Effect of chromium micro-alloying on the corrosion behavior of a low-carbon steel rebar in simulated concrete pore solutions

Abstract

A new low-cost corrosion-resistant rebar (HRB400R) was designed and fabricated by chromium micro-alloying. The effects of Cr on the passivation and corrosion behavior of this rebar in the simulated concrete pore solutions were studied systematically, and its improved corrosion resistance was revealed. In the Cl^--free saturated Ca(OH)₂ solution, the HRB400R rebar presented nearly the same passive film and similar passivation ability compared to the common carbon steel rebar. In the long-term immersion corrosion test in the Cl^--contained Ca(OH)₂ solution, the HRB400R rebar presented improved corrosion resistance and obvious longer passivation-maintaining period. Micro-alloying of Cr element in the rebar matrix enhanced its corrosion resistance against Cl^--attack and retarded the corrosion initiation in the matrix. In the alkaline NaCl salt spraying test, the HRB400R rebar also presented obviously lower mass-loss rate. The enrichment of Cr element in the rust layer improved its retardant effect to the penetration of aggressive medium, and decreased the corrosion propagation rate of the rebar.

Keywords

Cr micro-alloying / corrosion-resistant rebar / improved corrosion resistance / simulated concrete pore solutions

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