2001

[11]

Lei L, Plank J. A Concept for a Polycarboxylate Superplasticizer Possessing Enhanced Clay Tolerance[J]. Cement and Concrete Research, 2012, 42(10): 1299-1306.

[12]

Chen G, Lei J H, Du Y, et al. Synthesis of a Novel Polycarboxylate Superplasticizer with Carboxyl Group as Side Chain Terminal Group to Enhance Its Clay Tolerance[J]. Journal of Wuhan University of Technology-Materials Science Ed., 2018, 33(01): 226-232.

[13]

Sun C, Zhou H, Li X, et al. The Clay-tolerance of Amide-modified Polycarboxylate Superplasticizer and Its Performance with Clay-Bearing Aggregates, Proceedings of the 2015 International Conference on Materials[J]. Environmental and Biological Engineering, 2015, 237–241

[14]

Xing G B, Wang W P, Xu J. Grafting Tertiary Amine Groups into the Molecular Structures of Polycarboxylate Superplasticizers Lowers Their Clay Sensitivity[J]. RSC Advances, 2016, 6(108): 106921-106927.

[15]

China Metrology Press. Method for Testing Uniformity of Concrete Admixture[S]. GB/T 8077-2012, 2012

[16]

Fu C F, Zheng G J, Li K L. Effects of the Carboxyl Density on the Properties of Polycarboxylate-Type Superplasticizer[J]. Advanced Materials Research, 2014, 989–994: 151-155.

[17]

Jing Z J. Study on Synthesis and Properties of Low Sensitive Type Polycarboxylate Superplasticizer[J]. Materials and Chemical Engineering, 2018, 392(3): 032001

[18]

Ma X. Synthesis of New Polyether Polycarboxylate Superplasticizer[J]. Materials Science Edition, 2010, 25(50): 799-802.

[19]

Stecher J. Novel Concrete Superplasticizers Based on Phosphate Esters[J]. Cement and Concrete Research, 2019, 119: 36-43.

[20]

Tregger N A, Pakula M E, Shah S P. Influence of Clays on the Rheology of Cement Pastes[J]. Cement and Concrete Research, 2010, 40: 384-391.

[21]

Sakai E, Atarashi D, Daimon M. Interaction between Superplasticizers and Clay Minerals[J]. JCA Proceedings of Cement&Concrete, 2005, 58: 387-392.

[22]

Amarasinghe P M, Katti K S, Katti D R. Nature of Organic Fluid-montmorillonite Interactions:an FTIR Spectroscopic Study[J]. Colloid Interface Science, 2009, 337(91): 97-105.

[23]

Lei L, Plank J. Synthesis Working Mechanism and Effectiveness of a Novel Cycloaliphatic Superplasticizer for Concrete[J]. Cement and Concrete Research, 2012, 42(1): 118-123.

[24]

Lei L, Plank J. A Concept for a Polycarboxylate Superplasticizer Possessing Enhanced Clay Tolerance[J]. Cement and Concrete Research, 2012, 42(10): 1299-1306.

[25]

Lei L, Plank J. Synthesis and Properties of a Vinyl Ether-Based Polycarboxylate Superplasticizer for Concrete Possessing Clay Tolerance[J]. Industrial & Engineering Chemistry Research, 2014, 53(3): 1048-1055.

AI Summary AI Mindmap
PDF

153

Accesses

0

Citation

Detail

Sections
Recommended

AI思维导图

/