Effect of M/P and Borax on the Hydration Properties of Magnesium Potassium Phosphate Cement Blended with Large Volume of Fly Ash

Runqing Liu , Yuanquan Yang , Sihui Sun

Journal of Wuhan University of Technology Materials Science Edition ›› 2018, Vol. 33 ›› Issue (5) : 1159 -1167.

PDF
Journal of Wuhan University of Technology Materials Science Edition ›› 2018, Vol. 33 ›› Issue (5) : 1159 -1167. DOI: 10.1007/s11595-018-1948-z
Cementitious Materials

Effect of M/P and Borax on the Hydration Properties of Magnesium Potassium Phosphate Cement Blended with Large Volume of Fly Ash

Author information +
History +
PDF

Abstract

The effect of the borax content and magnesia to phosphate ratio (M/P) on the hydration properties of the magnesium potassium phosphate cement (MKPC) with large volume of fly ash was investigated, and a five-hydration-stage for MKPCs was proposed. The results show that MKPC sets rapidly with less than 8% of borax, which is unfavorable to the application of MKPC on construction. Adding more than 8% (including 8%) of borax results in a secondary hydration peak for MKPC, in which the process of hydration can be divided into five stages, namely, pre-induction period, induction period, acceleration period, deceleration period and stable period. M/P ratios could not change the multi-step reactive stages but higher M/P ratios could accelerate the hydration. Borax tends to impact the formation of Mg-containing hydrated products.

Keywords

MKPC / hydration properties / M/P / borax / process of hydration

Cite this article

Download citation ▾
Runqing Liu, Yuanquan Yang, Sihui Sun. Effect of M/P and Borax on the Hydration Properties of Magnesium Potassium Phosphate Cement Blended with Large Volume of Fly Ash. Journal of Wuhan University of Technology Materials Science Edition, 2018, 33(5): 1159-1167 DOI:10.1007/s11595-018-1948-z

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

Yang Q, Zhang S, Wu X. Deicer-Scaling Resistance of Phosphate Cement-Based Binder for Rapid Repair of Concrete[J]. Low Temp. Arch. Tech., 2002, 32(1): 165-168.

[2]

Zhang G, Li G, He T. Effects of Sulphoaluminate Cement on the Strength and Water Stability of Magnesium Potassium Phosphate Cement[J]. Constr. Build. Mater., 2016, 132: 335-342.

[3]

Abdelrazig B E I. Chemical Reactions in Magnesia-Phosphate Cement[C]. Proc. Br. Ceram. Soc., 1984

[4]

Lahalle H, Coumes C C D, Mesbah A, et al. Investigation of Magnesium Phosphate Cement Hydration in Diluted Suspension and Its Retardation by Boric Acid[J]. Cement Concrete Res., 2016, 87: 77-86.

[5]

Mestres G, Ginebra M P. Novel Magnesium Phosphate Cements with High Early Strength and Antibacterial Properties[J]. Acta Biomaterialia, 2010, 7(4): 1853-1861.

[6]

Michael G, Loanna P, Kosmas S, et al. Concrete Solutions, 2016 Oxfordshire: Taylor & Francis Group.

[7]

Formosa J, Lacasta A M, Navarro A, et al. Magnesium Phosphate Cements Formulated with a Low-Grade MgO By-Product: Physico-Mechanical and Durability Aspects[J]. Constr. Build. Mater., 2015, 91: 150-157.

[8]

Yang J, Qian C. Effect of Borax on Hydration and Hardening Properties of Magnesium and Potassium Phosphate Cement Pastes[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2010, 25: 613-618.

[9]

Yang J, Qian Chunxiang. The Influence of Retarder Borax on the Hydration and Hardening Properties of Magnesium Phosphate[J]. Journal of Materials Science and Engineering(China), 2010, 1: 31-35.

[10]

Li Y, Sun J, Chen B. Experimental Study of Magnesia and M/P Ratio Influencing Properties of Magnesium Phosphate Cement[J]. Constr. Build. Mater., 2014, 65: 177-183.

[11]

Qiao F, Chau C K, Li Z. Property Evaluation of Magnesium Phosphate Cement Mortar as Patch Repair Material[J]. Constr. Build. Mater., 2010, 24(5): 695-700.

[12]

Gardner L J, Bernal S A, Walling S A, et al. Characterisation of Magnesium Potassium Phosphate Cements Blended With Fly Ash and Ground Granulated Blast Furnace Slag[J]. Cement Concrete Res., 2015, 74: 78-87.

[13]

Li Y, Chen B. Factors that Affect the Properties of Magnesium Phosphate Cement[J]. Constr. Build. Mater., 2013, 47: 977-983.

[14]

Wang Hongtao. Study on the High Performance Magnesia-phosphate Cement Based Composites, 2006 Chongqing: Chongqing University.

[15]

Li Y, Sun J, Li J, et al. Effects of Fly Ash, Retarder and Calcination of Magnesia on Properties of Magnesia–Phosphate Cement[J]. Advances in Cement Research, 2015, 27(7): 373-380.

[16]

Fan S, Chen B. Experimental Study of Phosphate Salts Influencing Properties of Magnesium Phosphate Cement[J]. Constr. Build. Mater., 2014, 65(9): 480-486.

[17]

Lahalle H, Coumes C C D, Mesbah A, et al. Investigation of Magnesium Phosphate Cement Hydration in Diluted Suspension and Its Retardation by Boric Acid[J]. Cement Concrete Res., 2016, 87: 77-86.

[18]

Xu B, Ma H, Shao H, et al. Influence of Fly Ash on Compressive Strength and Micro-Characteristics of Magnesium Potassium Phosphate Cement Mortars[J]. Cement Concrete Res., 2017, 99: 86-94.

[19]

Rouzic M L, Chaussadent T, Platret G, et al. Mechanisms of K-Struvite Formation in Magnesium Phosphate Cements[J]. Cement Concrete Res., 2017, 91: 117-122.

[20]

Viani A, Peréz-Estébanez M, Pollastri S, et al. In Situ, Synchrotron Powder Diffraction Study of the Setting Reaction Kinetics of Magnesium-Potassium Phosphate Cements[J]. Cement Concrete Res., 2015, 79: 344-352.

AI Summary AI Mindmap
PDF

204

Accesses

0

Citation

Detail

Sections
Recommended

AI思维导图

/